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EP0824268A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method of fabricating a gate oxide layer

Assignee: Texas Instruments Inc
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Filing: 1997-08-11
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Granted: —
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Expires: 2017-08-11
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Abstract

Abstract A method of providing a MOSFET having improved gate oxide diffusion barrier properties, which comprises providing a partially fabricated MOSFET having an exposed gate oxide surface. During MOSFET fabrication, the surface of the exposed gate oxide is converted to an oxynitride by applying one or both of ions or free radicals of nitrogen to the exposed gate oxide surface. Fabrication of the MOSFET is then completed in standard manner.

Inventors

  • 👤 Thomas C. Holloway

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:09
CPC Classifications
H; H10; H10D; H10D64/00; H10D64/01; H10D64/013; H10D64/01302; H10D64/01332; H10D64/01336; H10D64/01344; H10D64/01348; H10D64/60; H10D64/66; H10D64/68; H10D64/693

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 63 words
A method of providing a MOSFET having improved gate oxide diffusion barrier properties, comprising the steps of: (a) providing a partially fabricated MOSFET having an exposed gate oxide surface; (b) converting the surface of said exposed gate oxide to an oxynitride by applying one or both of ions or free radicals of nitrogen to said surface; and (c) completing fabrication of said MOSFET.
Claim 2
Independent Claim 68 words
A method of providing a MOSFET having improved gate oxide diffusion barrier properties, comprising the steps of: (a) providing a partially fabricated MOSFET having an exposed gate oxide surface; (b) converting the surface of said exposed gate oxide to an oxynitride by a low energy implant of nitrogen into said exposed surface of from about 50 eV to about 1000 eV; and (c) completing fabrication of said MOSFET.
Claim 3
Dependent Claim 16 words
The method of Claim 2, wherein said converting step comprises performing a reactive ion etch implant.
Claim 4
Independent Claim 81 words
A method of fabricating a gate oxide for a MOSFET having a diffusion barrier thereon, comprising the steps of: (a) providing a partially fabricated MOSFET semiconductor device having a layer of semiconductor material and an exposed gate oxide on said layer of semiconductor material forming an interface with said semiconductor layer; and (b) subjecting said exposed surface to at least one of free radicals or ions of nitrogen to form an oxynitride region at the exposed surface of said gate oxide.
Claim 5
Dependent Claim 20 words
The method of Claim 4, further comprising forming said oxynitride spaced from said interface by at least one atomic monolayer.
Claim 6
Dependent Claim 60 words
The method of Claim 4 or Claim 5, wherein said step of subjecting said exposed surface to free radicals comprises heating said partially fabricated MOSFET semiconductor device to a temperature in the range of from about 27°C to about 800°C and generating and applying to said exposed gate oxide said free radicals by providing nitrogen gas in a microwave plasma.
Claim 7
Dependent Claim 23 words
The method of Claim 6, wherein said heating step comprises heating said partially fabricated MOSFET semiconductor device to a temperature of about 650°C.
Claim 8
Independent Claim 42 words
The method of any of Claims 4 to 7, further comprising forming said oxynitride region to a depth approaching between zero and about 90 percent of the distance from the surface of the exposed surface of the oxynitride layer to said interface.
Claim 9
Dependent Claim 67 words
The method of Claim 4, Claim 5 or Claim 8 wherein said step of subjecting said exposed surface to ions comprises heating said partially fabricated MOSFET semiconductor device to a temperature of about 400°C, providing a parallel plate reactor with RF power capacitively coupled to said heated partially fabricated MOSFET semiconductor device in the presence of N 2 gas and causing said reactor to provide said ions.
Claim 10
Dependent Claim 44 words
The method of Claim 9, further comprising performing said heating step at a pressure of said N 2 gas and RF power set to obtain about a -300 volt DC bias at said device to provide nitrogen ion bombardment of the exposed oxide layer.
Claim 11
Independent Claim 37 words
The method of any of Claims 4 to 10, further comprising subjecting said exposed surface to both of free radicals or ions of nitrogen to form an oxynitride region at the exposed surface of said gate oxide.

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