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Polyether-containing electrochemichromic solutions

Assignee: Magna Donnelly Corp
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Filing: 1991-11-07
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Granted: —
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Expires: 2011-11-07
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Abstract

Abstract Electrochemichromic solutions and devices are disclosed which have 0.5 percent by volume of at least one polyether which is soluble in the electrochemichromic solution to reduce segregation without unduly affecting leakage current.

Inventors

  • 👤 Desaraju Venkatapanduranga Varaprasad
  • 👤 Niall Richard Lynam
  • 👤 Hamid Reza Habibi
  • 👤 Padma Desaraju

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-28 15:06
CPC Classifications
C; C09; C09K; C09K9/00; C09K9/02; G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/1503; G02F2001/1502; G02F1/1514; G02F2001/15145

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 27 words
An electrochemichromic solution comprising a solvent, a redox chemical pair whose colour can be varied by a variation of an applied voltage (if any) and a polyether.
Claim 2
Dependent Claim 54 words
A solution according to claim 1 comprising a redox chemical pair in solution in the solvent which colours in the presence of an applied voltage and which bleaches to a colourless condition in the absence of an applied voltage, the solvent being thickened by addition of an effective amount of at least one polyether.
Claim 3
Dependent Claim 24 words
A solution according to claim 1 or 2 wherein the polyether has a molecular weight of from 100,000 to 6,000,000 such as to 4,000,000.
Claim 4
Dependent Claim 26 words
A solution according to any of claims 1 to 3 in which the viscosity of the electrochemichromic solution is not greater than 600 centistokes at 25°C.
Claim 5
Dependent Claim 29 words
A solution according to any of claims 1 to 4 in which the polyether comprises polyethylene oxide and/or hydroxypropylcellulose suitably at from 0.5 to 10 percent weight by volume.
Claim 6
Dependent Claim 27 words
A solution according to any of claims 1 to 5 in which the solvent comprises 3-hydroxypropionitrile, 2-acetylbutyrolactone, glutaronitrile, 3,3′-oxydipropio-nitrile, 3-methylsulpholane, 2-methylglutaronitrile, propylene carbonate and/or a mixture thereof.
Claim 7
Dependent Claim 39 words
A solution according to any of claims 1 to 6 in which the redox chemical pair comprises of from 0.025 to 0.05 molar of methylviologen (suitably perchlorate) and/or ethylviologen (suitably hexafluorophosphate) and of from 0.025 to 0.05 molar 5,10-dihydro-5,10-dimethylphenazine.
Claim 8
Dependent Claim 48 words
An electrochemichromic cell comprising at least two spaced apart substrates each having an inwardly facing conductive surface and an electrochemichromic solution locating therebetween, the solution comprising a solvent, a redox chemical pair whose colour can be varied by variation of an applied voltage (if any) and a polyether.
Claim 9
Dependent Claim 21 words
An electrochemichromic cell according to claim 8 wherein the electrochemichromic solution is as claimed in any of claims 1 to 7.
Claim 10
Dependent Claim 24 words
An electrochemichromic cell according to claim 8 or 9 wherein the polyether has a molecular weight in the range of from 100,000 to 6,000,000.
Claim 11
Independent Claim 78 words
A method of reducing segregation without unduly affecting leakage current in an electrochemichromic solution which comprises a solvent, a redox chemical pair in solution in the solvent which colours in the present of an applied voltage and which bleaches to a colourless condition in the absence of an applied voltage, the method comprising introducing into the solvent at least one polyether, such as having a molecular weight of from 100,000 to 4,000,000, which is soluble in the solvent.
Claim 12
Independent Claim 54 words
A method of manufacturing an electrochemichromic cell, the method comprising providing at least two spaced apart substrates each having an inwardly facing conductive surface and locating therebetween an electrochemichromic solution which comprises a solvent, a redox chemical pair whose colour can be varied by variation of an applied voltage (if any) and a polyether.

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