Patent EP0461672A2 successfully refreshed from Google Patents.
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EP0461672A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Image forming apparatus.

Assignee: Canon Inc
•
Filing: 1991-06-14
•
Granted: —
•
Expires: 2011-06-14
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Abstract

Abstract An image forming apparatus comprising an electrostatic latent image bearing member (1) and a developing apparatus (211) for developing an electrostatic latent image. The developing apparatus (211)comprises a developer container (212) in which a developer (5) is held, and a developer-carrying member (1) for carrying thereon the developer and transporting the developer to a developing zone. The developer-carrying member (2) has a surface layer of a resin containing at least conductive fine particles and a solid lubricant, and the surface layer has in its relative load curve (Abbot's load curve) a cutting depth C v of not more than 5 µm when a relative load length t p is 5 %; and the developer (5) contains a toner and a fine powder pretreated with a silicone oil or silicone varnish.

Inventors

  • 👤 Manabu Canon Kabushiki Kaisha Ohno
  • 👤 Yukari Canon Kabushiki Kaisha Ishibashi
  • 👤 Tetsuhito Canon Kabushiki Kaisha Kuwashima
  • 👤 Hiroyuki Canon Kabushiki Kaisha Suematsu

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 16:36
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/097; G03G9/09783; G03G13/00; G03G13/06; G03G13/08; G03G13/09; G03G15/00; G03G15/06; G03G15/08; G03G15/09; G03G15/0921; G03G15/0928; G03G9/0819; G03G9/09; G03G9/0906; G03G9/091

Claims Analysis

Total Claims: 82
Claim 1
Independent Claim 122 words
An image forming apparatus comprising an electrostatic latent image bearing member and a developing apparatus for developing an electrostatic latent image; said developing apparatus comprising a developer container in which a developer is held, and a developer-carrying member for carrying thereon the developer and transporting the developer to a developing zone; said developer-carrying member having a surface layer of a resin containing at least conductive fine particles and a solid lubricant, said surface layer having in its relative load curve (Abbot's load curve) a cutting depth C v of not more than 5 µm when a relative load length t p is 5 %; and said developer containing a toner and a fine powder pretreated with a silicone oil or silicone varnish.
Claim 2
Dependent Claim 27 words
The apparatus according to Claim 1, wherein said surface layer of said developer-carrying member has a cutting depth C v of from 0.5 µm to 5 µm.
Claim 3
Dependent Claim 19 words
The apparatus according to Claim 1, wherein the surface of said developer-carrying member has been subjected to surface polishing.
Claim 4
Dependent Claim 19 words
The apparatus according to Claim 2, wherein the surface of said developer-carrying member has been subjected to surface polishing.
Claim 5
Dependent Claim 30 words
The apparatus according to Claim 1, wherein the surface of said developer-carrying member is controlled by polishing a surface having a cutting depth C v of more than 5 µm.
Claim 6
Dependent Claim 16 words
The apparatus according to Claim 1, wherein the surface of said developer-carrying member contains graphite particles.
Claim 7
Dependent Claim 17 words
The apparatus according to Claim 1, wherein the surface of said developer-carrying member contains conductive carbon particles.
Claim 8
Dependent Claim 20 words
The apparatus according to Claim 1, wherein the surface of said developer-carrying member contains graphite particles and conductive carbon particles.
Claim 9
Dependent Claim 36 words
The apparatus according to Claim 1, wherein said developer-carrying member comprises a developing sleeve having a magnet in its inside, and said developer comprises a magnetic toner and a fine powder pretreated with a silicone oil.
Claim 10
Dependent Claim 23 words
The apparatus according to Claim 9, wherein said developer comprises an insulative magnetic toner and a fine powder pretreated with a silicone oil.
Claim 11
Dependent Claim 24 words
The apparatus according to Claim 1, wherein said surface layer of said developer-carrying member has a thickness of from 0.5 µm to 30 µm.
