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EP0976799A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Ink-jet compositions containing modified macromolecular chromophores with covalently attached polymers

Assignee: HP Inc
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Filing: 1999-07-29
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Granted: —
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Expires: 2019-07-29
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Abstract

Abstract The present invention relates to ink-jet ink compositions that comprise modified pigment particles (macromolecular chromophores) having functional groups covalently attached for water solubility and polymer chains covalently attached to the pigments. These pigmented inks have enhanced smearfastness, enhanced print quality, improved bleed control, and improved resistance to water when applied to the media. Moreover, these inks have good viscosity and surface tension. These inks are useful in ink-jet printing, including thermal ink jet printing, piezoelectric ink jet printing, and continuous ink jet printing.

Inventors

  • 👤 Joseph W. Tsang
  • 👤 John R. Moffatt

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 23:41
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 22 words
An ink-jet ink composition comprising a macromolecular chromophore comprising at least one water-solublizing functional group and at least one covalently attached polymer.
Claim 2
Dependent Claim 92 words
An ink composition according to Claim 1 wherein said water-solubilizing functional groups are aromatic groups having attached ionizable groups selected from the group consisting carboxylate, sulfonate, ammonium, quaternary ammonium, phosphonium, and mixtures thereof; and said said polymer is covalently attached to said macromolecular chromophore through a polyolefinic group having the structure: R"-CR=C(H)R' wherein R can be H or methyl, R' can be H or an alkyl or aryl having from 1 to 10 carbons and R" can be any alkyl, alkenyl, aryl groups having from 1 to 20 carbons and, optionally, heteroatoms.
Claim 3
Dependent Claim 27 words
An ink composition according to Claim 2 wherein said water-soluble functional groups and said polyolefinic groups comprise from 0.001 mmol/g to 10 mmol/g of said macromolecular chromophore.
Claim 4
Dependent Claim 25 words
An ink composition according to Claim 2 wherein said polyolefinic group is selected from the group consisting vinyl, acrylate, methacrylate, acrylamide, methacrylamide, and mixture thereof.
Claim 5
Dependent Claim 21 words
An ink composition according to Claim 2 wherein said polymer comprises monomers selected from the group consisting of and mixtures thereof.
Claim 6
Dependent Claim 21 words
An ink composition according to Claim 5 wherein said polymer comprises monomers selected from the group consisting of and mixtures thereof.
Claim 7
Dependent Claim 71 words
An ink composition for use in ink-jet printing comprising: a) from 0.001% to 10 wt% of a macromolecular chromophore comprising at least one water-solublizing functional group and at least one covalently attached polymer; b) from 0.01% to 50 wt% of one or more cosolvents; c) from 0% to 40 wt% of one or more water-soluble surfactants/amphiphiles; and d) from 0% to 3 wt% of one or more high molecular weight colloid.
Claim 8
Independent Claim 32 words
A method of ink-jet printing comprising printing on a medium an ink-jet ink composition comprising a macromolecular chromophore comprising at least one water-solublizing functional group and at least one covalently attached polymer.
Claim 9
Dependent Claim 116 words
A method of ink-jet printing according to Claim 8 wherein said water-solubilizing functional groups are aromatic groups having attached ionizable groups selected from the group consisting carboxylate, sulfonate, ammonium, quaternary ammonium, phosphonium, and mixtures thereof, and wherein said polymer is covalently attached to said macromolecular chromophore through a polyolefinic group having the structure: R"-CR=C(H)R' wherein R can be H or methyl, R' can be H or an alkyl or aryl having from 1 to 10 carbons and R" can be any alkyl, alkenyl, aryl groups having from 1 to 20 carbons and, optionally, heteroatoms; and further wherein said water-soluble functional groups and said polyolefinic groups comprise from 0.001 mmol/g to 10 mmol/g of said macromolecular chromophore.
Claim 10
Dependent Claim 28 words
A method of ink-jet printing according to Claim 9 wherein said polyolefinic group is selected from the group consisting of vinyl, acrylate, methacrylate, acrylamide, methacrylamide, and mixture thereof.
Claim 11
Dependent Claim 20 words
A method according to Claim 9 wherein said polymer comprises monomers selected from the group consisting of and mixtures thereof.
Claim 12
Dependent Claim 20 words
A method according to Claim 9 wherein said polymers comprises monomers selected from the group consisting of and mixtures thereof.

References Cited (Backward Citations)

EP0098338A1 Cited
US5176745A Cited
EP0787777A1 Cited
WO1997047699A1 Cited

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