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Method for processing Black-and-white silver halide photographic light-sensitive materials

Assignee: Konica Minolta Inc
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Filing: 1994-01-18
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Granted: —
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Expires: 2014-01-18
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Abstract

Abstract A process for processing a black-and-white silver halide photographic light-sensitive material is disclosed, the material comprising a photographic component layer containing a hydrazine compound, and the process comprising the step of exposing the light-sensitive material, and developing the exposed material with developer having a pH of not more than 10.7, the developer being prepared from a solid developing composition and the developer being replenished with developer replenisher in an amount of not more than 250 cc per m² of the light-sensitive material to be developed.

Inventors

  • 👤 Akira Shimizu
  • 👤 Shoji Nishio
  • 👤 Takeshi Sanpei
  • 👤 Hiroyuki Ushiroyama

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 19:58
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/31; G03C1/00; G03C1/005; G03C1/06; G03C1/061; G03C5/30; G03C5/264; G03C5/265

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 99 words
A process for processing a black-and-white silver halide photographic light-sensitive material comprising a support and provided thereon, a photographic component layer comprising a silver halide emulsion layer, said photographic component layer containing a hydrazine compound, comprising the step of: exposing the light-sensitive material; developing the exposed material with developer having a pH of not more than 10.7, said developer being prepared from a solid developing composition and said developer being replenished with developer replenisher in an amount of not more than 250 cc per m² of the light-sensitive material to be developed; and fixing the developed material with fixer.
Claim 2
Dependent Claim 30 words
The process of claim 1, wherein said developer is replenished with developer replenisher in an amount of 60 to 250 cc per m² of the light-sensitive material to be developed.
Claim 3
Dependent Claim 30 words
The process of claim 1, wherein said developer is replenished with developer replenisher in an amount of 100 to 200 cc per m² of the light-sensitive material to be developed.
Claim 4
Dependent Claim 20 words
The process of claim 1, 2 or 3, wherein said developing is carried out in not more than 18 seconds.
Claim 5
Dependent Claim 18 words
The process of claims 1 to 3, wherein said developing is carried out in 7 to 18 seconds.
Claim 6
Dependent Claim 33 words
The process of claims 1 to 5, wherein said solid developing composition contains an organic solvent in an amount of not more than 100 % by weight based on the total solid content.
Claim 7
Dependent Claim 28 words
The process of claims 1 to 6, wherein said photographic component layer contains gelatin in an amount of not more than 3.0 g per m² of the material.
Claim 8
Dependent Claim 131 words
The process of claims 1 to 7 , wherein the hydrazine compound is a compound represented by the following Formula (H): wherein A represents an aryl group or a heterocyclic group containing a sulfur atom or an oxygen atom; G represents a group, a sulfonyl group, a sulfoxy group, a group or an iminomethylene group; wherein n is an integer of 1 or 2; A¹ and A² represent a hydrogen atom or when one of A¹ and A² is a hydrogen atom, the other is an alkylsulfonyl group or an acyl group; R represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group, an oxycarbonyl group or -O-R₂ wherein R₂ represents an alkyl group or a saturated heterocyclic group.
Claim 9
Dependent Claim 21 words
The process of claims 1 to 8, wherein said fixing is carried out by fixer prepared from a solid fixing composition.
Claim 10
Dependent Claim 20 words
The process of claim 9, wherein said fixer contains a thiosulfate and has a pH of not less than 3.8.
Claim 11
Dependent Claim 209 words
The process of claim 8, 9 or 10, wherein said hydrazine compound is a compound represented by the following Formula (H-c) or (H-d): wherein A represents an aryl group or a heterocyclic group containing a sulfur atom or an oxygen atom; n is an integer of 1 or 2; R₁₅ and R₁₆ independently represent a substituent; and R₁₇ represents an alkynyl group or a saturated heterocyclic group; wherein, when n is 1, said substituent represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a heterocyclicoxy group or R₁₅ and R₁₆ may form a ring together with a nitrogen atom or when n is 2, said substituent represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a heterocyclicoxy group, provided that at least one of R₁₅ and R₁₆ represents an alkenyl group, an alkynyl group, a saturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a heterocyclicoxy group.
Claim 12
Dependent Claim 34 words
The process of claim 8 or 11, wherein said hydrazine compound is contained in said photographic component layer in an amount of 1 × 10⁻⁶ to 1 × 10⁻¹ mol per mol of silver.
Claim 13
Dependent Claim 17 words
The process of claims 6 to 12, wherein said solid developing composition further contains a granulation aid.
Claim 14
Dependent Claim 16 words
The process of claim 13, wherein said solid developing composition is a tablet or a granule.
Claim 15
Dependent Claim 339 words
A process for processing a black-and-white silver halide photographic light-sensitive material comprising a support and provided thereon, a photographic component layer comprising a silver halide emulsion layer and layers adjacent thereto, said photographic component layer containing a hydrazine compound in an amount of 1 × 10⁻⁶ to 1 × 10⁻¹ mol per mol of silver and gelatin in an amount of not more than 3.0 % by weight, comprising the step of: exposing the light-sensitive material; developing the exposed material with developer having a pH of not more than 10.7 in not more than 18 seconds, said developer being prepared from a solid developing composition containing a granulation aid, and replenished with developer replenisher in an amount of not more than 250 cc per m² of the light-sensitive material to be developed; fixing the developed material with fixer, wherein said hydrazine compound is a compound represented by the following Formula (H-c) or (H-d): wherein A represents an aryl group or a heterocyclic group containing a sulfur atom or an oxygen atom; n is an integer of 1 or 2; R₁₅ and R₁₆ independently represent a substituent; and R₁₇ represents an alkynyl group or a saturated heterocyclic group; wherein, when n is 1, said substituent represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a heterocyclicoxy group or R₁₅ and R₁₆ may form a ring together with a nitrogen atom or when n is 2, said substituent represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a heterocyclicoxy group, provided that at least one of R₁₅ and R₁₆ represents an alkenyl group, an alkynyl group, a saturated heterocyclic group, a hydroxy group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group or a heterocyclicoxy group.

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