Claim 12
Dependent Claim 24 words
The apparatus according to Claim 1, wherein said surface layer of said developer-carrying member has a thickness of from 2 µm to 20 µm.
Claim 13
Dependent Claim 24 words
The apparatus according to Claim 1, wherein said solid lubricant comprises graphite particles having a particle diameter of from 0.5 µm to 10 µm.
Claim 14
Dependent Claim 26 words
The apparatus according to Claim 1, wherein said conductive fine particles comprise amorphous carbon particles having a particle diameter of from 5 µm to 100 µm.
Claim 15
Dependent Claim 26 words
The apparatus according to Claim 1, wherein said conductive fine particles comprise amorphous carbon particles having a particle diameter of from 10 µm to 80 µm.
Claim 16
Dependent Claim 26 words
The apparatus according to Claim 1, wherein said conductive fine particles comprise amorphous carbon particles having a particle diameter of from 15 µm to 40 µm.
Claim 17
Dependent Claim 25 words
The apparatus according to Claim 1, wherein said surface layer of said developer-carrying member has a volume resistivity of from 10⁻⁶ Ω·cm to 10⁶ Ω·cm
Claim 18
Dependent Claim 58 words
The apparatus according to Claim 1, wherein said surface layer of said developer-carrying member comprises graphite particles, conductive carbon particles, or a mixture of these, and a resin selected from the group consisting of a phenol resin, a silicone resin, a fluorine resin, a polyether sulfone, a polycarbonate, a polyphenylene oxide, a polyamide and a polystyrene type resin.
Claim 19
Dependent Claim 29 words
The apparatus according to Claim 1, wherein said surface layer of said developer-carrying member comprises graphite particles, conductive carbon particles, or a mixture of these, and a phenol resin.
Claim 20
Dependent Claim 19 words
The apparatus according to Claim 1, wherein said electrostatic latent image bearing member comprises a laminated OPC photosensitive drum.
Claim 21
Dependent Claim 75 words
The apparatus according to Claim 1, wherein said toner contains a binder resin having i) a polymerizable monomer unit contained in an amount of from 2 parts by weight to 30 parts by weight based on the total weight of the resin, the monomer unit having an acid group comprised of a carboxyl group or an acid anhydride thereof, and ii) an acid value of from 1 to 70 as that of the whole resin.
Claim 22
Dependent Claim 24 words
The apparatus according to Claim 1, wherein said toner contains a metal complex compound (A) of an aromatic hydroxycarboxylic acid having a lipophilic group.
Claim 23
Dependent Claim 22 words
The apparatus according to Claim 1, wherein said toner contains a metal complex salt type monoazo dye (B) having a hydrophilic group.
Claim 24
Dependent Claim 37 words
The apparatus according to Claim 1, wherein said toner contains a metal complex compound (A) of an aromatic hydroxycarboxylic acid having a lipophilic group, and a metal complex salt type monoazo dye (B) having a hydrophilic group.
Claim 25
Dependent Claim 272 words
The apparatus according to Claim 22, wherein said metal complex comound (A) has a structure selected from the group consisting of the following formulas (I), (II) and (III). wherein R¹ to R⁴ may be the same or different from each other, and each represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, provided that at least one of R¹ to R⁴ represents said hydrocarbon group; Me represents Cr, Ni, Co, Cu or Zn; and X⁺ represents H⁺, K⁺, Na⁺, NH₄ or Li⁺. wherein R¹ and R² may be the same or different from each other, and each represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; one of a and b is a benzene ring or a cyclohexene ring and the other is absent or selected from the group consisiting of a hydrocarbon group having 4 to 9 carbons, a benzene ring and a cyclohexene ring; Me represents Cr, Ni, Co, Cu or Zn; and X⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺. wherein one of a and b is a benzene ring or a cyclohexene ring and the other is absent or selected from the group consisiting of a hydrocarbon group having 4 to 9 carbons, a benzene ring and a cyclohexene ring; and one of c and d is a benzene ring or a cyclohexene ring and the other is absent or selected from the group consisiting of a hydrocarbon group having 4 to 9 carbons, a benzene ring and a cyclohexene ring; Me represents Cr, Ni, Co, Cu or Zn; and X⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺.
