Silicone polymer, paste-like composition and water-in-oil type cosmetic composition comprising the same

Claim 2

The silicone polymer according to Claim 1, which is prepared by the addition polymerization of the organohydrogenpolysiloxane represented by formula (2) and the polyoxyalkylene represented by formula (A).

Claim 3

The silicone polymer according to Claim 1, which is prepared by the addition polymerization of the organohydrogenpolysiloxane represented by formula (1) and the organopolysiloxane represented by formula (B).

Claim 4

The silicone polymer according to Claim 1, which is prepared by the addition polymerization of the organohydrogenpolysiloxane represented by formula (1) and the polyoxyalkylene represented by formula (A).

Claim 5

A silicone polymer prepared by the addition polymerization of 100 parts by weight of components comprising, (I) an organohydrogenpolysiloxane represented by the following formula (1), R¹ a R² b H c SiO (4-a-b-c)/2 (1) wherein R¹ represents substituted or unsubstituted alkyl, aryl, or aralkyl group having carbon atoms of 1-18, or a halogenated hydrocarbon group; R² represents a group -C n H 2n O(C₂H₄O) d (C₃H₆O) e R³, wherein R³ is a hydrogen, a saturated aliphatic hydrocarbon group having 1-10 carbon atoms, or a group -(CO)-R⁵ (wherein R⁵ is a saturated aliphatic hydrocarbon group having 1-5 carbon atoms), d is an integer of 2-200, e is an integer of 0-200, provided that d + e is 2-200, and n is 2-6; a is a value satisfying inequality 1.0 ≦ a ≦ 2.5; b is a value satisfying inequality 0.001 ≦ b ≦ 1.0; and c is a value satisfying inequality 0.001 ≦ c ≦ 1.0; or an organohydrogenpolysiloxane represented by the following formula (2), R¹ f H g SiO (4-f-g)/2 (2) wherein R¹ is the same as defined in formula (1), f is a value satisfying inequality 1.0 ≦ f ≦ 3.0, and g is a value satisfying inequality 0.001 ≦ g ≦ 1.5; or a mixture of said organohydrogenpolysiloxanes of formulas (1) and (2), and (II) a polyoxyalkylene represented by the following formula (A), C m H 2m-1 O(C₂H₄O) h (C₃H₆O) i C m H 2m-1 (A) wherein h is an integer of 2-200, i is an integer of 0-200, provided that h + i is 2-200, and m is 2-6, or an organopolysiloxane represented by the following formula (B), R¹ j R⁴ k SiO (4-j-k)/2 (B) wherein R¹ is the same as defined in formula (1), R⁴ is a monovalent hydrocarbon group having an aliphatic unsaturated bond at the terminal thereof and containing 2-10 carbon atoms, j is a value satisfying inequality 1.0 ≦ j ≦ 3.0, and k is a value satisfying inequality 0.001 ≦ k ≦ 1.5, or a mixture of the polyoxyalkylene of formula (A) and the organopolysiloxane of formula (B), wherein at least one organohydrogenpolysiloxane of formula (1) or at least one polyoxyalkylene of formula (A) are contained as an essential component of the addition polymerization, in the presence of 3-200 parts by weight of a low viscosity silicone oil having a viscosity of 100 cS or lower at 25°C or a polyhydric alcohol, or both.

Claim 6

The silicone polymer according to Claim 5, which is prepared by the addition polymerization of the organohydrogenpolysiloxane represented by formula (2) and the polyoxyalkylene represented by formula (A).

Claim 7

The silicone polymer according to Claim 5, which is prepared by the addition polymerization of the organohydrogenpolysiloxane represented by formula (1) and the organopolysiloxane by formula (B).

Claim 8

The silicone polymer according to Claim 5, which is prepared by the addition polymerization of the organohydrogenpolysiloxane represented by formula (1) and the polyoxyalkylene represented by formula (A).

Claim 9

A paste-like silicone composition which can disperse water and is prepared by kneading 100 parts by weight of the silicone polymer of Claim 1 or Claim 5 and 5-1,000 parts by weight of a silicone oil under a shearing force.

Claim 10

A water-in-oil type cosmetic composition comprising the paste-like silicone composition of Claim 9 as an oil phase component and at least one water phase component.

Claim 11

A water-in-oil type cosmetic composition comprising (i) the paste-like silicone composition of Claim 9 and (ii) silicic acid anhydride or hydrophobic silica, or both, as oil phase components, and at least one water phase component.

Claim 12

A water-in-oil type cosmetic composition comprising the paste-like silicone composition of Claim 9 as an oil phase component and one or more components selected from the group consisting of saccharides, sugar alcohols, and inorganic salts, as water phase components.

Claim 13

A water-in-oil type emulsion cosmetic composition comprising the paste-like silicone composition of Claim 9 as an oil phase component, at least one water phase component, and a polyoxyalkylene-modified organopolysiloxane type surface active agent.

Claim 14

A water-in-oil type cosmetic composition comprising the paste-like silicone composition of Claim 9 as an oil phase component, at least one water phase component, and a cosmetic powder.

Claim 15

A water-in-oil type make-up cosmetic composition comprising: (a) a semisolid oil or a liquid oil, or both, (b) a solid oil or an oil gelling agent, or both, (c) the paste-like silicone composition of Claim 9, (d) at least one water phase component, and (e) a cosmetic powder.