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EP0943666A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Ink, ink set, ink cartridge, recording unit, image recording apparatus and image recording method

Assignee: Canon Inc
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Filing: 1999-03-19
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Granted: —
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Expires: 2019-03-19
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Abstract

Abstract Provided is a black ink capable of mitigating the dependency on image quality of recording media and giving a high quality image stably, which comprises at least one salt selected from the group consisting of (M1) 2 SO 4 , CH 3 COO(M1), Ph_COO(M1), (M1)NO 3 , (M1)Cl, (M1)Br, (M1)I, (M1) 2 SO 3 and (M1) 2 CO 3 , where M1 is an alkali metal, ammonium or organo-ammonium and Ph is a phenyl group, and a self dispersible carbon black.

Inventors

  • 👤 Osumi c/o CANON K.K. Koichi
  • 👤 Hattori c/o CANON K.K. Yoshifumi
  • 👤 Takizawa c/o CANON K.K. Yoshihisa
  • 👤 Mishina c/o CANON K.K. Shinya
  • 👤 Sanada c/o CANON K.K. Mikio
  • 👤 Teraoka c/o CANON K.K. Hisashi
  • 👤 Yakushigawa c/o CANON K.K. Yuko

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-24 22:08
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/38; B; B41; B41J; B41J2/00; B41J2/005; B41J2/01; C09D11/32; C09D11/324; C09D11/40