Claim 26
Dependent Claim 125 words
The apparatus according to Claim 23, wherein said metal complex salt type monoazo dye (B) has a structure selected from the group consisting of the following formulas (IV) and (V). wherein at least one of X and Y represent(s) a hydrophilic group, and any other represent(s) a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; Me represents Cr, Ni, Co, Cu, Zn or Fe; and A⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺. wherein at least one of X, Y and Z represent(s) a hydrophilic group, and any others represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; Me represents Cr, Ni, Co, Cu, Zn or Fe; and A⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺.
Claim 27
Dependent Claim 50 words
The apparatus according to Claim 23, wherein said hydrophilic group is a group selected from the group consisting of -SO₃H, -SO₃M, -COOM, -NR₃X, -COOH, -NH₂, -CN, -OH, -NHCONH₂, -X, and -NO₂, wherein R represents an alkyl group, M represents an alkali metal or -NH₄, and X represents a halogen atom.
Claim 28
Dependent Claim 67 words
The apparatus according to Claim 1, wherein said toner has a weight average particle diameter D₄ of 10 µm to 15 µm, a fine-powder content (particle diameter: 6.35 µm or smaller) of not more than 30 % by number, a coarse-powder content (particle diameter: 20.2 µm or larger) of not more than 4 % by weight, and an MI (melt index) value of not more than 10.
Claim 29
Dependent Claim 115 words
The apparatus according to Claim 1, wherein said toner comprises a binder resin, magnetic particles and a charge control agent; said binder resin having i) a polymerizable monomer unit contained in an amount of from 2 parts by weight to 30 parts by weight based on the total weight of the resin, said monomer unit having an acid group comprised of a carboxyl group or an acid anhydride thereof, and ii) an acid value of from 1 to 70 as that of the whole resin; said magnetic particles having a bulk density of not less than 0.35 g/cm³; and said charge control agent comprises a metal complex salt type monoazo dye having a hydrophilic group.
Claim 30
Dependent Claim 15 words
The apparatus according to Claim 1, wherein said toner contains a cross-linked styrene type copolymer.
Claim 31
Dependent Claim 16 words
The apparatus according to Claim 29, wherein said binder resin contained a cross-linked styrene type copolymer.
Claim 32
Dependent Claim 22 words
The apparatus according to Claim 1, wherein said toner contains a weight average particle diameter D₄ of 5 µm to 15 µm.
Claim 33
Dependent Claim 14 words
The apparatus according to Claim 1, wherein said toner contains a low-molecular weight polyalkylene.
Claim 34
Dependent Claim 22 words
The apparatus according to Claim 33, wherein said toner shows two or more maximum values in a chromatogram in gel permeation chromatography.
Claim 35
Dependent Claim 24 words
The apparatus according to Claim 1, wherein said developer comprises an insulative magnetic toner and a fine silica powder pretreated with a silicone oil.
Claim 36
Dependent Claim 29 words
The apparatus according to Claim 1, wherein said developer comprises an insulative magnetic toner and a fine silica powder pretreated with a silane coupling agent and a silicone oil.
Claim 37
Dependent Claim 23 words
The apparatus according to Claim 1, wherein said developer comprises an insulative magnetic toner and an alumina powder pretreated with a silicone oil.
Claim 38
Dependent Claim 19 words
The apparatus according to Claim 1, wherein said developer-carrying member is equipped with a means for applying a bias.
Claim 39
Dependent Claim 18 words
The apparatus according to Claim 1, wherein said electrostatic latent image bearing member has a digital latent image.
Claim 40
Dependent Claim 29 words
The apparatus according to Claim 39, wherein said electrostatic latent image bearing member has an OPC photosensitive layer and a digital latent image formed by exposure to laser light.
