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Optical semiconductor element and fabricating method therefor

Assignee: Japan Science and Technology Agency
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Filing: 1998-03-06
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Granted: —
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Expires: 2018-03-06
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Abstract

Abstract A ZnO thin film is fabricated on the c-surface of a sapphire substrate through use of a laser molecular beam epitaxy (MBE) method―which is effective for epitaxial growth of an oxide thin film through control at an atomic level. The thus-formed ZnO thin film has a considerably high crystallinity; the half width of an X-ray rocking curve was 0.06°. The thin film is of an n-type and has a carrier density of 4 x 10 17 /cm 3 . The thin film fabricated in a state in which oxygen partial pressure is held constant at 10 -6 Torr has a structure in which hexagon-shaped nanocrystals of uniform size are close-packed, reflecting the crystal behavior of a wurtzite type. Since in each nanocrystal there is observed a spiral structure formed by steps of a unit cell height (0.5 nm), the nanocrystals are considered to grow in a thermodynamically equilibrated state. The lateral size of the nanocrystal can be controlled within the range of approximately 50 to 250 nm. A II-oxide optical semiconductor element utilizes a zinc oxide thin film containing magnesium or cadmium in a solid-solution state. Through addition of magnesium or cadmium, the band gap of zinc oxide can be controlled within the range of 3 to 4 eV.

Inventors

  • 👤 Masashi Kawasaki
  • 👤 Hideomi Koinuma
  • 👤 Akira Ohtomo
  • 👤 Yusaburo Segawa
  • 👤 Takashi Yasuda

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-06 17:24
CPC Classifications
H; H10; H10H; H10H20/00; H10H20/80; H10H20/81; H10H20/822; H10H20/823; H01; H01S; H01S5/00; H01S5/30; H01S5/32; H01S5/327; H10H20/01; H10H20/011; H10H20/012; H10H20/0125; H01S2304/00; H01S2304/02; H01S5/02; H01S5/0206; H01S5/0213; H01S5/04; H01S5/041; H01S5/323; H01S5/32308; H10H20/85; H10H20/851

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 18 words
An optical semiconductor element in which a thin film containing ZnO is used as a light emitting layer.
Claim 2
Dependent Claim 30 words
An optical semiconductor element according to Claim 1, wherein grain boundaries existing in the thin film are utilized as resonators to thereby enable laser oscillation by exciton or electron-hole plasma.
Claim 3
Dependent Claim 22 words
An optical semiconductor element according to Claim 1 or 2, wherein the thin film is a thin film of hexagonal ZnO nanocrystals.
Claim 4
Dependent Claim 28 words
An optical semiconductor element according to Claim 3, wherein the thin film of hexagonal ZnO nanocrystals is formed by use of a laser molecular beam epitaxy (MBE) method.
Claim 5
Dependent Claim 41 words
An optical semiconductor element according to Claim 1, further comprising a fluorescence layer that is excited by ultraviolet or blue light emitted from the light emitting layer to generate light, thereby enabling visible light emission usable for color display and illumination.
Claim 6
Independent Claim 35 words
A method of fabricating an optical semiconductor element in which a ZnO-containing thin film that serves as a light emitting layer is formed on a substrate of a sapphire c-surface through laser molecular beam epitaxy.
Claim 7
Independent Claim 43 words
A method of fabricating an optical semiconductor element, wherein formation of a ZnO-containing thin film on a substrate of a sapphire c-surface is carried out by two separate steps of forming nuclei which determine size and density of nanocrystals, and growing the nuclei.
Claim 8
Dependent Claim 24 words
A II-oxide optical semiconductor element which comprises a zinc oxide thin film containing Mg or Cd in a solid solution or mixed phase state.
Claim 9
Dependent Claim 38 words
A II-oxide optical semiconductor element according to Claim 8, which utilizes modulation of the band of the zinc oxide thin film resulting from the presence of the Mg or Cd in a solid solution or mixed phase state.
Claim 10
Dependent Claim 40 words
A II-oxide optical semiconductor element according to Claim 8 or 9, further comprising a fluorescence layer that is excited by ultraviolet or blue light emitted from the light emitting layer to generate visible light, thereby enabling color display or illumination.
Claim 11
Dependent Claim 55 words
A II-oxide optical semiconductor element according to Claim 8 or 9, which has a double heterostructure in which the zinc oxide thin film serving as a light emitting layer is sandwiched between zinc oxide thin films each containing Mg or Cd in a solid solution state and serving as a carrier confinement and clad layer.
Claim 12
Independent Claim 35 words
A method of fabricating a II-oxide optical semiconductor element in which a zinc oxide thin film containing Mg or Cd in a solid solution state is formed on a substrate through laser molecular beam epitaxy.
Claim 13
Dependent Claim 28 words
An optical semiconductor element in which a thin film of AlCuO 2 is used as an intermediate layer disposed between a p-type zinc oxide layer and an electrode.

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