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EP0837497A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method for etching transistor gates using a hardmask

Assignee: Applied Materials Inc
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Filing: 1997-09-25
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Granted: —
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Expires: 2017-09-25
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Abstract

Abstract An etchant composition of nitrogen trifluoride and chlorine, preferably also including a passivation material such as hydrogen bromide, etches tungsten silicide-polysilicon gate layers with high selectivity to a thin underlying silicon oxide gate oxide layer to form straight wall, perpendicular profiles with low microloading and excellent profile control.

Inventors

  • 👤 Ajay Kumar
  • 👤 Jeffrey Chinn
  • 👤 Shashank C. Deshmukh
  • 👤 Weinan Jiang
  • 👤 Rolf Adolf Guenter
  • 👤 Bruce Minaee
  • 👤 Mark Wiltse

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 09:32
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 45 words
An etch composition for etching transistor gates on a silicon oxide layer comprising a layer of tungsten silicide over a layer of polysilicon adjacent to said silicon oxide layer, using a silicon oxide hardmask, the etch composition comprising a mixture of nitrogen trifluoride and chlorine.
Claim 2
Dependent Claim 21 words
An etch composition according to claim 1 additionally including one or more of hydrogen bromide, nitrogen, oxygen and a carrier gas.
Claim 3
Dependent Claim 29 words
An etch composition according to claim 1 or claim 2 comprising from 75 to 85% by volume of chlorine and from 15 to 25% by volume of nitrogen trifluoride.
Claim 4
Dependent Claim 36 words
An etch composition according to claim 1 or claim 2 comprising from 75% to 80% by volume of chlorine, 10 to 15% by volume of nitrogen trifluoride and 5 to 10% by volume of hydrogen bromide.
Claim 5
Independent Claim 48 words
A method of etching transistor gates comprising sequential layers of gate oxide, polysilicon and tungsten silicide on a substrate and using a patterned silicon oxide layer as a hardmask, the method comprising etching the tungsten silicide and polysilicon layers with an etchant composition including nitrogen trifluoride and chlorine.
Claim 6
Dependent Claim 29 words
A method according to claim 5, wherein the etchant composition comprises from 75% to 85% by volume of chlorine and from 15 to 25% by volume of nitrogen trifluoride.
Claim 7
Dependent Claim 17 words
A method according to claim 5 or claim 6, wherein said etchant composition further includes hydrogen bromide.
Claim 8
Dependent Claim 36 words
A method according to claim 7, wherein the etchant composition comprises from 75% to 80 by volume of chlorine, 10 to 15% by volume of nitrogen trifluoride and 5 to 10% by volume of hydrogen bromide.
Claim 9
Dependent Claim 42 words
A method according to any one of claim 6 to 8, wherein said tungsten silicide layer is about 1500 angstroms thick, said polysilicon layer is about 1000 angstroms thick and said gate oxide layer is from about 90 to 100 angstroms thick.
Claim 10
Independent Claim 23 words
A method according to any one of claims 6 to 9, wherein the temperature of etching is chosen to obtain the desired profile.

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