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Heterocyclic disperse dye compounds, their production and their use for dyeing or printing of hydrophobic fibers

Assignee: Sumitomo Chemical Co Ltd
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Filing: 1991-11-08
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Granted: —
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Expires: 2011-11-08
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Abstract

Abstract A heterocyclic compound which is useful for dyeing or printing hydrophobic fiber materials and which has the following formula (I), wherein A 1 , A 2 , A3 and A4 are each hydrogen, halogen, alkyl, alkoxy or alkenyl, X 1 is -O- or the like, R 1 is a methylene or the like, X 2 is a direct linkage or a divalent group of -O-, -S-, -SO-, -S0 2 -, in which R 3 is a hydrogen atom or a C 1 - 4 alkyl group, in which R 3 is as defined above, T and u are each independently hydrogen or a C 1 - 4 alkyl, ℓ is O or an integer of 1 to 3, Q is an unsubstituted or substituted 5-, 6- or 7-membered saturated or unsaturated heterocyclic residue, Y is hydrogen, C 1 - 4 alkyl, a C 1 - 4 alkoxy group or the like.

Inventors

  • 👤 Jun Yamamoto
  • 👤 Junichi Sekihachi
  • 👤 Yosuke Yamamoto
  • 👤 Kazuhiro Machiguchi
  • 👤 Yutaka Kayane

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 21:40
CPC Classifications
C; C07; C07D; C07D493/00; C07D493/02; C07D493/04; C09; C09B; C09B57/00; D; D06; D06P; D06P1/00; D06P1/44; D06P1/64; D06P1/642; D06P1/6426