Claims Analysis

Total Claims: 37
Claim 1
Independent Claim 61 words
An aqueous ink comprising at least one salt selected from the group consisting of (M1) 2 SO 4 , CH 3 COO(M1), Ph-COO(M1), (M1)NO 3 , (M1)Cl, (M1)Br, (M1)I, (M1) 2 SO 3 and (M1) 2 CO 3 , where M1 represents an alkali metal, ammonium or an organo-ammonium and Ph is a phenyl group, and a self dispersible carbon black.
Claim 2
Dependent Claim 29 words
The ink according to claim 1, wherein the salt is contained in an amount of from 0.05 to 10 % by weight relative to the whole weight of ink.
Claim 3
Dependent Claim 29 words
The ink according to claim 2, wherein the salt is contained in an amount of from 0.1 to 5 % by weight relative to the whole weight of ink.
Claim 4
Dependent Claim 26 words
The ink according to claim 1, wherein the carbon black has at least one hydrophilic group bonded directly or via another atomic group to the surface.
Claim 5
Dependent Claim 97 words
The ink according to claim 4, wherein the hydrophilic group is at least one selected from the group consisting of -COO(M2), -SO 3 (M2) 2 , -PO 3 H( M2), PO 3 (M2) 2 , -NH 3 + , -NR 3 + , -SO 3 N + H 3 , -SO 3 N + H 2 COR, and where M2 in the formulae is a hydrogen atom, an alkali metal, ammonium or organo-ammonium and R is an alkyl group having 1 to 12 carbon atoms, a substituted or unsubstituted phenyl group or substituted or unsubstituted naphthyl group.
Claim 6
Dependent Claim 33 words
The ink according to claim 4, wherein the another atomic group is an alkylene group having 1 to 12 carbon atoms, a substituted or unsubstituted phenylene group or substituted or unsubstituted naphthylene group.
Claim 7
Dependent Claim 37 words
The ink according to claim 1, wherein the hydrophilic group is at least one selected from the group consisting of -COO(M2), -SO 3 (M2) 2 and -PO 3 H(M2) 2 where M2 is the same as M1.
Claim 8
Dependent Claim 18 words
The ink according to any one of claims 1 to 7, wherein the ink further comprises a stabilizer.
Claim 9
Dependent Claim 12 words
The ink according to claim 8, wherein the stabilizer is a surfactant.
Claim 10
Dependent Claim 13 words
The ink according to claim 9, wherein the surfactant is an ionic surfactant.
Claim 11
Dependent Claim 11 words
The ink according to claim 8, wherein the stabilizer is dodecylbenzenesulfonate.
Claim 12
Dependent Claim 27 words
The ink according to any one of claims 8 to 11, wherein the stabilizer is contained in an amount of from 0.02 to 0.1 % by weight.
Claim 13
Dependent Claim 22 words
The ink according to any one of claims 1 to 12, wherein the ink has a pH of from 9 to 12.
Claim 14
Dependent Claim 17 words
The ink according to claim 13, wherein the ink has a pH of from 9 to 11.
Claim 15
Dependent Claim 18 words
The ink according to any one of claims 1 to 12, wherein the ink further comprises an antioxidant.
Claim 16
Dependent Claim 21 words
The ink according to claim 15, wherein the antioxidant is contained in an amount of from 0.02 to 10% by weight.
Claim 17
Dependent Claim 25 words
The ink according to claim 15 or 16, wherein the antioxidant is at least one selected from the group consisting of sulfites, ascorbates and hydrogensulfite.
Claim 18
Dependent Claim 20 words
The ink according to any one of claims 1 to 17, wherein the ink further comprises a water-soluble polymer compound.
Claim 19
Dependent Claim 22 words
The ink according to claim 18, wherein the water-soluble polymer compound has a weight average molecular weight of from 1,000 to 5,000.
Claim 20
Dependent Claim 33 words
The ink according to claim 18 or 19, wherein the water-soluble polymer compound is contained in an amount of from 0.02 to 2 % by weight relative to the whole weight of ink.
Claim 21
Dependent Claim 36 words
The ink according to any one of claims 18 to 20, wherein the water-soluble polymer compound is contained in an amount of from 0.1 to 1 % by weight relative to the whole weight of ink.
Claim 22
Dependent Claim 107 words
An ink for forming a predetermined optical density of print image on a recording medium by an ink-jet method, wherein the ink comprises at least one salt selected from the group consisting of (M1) 2 SO 4 , CH 3 COO(M1), Ph-COO(M1), (M1)NO 3 , (M1)Cl, (M1)Br, (M1)I, (M1) 2 SO 3 and (M1) 2 CO 3 , where M1 is an alkali metal, ammonium or organic ammonium and Ph is a phenyl group, and a self dispersible carbon black; and wherein a concentration of the carbon black is concentration that the predetermined optical density of image cannot be obtained in case that no salt is contained.
Claim 23
Dependent Claim 24 words
The ink according to any one of claims 1 to 22, wherein Ka value measured by the Bristow method is not more than 1.5.
Claim 24
Dependent Claim 24 words
The ink according to claims 23, wherein the Ka value measured by the Bristow method is within a range of from 0.2 to 1.5.
Claim 25
Dependent Claim 45 words
An ink set comprising a combination of an aqueous ink comprising at least one coloring material selected from coloring materials for cyan, for magenta, for yellow, for red, for green and for blue and the ink according to any one of claims 1 to 24.
Claim 26
Dependent Claim 19 words
The ink set according to claim 25, wherein the coloring material is an acid dye or a direct dye.
Claim 27
Dependent Claim 14 words
The ink set according to claim 25, wherein the coloring material is a pigment.
Claim 28
Dependent Claim 19 words
An ink cartridge comprising an ink tank containing the ink according to any one of claims 1 to 25.
Claim 29
Dependent Claim 28 words
A recording unit equipped with an ink container containing an ink according to any one of claims 1 to 25; and a head section for ejecting the ink.
Claim 30
Dependent Claim 34 words
An image recording apparatus comprising: an ink cartridge according to claim 28, a recording head for ejecting the ink; and supply means for supplying the ink from the ink cartridge to the recording head.
Claim 31
Dependent Claim 12 words
An image recording apparatus comprising a recording unit according to claim 29.
Claim 32
Dependent Claim 66 words
An image recording apparatus comprising an ink container holding an aqueous ink comprising at least one coloring material selected from coloring materials for cyan, for magenta, for yellow, for red, for green and for blue, an ink container holding an aqueous ink according to any one of claims 1 to 24; and a head section for respectively ejecting the inks stored in individual ink storing sections.
Claim 33
Dependent Claim 91 words
An image recording apparatus comprising an ink cartridge equipped with an ink container holding an aqueous ink comprising at least one coloring material selected from coloring materials for cyan, for magenta, for yellow, for red, for green and for blue; an ink cartridge equipped with an ink container holding an aqueous ink according to any one of claims 1 to 24; a head section for respectively ejecting the ink held in individual ink containers; and supply means for supplying the ink from the respective ink cartridges to the respective head sections.
Claim 34
Dependent Claim 35 words
An image recording method for ejecting an ink according to any one of claims 1 to 24 toward a recording medium surface and depositing the ink to the surface for the recording of an image.
Claim 35
Dependent Claim 17 words
An image recording method according to claim 31, wherein energy for ejecting the ink is thermal energy.
Claim 36
Dependent Claim 17 words
An image recording method according to claim 31, wherein energy for ejecting the ink is mechanical energy.
Claim 37
Dependent Claim 80 words
A color image forming method comprising the steps of: ejecting a first aqueous ink comprising at least one coloring material selected from coloring materials for cyan, for magenta, for yellow, for red, for green and for blue toward the surface of a recording medium to deposit the ink to the surface; and ejecting a second ink as set forth in any one of claims 1 to 24 toward the surface of a recording medium and depositing it to the surface.

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