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EP0462504A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for coating finely divided material with titania and moisture insensitive zinc sulfide luminescent materials made therefrom

Assignee: Osram Sylvania Inc
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Filing: 1991-06-12
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Granted: —
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Expires: 2011-06-12
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Abstract

Abstract A method for coating finely divided material with titania is disclosed. The method involves the fluidization of the finely divided material (16) in an inert carrier gas containing vaporized titanium isopropoxide. The isothermal fluidized bed (15) is kept at a temperature equal to or below approximately 300°C. The vaporised titanium isopropoxide reacts to form a coating of titania on the surfaces of the particles (16) within the fluidized bed (15). The greatest coating efficiency occurs when the fluidized bed is kept at approximately 300°C for approximately the first 10 minutes of the reaction and thereafter at approximated 250°C. The titania coating process is particularly useful for electroluminescent phosphors such as copper doped zinc sulfide phosphor. The titania coated electroluminescent phosphors are relatively insensitive to moisture. Lamps made from the coated electroluminescent phosphor are also relatively insensitive to moisture.

Inventors

  • 👤 Keith A. Klinedinst

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-01 19:42
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/08; C09K11/58; C09K11/582; C09K11/584; C09K11/02; C09K11/025; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/40; C23C16/405; C23C16/44; C23C16/442; H; H05; H05B; H05B33/00; H05B33/12; H05B33/14

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 124 words
A method for forming a continuous coating of titania on particles of a phosphor powder comprising: a) vaporizing titanium isopropoxide in an inert carrier gas to form a carrier gas containing vaporized titanium isopropoxide; b) passing said carrier gas containing vaporized titanium isopropoxide through particles of a phosphor powder to form a fluidized bed in which the particles of the phosphor powder are suspended in the carrier gas and to envelop the fluidized particles in the carrier gas containing titanium isopropoxide said fluidized bed being maintained at a nearly isothermal condition at a temperature of approximately 300°C or less; c) reacting the vaporized titanium isopropoxide on the particles of the phosphor powder to from a coating of titania of predetermined thickness on the particles.
Claim 2
Dependent Claim 30 words
The method according to claim 1 wherein said fluidized bed is maintained at a temperature of approximately 300°C for approximately the first ten minutes and thereafter maintained at approximately 250°.
Claim 3
Dependent Claim 16 words
The method according to claim 1 wherein said phosphor comprises a copper doped zinc sulfide phosphor.
Claim 4
Dependent Claim 19 words
A particle of a finely divided phosphor having a coating comprising a layer of titania which surrounds the particle.
Claim 5
Dependent Claim 14 words
A particle in accordance with claim 4 wherein the phosphor is an electroluminescent phosphor.
Claim 6
Dependent Claim 55 words
An electroluminescent device comprising: a first transparent electrode and a second electrode; a electroluminescent phosphor layer disposed between said first electrode and second electrode wherein said phosphor layer comprises titania coated zinc sulfide phosphor; and a transparent substrate supporting said first electrode, said first electrode being disposed between said transparent substrate and said phosphor layer.

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