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 482 words
A heterocyclic compound of the following formula (I), wherein A 1 , A 2 , A3 and A4 are each independently a hydrogen atom, a halogen atom or an unsubstituted or substituted alkyl, alkoxy or alkenyl group, X 1 is -O-or in which R 2 is a hydrogen atom or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl group and R 2 may link to A3 or A4 to form a heterocyclic ring, R 1 is a methylene group or a straight or branched C 2 - 6 alkylene group unsubstituted or substituted by a hydroxy group, a C 1-4 alkoxy group or a C 1 - 4 alkylcarbonyloxy group, X 2 is a direct linkage or a divalent group of -O-, -S-, -SO-, -S0 2 -, in which R 3 is a hydrogen atom or a C 1 - 4 alkyl group, in which R 3 is as defined above, T and u are each independently a hydrogen atom or a C 1 - 4 alkyl group, ℓ is O or an integer of 1 to 3, Q is an unsubstituted or substituted 5-, 6- or 7-membered saturated or unsaturated heterocyclic residue, Y is a hydrogen atom, a C 1 - 4 alkyl group, a C 1 - 4 alkoxy group, a group of the formula (i), in which R 1 , X 2 , T, u, Q and tare as defined above, and X 3 is in which R 4 is a hydrogen atom or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl group and R 4 may link to A 1 or A 2 to form a hetrocyclic ring, provided that the group of the formula (i) as Y is the same as or different from the group of the formula(i) appended to Xi, a group of the formula (ii), in which L 1 and L 2 are each independently a hydrogen atom or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl group and one of L 1 and L 2 may link to A 1 or A 2 to form heterocyclic ring, or a group of the formula (iii), in which L 3 and L 4 are each independently an alkylene group, an alkenylene group or a C 1-4 alkylcarbonyl group, or a group of the formula (iv) in which L 3 and L 4 are as defined above, and Y may link to A 1 or A 2 to form -OCH 2 0-, with a proviso that when X is -O-, Y is (ii) in which L 1 and L 2 are as defined above, (iii) in which L 3 and L 4 are as defined above, (iV) in which L 3 and L 4 are as defined above, or (i) in which X 3 , R i , X 2 , T, u, ℓ and Q are as defined above.
Claim 2
Dependent Claim 482 words
A heterocyclic compound of the following formula (I), wherein A 1 , A 2 , A3 and A4 are each independently a hydrogen atom, a halogen atom or an unsubstituted or substituted alkyl, alkoxy or alkenyl group, X 1 is -O-or in which R 2 is a hydrogen atom or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl group and R 2 may link to A3 or A4 to form a heterocyclic ring, R 1 is a methylene group or a straight or branched C 2 - 6 alkylene group unsubstituted or substituted by a hydroxy group, a C 1-4 alkoxy group or a C 1 - 4 alkylcarbonyloxy group, X 2 is a direct linkage or a divalent group of -O-, -S-, -SO-, -S0 2 -, in which R 3 is a hydrogen atom or a C 1 - 4 alkyl group, in which R 3 is as defined above, T and u are each independently a hydrogen atom or a C 1 - 4 alkyl group, ℓ is O or an integer of 1 to 3, Q is an unsubstituted or substituted 5-, 6- or 7-membered saturated or unsaturated heterocyclic residue, Y is a hydrogen atom, a C 1 - 4 alkyl group, a C 1 - 4 alkoxy group, a group of the formula (i), in which R 1 , X 2 , T, u, Q and tare as defined above, and X 3 is in which R 4 is a hydrogen atom or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl group and R 4 may link to A 1 or A 2 to form a hetrocyclic ring, provided that the group of the formula (i) as Y is the same as or different from the group of the formula(i) appended to Xi, a group of the formula (ii), in which L 1 and L 2 are each independently a hydrogen atom or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or aralkyl group and one of L 1 and L 2 may link to A 1 or A 2 to form heterocyclic ring, or a group of the formula (iii), in which L 3 and L 4 are each independently an alkylene group, an alkenylene group or a C 1-4 alkylcarbonyl group, or a group of the formula (iv) in which L 3 and L 4 are as defined above, and Y may link to A 1 or A 2 to form -OCH 2 0-, with a proviso that when X is -O-, Y is (ii) in which L 1 and L 2 are as defined above, (iii) in which L 3 and L 4 are as defined above, (iV) in which L 3 and L 4 are as defined above, or (i) in which X 3 , R i , X 2 , T, u, ℓ and Q are as defined above.
Claim 3
Dependent Claim 85 words
The compound according to claim 1, wherein Q is a 5-, 6- or 7-membered unsaturated heterocyclic residue unsubstituted or substituted once or twice by a halogen atom, a hydroxy group, a C 1 - 4 alkyl group, a C 1 - 4 alkoxy group, a C 1 - 4 alkylcarbonyl group, a C 1 - 4 alkoxycarbonyl group, a cyano group, a keto group, or a primary, secondary or tertiary amino group unsubstituted or substituted by an alkyl group having 1 to 4 carbon atoms.
Claim 4
Dependent Claim 30 words
The compound according to claim 2, wherein the unsaturated heterocyclic residue is furyl, thienyl, pyrrolyl, pyridyl, pyranyl, thiazolyl, oxazolyl, pyrazolyl, imidazolyl, thiadiazolyl, s-triazinyl, benzofuranyl, benzothienyl, indolyl, benzoxazolyl, benzimidazolyl or benzothiazolyl.
Claim 5
Dependent Claim 85 words
The compound according to claim 1, wherein Q is a 5-, 6- or 7-membered saturated heterocyclic residue unsubstituted or substituted once or twice by a halogen atom, a hydroxy group, a C 1 - 4 alkyl group, a C 1 - 4 alkoxy group, a C 1 - 4 alkylcarbonyl group, a C 1 - 4 alkoxycarbonyl group, a cyano group, a keto group, or a primary, secondary or tertiary amino group unsubstituted or substituted by an alkyl group having 1 to 4 carbon atoms.
Claim 6
Dependent Claim 21 words
The compound according to claim 4, wherein the saturated heterocyclic residue is tetrahydrofuryl, tetrahydrothienyl, tetrahydropyranyl, pyrrolidyl, piperidyl, piperazinyl, morpholinyl or hexahydroazepinyl.
Claim 7
Dependent Claim 80 words
A process for producing the heterocyclic compound according to claim 1, which comprises reacting a tartronic acid compound of the following formula (II)a, wherein A 1 , A 2 and Y are as defined above, with a compound of the following formula (III)a, wherein Q, T, u, X 2 , R i , X 1 , ℓ, A3 and A4 are as defined above, without solvent or in an acidic medium and then oxidizing the reaction product with an oxidant.
Claim 8
Dependent Claim 75 words
A process for producing the heterocyclic compound according to claim 1, which comprises reacting a tartronic acid compound of the following formula (II)b, wherein Q, T, u, ℓ, X 2 , Ri, Xi, A3 and A4 are as defined above, with a compound of the following formula (III)b, wherein Y, A 1 and A 2 are as defined above, without solvent or in an acidic medium and then oxidizing the reaction product with an oxidant.
Claim 9
Dependent Claim 23 words
A process for dyeing or printing hydrophobic fiber materials, which comprises contacting the fiber materials with the heterocyclic compound according to claim 1.

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