Claim 41
Independent Claim 153 words
An apparatus unit comprising an electrostatic latent image bearing member and a developing apparatus for developing an electrostatic latent image; said developing apparatus comprising a developer container in which a developer is held, and a developer-carrying member for carrying thereon the developer and transporting the developer to a developing zone; said developer-carrying member having a surface layer of a resin containing at least conductive fine particles and a solid lubricant, said surface layer having in its relative load curve (Abbot's load curve) a cutting depth C v of not more than 5 µm when a relative load length t p is 5 %; and said developer containing a toner and a fine powder pretreated with a silicone oil or silicone varnish; said developing apparatus being supported together with said electrostatic latent image bearing member to form a single unit, and said single unit being detachably provided in the body of an electrophotographic apparatus.
Claim 42
Dependent Claim 28 words
The apparatus unit according to Claim 41, wherein said surface layer of said developer-carrying member has a cutting depth C v of from 0.5 µm to 5 µm.
Claim 43
Dependent Claim 20 words
The apparatus unit according to Claim 41, wherein the surface of said developer-carrying member has been subjected to surface polishing.
Claim 44
Dependent Claim 20 words
The apparatus unit according to Claim 42, wherein the surface of said developer-carrying member has been subjected to surface polishing.
Claim 45
Dependent Claim 31 words
The apparatus unit according to Claim 41, wherein the surface of said developer-carrying member is controlled by polishing a surface having a cutting depth C v of more than 5 µm.
Claim 46
Dependent Claim 17 words
The apparatus unit according to Claim 41, wherein the surface of said developer-carrying member contains graphite particles.
Claim 47
Dependent Claim 18 words
The apparatus unit according to Claim 41, wherein the surface of said developer-carrying member contains conductive carbon particles.
Claim 48
Dependent Claim 21 words
The apparatus unit according to Claim 41, wherein the surface of said developer-carrying member contains graphite particles and conductive carbon particles.
Claim 49
Dependent Claim 37 words
The apparatus unit according to Claim 41, wherein said developer-carrying member comprises a developing sleeve having a magnet in its inside, and said developer comprises a magnetic toner and a fine powder pretreated with a silicone oil.
Claim 50
Dependent Claim 24 words
The apparatus unit according to Claim 49, wherein said developer comprises an insulative magnetic toner and a fine powder pretreated with a silicone oil.
Claim 51
Dependent Claim 25 words
The apparatus unit according to Claim 41, wherein said surface layer of said developer-carrying member has a thickness of from 0.5 µm to 30 µm.
Claim 52
Dependent Claim 25 words
The apparatus unit according to Claim 41, wherein said surface layer of said developer-carrying member has a thickness of from 2 µm to 20 µm.
Claim 53
Dependent Claim 25 words
The apparatus unit according to Claim 41, wherein said solid lubricant comprises graphite particles having a particle diameter of from 0.5 µm to 10 µm.
Claim 54
Dependent Claim 27 words
The apparatus unit according to Claim 41, wherein said conductive fine particles comprise amorphous carbon particles having a particle diameter of from 5 µm to 100 µm.
Claim 55
Dependent Claim 27 words
The apparatus unit according to Claim 41, wherein said conductive fine particles comprise amorphous carbon particles having a particle diameter of from 10 µm to 80 µm.
Claim 56
Dependent Claim 27 words
The apparatus unit according to Claim 41, wherein said conductive fine particles comprise amorphous carbon particles having a particle diameter of from 15 µm to 40 µm.
Claim 57
Dependent Claim 26 words
The apparatus unit according to Claim 41, wherein said surface layer of said developer-carrying member has a volume resistivity of from 10⁻⁶ Ω·cm to 10⁶ Ω·cm
Claim 58
Dependent Claim 59 words
The apparatus unit according to Claim 41, wherein said surface layer of said developer-carrying member comprises graphite particles, conductive carbon particles, or a mixture of these, and a resin selected from the group consisting of a phenol resin, a silicone resin, a fluorine resin, a polyether sulfone, a polycarbonate, a polyphenylene oxide, a polyamide and a polystyrene type resin.
