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EP0926192A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Rubber blend for tire tread compounds

Assignee: Goodyear Tire and Rubber Co
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Filing: 1998-12-11
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Granted: —
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Expires: 2018-12-11
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Abstract

Abstract This invention relates to a rubber blend that is easily processable and that can be beneficially used in tire tread rubber compositions. This blend offers particular advantages in cases where silica is used as a filler in the blend. This is because it is possible to attain a given level of modulus while employing a much lower level of silica coupling agent. The blends of this invention can also be easily mixed while utilizing a mixing cycle of reduced duration. These rubber blends also offer excellent tire performance characteristics such as good traction, treadwear and rolling resistance. This invention more specifically discloses a rubber blend which is particularly suitable for utilization in making tire tread compounds which is comprised of: (1) from about 1 phr to about 70 phr of a vinylpyridine containing rubbery polymer, wherein said vinylpyridine containing rubbery polymer contains from about 0.5 weight percent to about 15 weight percent vinylpyridine and wherein said vinylpyridine containing rubbery polymer has a Mooney ML 1+4 viscosity of less than about 25, (2) from about 30 phr to about 99 phr of a styrene-butadiene rubber, wherein said styrene-butadiene rubber has a Mooney ML 1+4 viscosity which is within the range of about 40 to about 150, (3) a silica filler and (4) a silica coupling agent.

Inventors

  • 👤 Howard Allen Colvin
  • 👤 Michael Leslie Senyek
  • 👤 Shingo Futamura

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 01:05
CPC Classifications
C; C08; C08L; C08L9/00; B; B60; B60C; B60C1/00; B60C1/0016; C08K; C08K3/00; C08K3/34; C08K3/36; C08K5/00; C08K5/54; C08K5/541; C08K5/5415; C08L9/06; Y; Y02; Y02T; Y02T10/00; Y02T10/80; Y02T10/86

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 118 words
A rubber blend which is particularly suitable for utilization in making tire tread compounds which is characterized by being comprised of: (1) from 1 phr to 70 phr of a vinylpyridine containing rubbery polymer, wherein said vinylpyridine containing rubbery polymer contains from 0.5 weight percent to 15 weight percent vinylpyridine and wherein said vinylpyridine containing rubbery polymer has a Mooney ML 1+4 viscosity of less than 25, (2) from 30 phr to 99 phr of an additional rubber selected from the group consisting of styrene-butadiene rubber and polybutadiene rubber, wherein said additional rubber has a Mooney ML 1+4 viscosity which is within the range of 40 to 150, (3) a silica filler and (4) a silica coupling agent.
Claim 2
Dependent Claim 36 words
A rubber blend as specified in claim 1 characterized in that the additional rubber is a styrene-butadiene rubber having a bound styrene content which is within the range of 10 weight percent to 35 weight percent.
Claim 3
Dependent Claim 84 words
A rubber blend as specified in claim 1 or 2 characterized in that from 5 phr to 55 phr of the vinylpyridine containing rubbery polymer and from 45 phr to 95 phr of the styrene-butadiene rubber is present in said rubber blend; characterized in that the vinylpyridine containing rubbery polymer contains from 1 weight percent to 12 weight percent vinylpyridine; and characterized in that said vinylpyridine containing rubbery polymer has a Mooney ML 1+4 viscosity which is within the range of 8 to 23.
Claim 4
Dependent Claim 109 words
A rubber blend as specified in claim 1, 2 or 3 characterized in that the styrene-butadiene rubber has a Mooney ML 1+4 viscosity which is within the range of 50 to 130; characterized in that the silica filler is present in an amount which is within the range of 10 phr to 250 phr; characterized in that the silica coupling agent is present in an amount which is within the range of 0.01 to 1 parts by weight per part by weight of the silica present in the blend; and characterized in that the silica has a dibutylphthalate absorption value which is within the range of 100 to 400.
Claim 5
Dependent Claim 23 words
A tire which is characterized by including a tread which is comprised of the rubber blend specified in any of the preceding claims.
Claim 6
Dependent Claim 91 words
A rubber compound which is particularly suitable for utilization in making tire treads, said rubber compound being characterized by being comprised of: (1) a vinylpyridine containing rubbery polymer which is comprised of repeat units which are derived from 48 to 99.75 weight percent 1,3-butadiene, from 0.25 weight percent to 7 weight percent vinylpyridine and up to 45 weight percent styrene, wherein said vinylpyridine containing rubbery polymer has a Mooney ML 1+4 viscosity which is within the range of 35 to 150, (2) a silica filler and (3) a silica coupling agent.
Claim 7
Dependent Claim 130 words
A rubber compound as specified in claim 6 characterized in that the vinylpyridine containing rubbery polymer is comprised of repeat units which are derived from 48 to 99.75 weight percent 1,3-butadiene, from 0.5 weight percent to 5 weight percent vinylpyridine and from 15 weight percent to 30 weight percent styrene; characterized in that the vinylpyridine containing rubbery polymer has a Mooney ML 1+4 viscosity which is within the range of 40 to 100; and characterized in that silica filler is present in an amount which is within the range of 10 phr to 250 phr and wherein the silica coupling agent is present in an amount which is within the range of 0.01 to 1 parts by weight per part by weight of the silica present in the rubber compound.
Claim 8
Dependent Claim 95 words
A rubber compound as specified in claim 6 or 7 characterized in that the vinylpyridine containing rubbery polymer is comprised of repeat units which are derived from 60 to 84.5 weight percent 1,3-butadiene, from 1 weight percent to 3 weight percent vinylpyridine and from 20 weight percent to 25 weight percent styrene; characterized in that the vinylpyridine containing rubbery polymer has a Mooney ML 1+4 viscosity which is within the range of 45 to 60; and characterized in that the silica has a dibutylphthalate absorption value which is within the range of 100 to 400.
Claim 9
Dependent Claim 67 words
A rubber compound as specified in claim 6, 7 or 8 characterized in that silica filler is present in an amount which is within the range of 15 phr to 80 phr and wherein the silica coupling agent is present in an amount which is within the range of 0.02 to 0.04 parts by weight per part by weight of the silica present in the rubber compound.
Claim 10
Dependent Claim 48 words
A rubber compound as specified in claim 6, 7, 8 or 9 characterized in that the silica coupling agent is present in an amount which is within the range of 0.05 to 0.25 parts by weight per part by weight of the silica present in the rubber compound.

References Cited (Backward Citations)

WO1996030444A1 Cited
EP0819731A1 Cited
WO1997009378A1 Cited
EP0849321A1 Cited

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