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Non-aqueous electrolyte and lithium secondary battery

Assignee: Sumitomo Chemical Co Ltd
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Filing: 1996-07-24
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Granted: —
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Expires: 2016-07-24
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Abstract

Abstract A non-aqueous electrolyte is provided comprising a non-aqueous solvent and a lithium salt, said non-aqueous solvent is containing a mixture of a halogen-substituted ether compound represented by the general formula [I]: R 1 -O-R 2 [I] (wherein R 1 is an alkyl or halogen-substituted alkyl group having 2 or less carbon atoms and R 2 is a halogen-substituted alkyl group having 2 to 10 carbon atoms) and at least one sort of another compound, and said solvent obtained by adding the other compound to the halogen-substituted ether compound is capable of dissolving the lithium salt in an amount of not less than 0.5 mol/l, and a lithium secondary battery comprising a cathode that can be doped/undoped with lithium ions, an anode of a lithium metal or alloy or a material that can be doped/undoped with lithium ions and the non-aqueous electrolyte described above. A lithium secondary battery using the non-aqueous electrolyte above is superior in cycle life, for repeating charging/discharging and low-temperature capacity, particularly superior in high-rate capacity, and causes little deterioration of high-rate capacity due to cycles.

Inventors

  • 👤 Taketsugu Yamamoto
  • 👤 Hitoshi Miura

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 20:47
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/14; H01M6/16; H01M6/162; H01M6/164; H01M10/00; H01M10/20; H01M10/22; H01M10/05; H01M10/056; H01M10/0564; H01M10/0566; H01M10/0569; H01M2300/00; H01M2300/0017; H01M2300/0025; H01M2300/0028; H01M2300/0034; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 102 words
A non-aqueous electrolyte comprising a non-aqueous solvent and a lithium salt, said non-aqueous solvent is containing a mixture of a halogen-substituted ether compound represented by the general formula [I]: R 1 -O-R 2 [I] (wherein R 1 is an alkyl or halogen-substituted alkyl group having 2 or less carbon atoms and R 2 is a halogen-substituted alkyl group having 2 to 10 carbon atoms) and at least one sort of another compound, and said solvent obtainable by combining the other compound and the halogen-substituted ether compound is capable of dissolving the lithium salt in an amount of not less than 0.5 mol/l.
Claim 2
Dependent Claim 24 words
A non-aqueous electrolyte according to Claim 1, wherein R 1 of the halogen-substituted ether compound in the formula is methyl, fluoromethyl, difluoromethyl or trifluoromethyl.
Claim 3
Dependent Claim 26 words
A non-aqueous electrolyte according to Claim 1 or 2, wherein R 2 in the formula is a halogen-substituted alkyl group having 3 to 5 carbon atoms.
Claim 4
Dependent Claim 24 words
A non-aqueous electrolyte according to Claim 3, wherein R 2 in the formula is a fluorine-substituted alkyl group having 3 to 5 carbon atoms.
Claim 5
Dependent Claim 25 words
A non-aqueous electrolyte according to any one of Claims 1 to 4, wherein the compound coined with the halogen-substituted ether compound is an acyclic carbonate.
Claim 6
Dependent Claim 32 words
A non-aqueous electrolyte according to Claim 5, wherein the acyclic carbonate is dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, methyl propyl carbonate, isopropyl methyl carbonate, ethyl propyl carbonate or isobutyl methyl carbonate.
Claim 7
Dependent Claim 20 words
A non-aqueous electrolyte according to any one of Claims 1 to 6, wherein the non-aqueous solvent contains a cyclic carbonate.
Claim 8
Dependent Claim 25 words
A non-aqueous electrolyte according to Claim 7, wherein the content of the cyclic carbonate in the non-aqueous solvent is 50 % by volume or less.
Claim 9
Dependent Claim 25 words
A non-aqueous electrolyte according to Claim 8, wherein the content of the cyclic carbonate in the non-aqueous solvent is 30 % by volume or less.
Claim 10
Dependent Claim 31 words
A non-aqueous electrolyte according to claim 7, wherein the cyclic carbonate is ethylene carbonate (1,3-dioxolane-2-one), vinylene carbonate (1,3-dioxol-2-one), propylene carbonate (4-methyl-1,3-dioxolane-2-one), 1,2-butylene carbonate (4-ethyl-1,3-dioxolane-2-one), 2,3-butylene carbonate (4,5-dimethyl-1,3-dioxolane-2-one) or isobutylene carbonate (4,4-dimethyl-1,3-dioxolane-2-one).
Claim 11
Dependent Claim 45 words
A lithium secondary battery comprising a cathode that can be doped/undoped with lithium ions, an anode of a lithium metal or alloy or a material that can be doped/undoped with lithium ions, and a non-aqueous electrolyte according to any one of Claims 1 to 10.
Claim 12
Dependent Claim 44 words
A lithium secondary battery according to claim 11, wherein the anode of the material that can be doped/undoped with lithium ions, contains as a single ingredient or a main ingredient at least one carbonaceous material selected from natural or artificial graphite, and coke material
Claim 13
Dependent Claim 42 words
A lithium secondary battery according to claim 11 or 12, wherein the cathode comprises a lithiated metal dioxide which contains at least one sort of lithiated transition metal dioxide wherein the transition metal is selected from vanadium, manganese, iron, cobalt and nickel.
Claim 14
Dependent Claim 29 words
A lithium secondary battery according to claim 13 or 16, wherein the cathode comprises a laminar lithiated metal dioxide which contains as a main ingredient a lithiated nickel dioxide.
Claim 15
Dependent Claim 38 words
A lithium secondary battery according to any one of claim 11 to 14, wherein the anode contains a polymer having a carbonate structure represented by the genaral formula [II] and number average molecular weight of 300 or more

References Cited (Backward Citations)

JPS6161369A Cited
JPS6229070A Cited
JPH01117838A Cited
JPH02207464A Cited
EP0599534A1 Cited
EP0634805A1 Cited

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