Clear and pigmented multi-component oil-in-water resin emulsion textile decorating compositions and process for preparing same

Claim 1

THE PROCESS OF PREPARING AN OIL-IN-WATER RESIN EMULSION TEXTILE DECORATING PIGMENT COLOR COMPOSITION WHICH COMPRISES PREPARING AS A FIRST COMPONENT AN AQUEOUS RESIN EMULSION CONTAINING AN ESTER OF A POLYUNSATURATED FATTY ACID WITH A SYNTHETIC ALCOHOL FOARMED BY THE CONDENSATION OF EPICHLOROHYDRIN AND BISPHENOL AS A RESIN BINDER, AN EMULSIFYING AGENT SELECTED FROM THE CLASS CONSISTING OF SOAPS OF FATTY ACIDS, FATTY ACID ESTERS OF POLYETHYLENE GLYCOLS, QUATERNARY AMMONIUM SALTS, FATTY ALCOHOL FATES, POLYETHYLENE OXIDE CONDENSATION PRODUCTS, POLYMERIZED GLYCOL ESTERS AND SODIUM SALTS OF RGANIC SULFONATES, AND A PROTECTIVE COLLIOD, SELECTED FROM THE CLASS CONSISTING OF CASEIN, AMMONIUM CASEINATE, METHYCELLULOSE, SODIUM CARBOXYMETHYLCELLULOSE, GUM TRAGACANTH, DEXTRIN, STARCH, SODIUM POLYACRYLATE, SODIUM POLYMETHACRYLATE, WATER-SOLUBLE AND ALKALU-SOLUBLE HYDROXYETHYLCELLULOSE, LOCUST BEAN GUM, WAATER-SOLUBLE SALTS OF THE MALEIC ADDUCT OF STYRENE, AND ALGINATES, PREPARING AS A SEPARATE SECOND COMPONENT AN AQUEOUS PIGMENT DISPERSION CONTAINING A PIGMENT WHICH IS IN THE IN-WATER DEFLOCCULATED STATE AND WHICH IS A MEMBER OF THE CLASS CONSISTING OF PHTYALOCYANINE PIGMENTS, INSOLUBLE AZO PIGMENTS, VAT PIGMENTS, CARBON BLACKS AND TITANIUM DIOXIDE THE PARTICLES OF SAID PIGMENT IN SAID SEPARATE COMPONENT BEING SURROUNDED BY WATER HAVING DISSOLVED THEREIN A WATER-SOLUBLE FATTY ALCOHOL SULFATE AS A PIGMENT-DISPERSING AGENT, SAID FATTY ALCOHOL FULFATE HAVING AT LEAST 12 CARBON ATOMS IN THE MOLECULE AND BEING PRESENT IN THE SAID SEPARATE COMPONENT IN PROPORTIONS OF AT LEAST ABOUT 10% OF THE WEIGHT OF THE PIGMENT, AND COMBINING SAID EMULSION AND SAID SEPARATE COMPONENT TO FORM A VISCOUS PIGMENT COLOR COMPOSITION SUITABLE AS A COLOR CONCENTATE, WHICH IS DILUTABLE WITH CLEAR EXTENDER PRINT PASTE EMULSIONS TO FORM THE DESIRED STRENGTH OF SHADE WHEN USED FOR TEXTILE PRINTING, SAID PIGMENT COLOR COMPOSITION HAVING, BASED ON THE TOTAL WEIGHT OF SAID PIGMENT COLOR COMPOSITION, BETWEEN ABOUT 4.5% AND ABOUT 31% OF SAID RESIN BINDER BETWEEN ABOUT 0.18% AND ABOUT 2.16% OF SAID EMULSIFYING AGENT, BETWEEN ABOUT 0.07% AND ABOUT 4.34% OF SAID PROTECTIVE COLLOID, SAID RESIN BINDER, EMULSIFYING AGENT AND PROTECTIVE COLLOID ALL BEING DERIVED FROM SAID FIRST RESIN EMULSION COMPONENT, AND BETWEEN ABOUT 7% AND ABOUT 22% OF SAID PIGMENT DERIVED FROM SAID SEPARATE SECOND COMPONENT.