Claim 59
Dependent Claim 30 words
The apparatus unit according to Claim 41, wherein said surface layer of said developer-carrying member comprises graphite particles, conductive carbon particles, or a mixture of thereof, and a phenol resin.
Claim 60
Dependent Claim 20 words
The apparatus unit according to Claim 41, wherein said electrostatic latent image bearing member comprises a laminated OPC photosensitive drum.
Claim 61
Dependent Claim 76 words
The apparatus unit according to Claim 41, wherein said toner contains a binder resin having i) a polymerizable monomer unit contained in an amount of from 2 parts by weight to 30 parts by weight based on the total weight of the resin, said monomer unit having an acid group comprised of a carboxyl group or an acid anhydride thereof, and ii) an acid value of from 1 to 70 as that of the whole resin.
Claim 62
Dependent Claim 25 words
The apparatus unit according to Claim 41, wherein said toner contains a metal complex compound (A) of an aromatic hydroxycarboxylic acid having a lipophilic group.
Claim 63
Dependent Claim 23 words
The apparatus unit according to Claim 41, wherein said toner contains a metal complex salt type monoazo dye (B) having a hydrophilic group.
Claim 64
Dependent Claim 38 words
The apparatus unit according to Claim 41, wherein said toner contain a metal complex compound (A) of an aromatic hydroxycarboxylic acid having a lipophilic group, and a metal complex salt type monoazo dye (B) having a hydrophilic group.
Claim 65
Dependent Claim 295 words
The apparatus unit according to Claim 62, wherein said metal complex compound (A) has a structure selected from the group consisting of the following formulas (I), (II) and (III). wherein R¹ to R⁴ may be the same or different from each other, and each represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, provided that at least one of R¹ to R⁴ represents said hydrocarbon group; Me represents Cr, Ni, Co, Cu or Zn; and X⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺. wherein R¹ and R² may be the same or different from each other, and each represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; and one of a and b is a benzene ring or a cyclohexene ring and the other is absent or selected from the group consisiting of a hydrocarbon group having 4 to 9 carbons, a benzene ring and a cyclohexene ring; and represents Cr, Ni, Co, Cu or Zn; and X⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺. wherein one of a and b is a benzene ring or a cyclohexene ring and the other is absent or selected from the group consisiting of a hydrocarbon group having 4 to 9 carbons, a benzene ring and a cyclohexene ring; and one of c and d is a benzene ring or a cyclohexene ring and the other is absent or selected from the group consisiting of a hydrocarbon group having 4 to 9 carbons, a benzene ring and a cyclohexene ringsymbols a and b each represent a hydrocarbon group having 4 to 9 carbon atoms, a benzene ring or a cyclohexene ring; Me represents Cr, Ni, Co, Cu or Zn; and X⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺.
Claim 66
Dependent Claim 126 words
The apparatus unit according to Claim 63, wherein said metal complex salt type monoazo dye (B) has a structure selected from the group consisting of the following formulas (IV) and (V). wherein at least one of X and Y represent(s) a hydrophilic group, and any other represent(s) a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; Me represents Cr, Ni, Co, Cu, Zn or Fe; and A⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺. wherein at least one of X, Y and Z represent(s) a hydrophilic group, and any others represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; Me represents Cr, Ni, Co, Cu, Zn or Fe; and A⁺ represents H⁺, K⁺, Na⁺, NH₄⁺ or Li⁺.
Claim 67
Dependent Claim 51 words
The apparatus unit according to Claim 63, wherein said hydrophilic group is a group selected from the group consisting of -SO₃H, -SO₃M, -COOM, -NR₃X, -COOH, -NH₂, -CN, -OH, -NHCONH₂, -X, and -NO₂, wherein R represents an alkyl group, M represents an alkali metal or -NH₄, and X represents a halogen atom.
Claim 68
Dependent Claim 68 words
The apparatus unit according to Claim 41, wherein said toner has a weight average particle diameter D₄ of 5 µm to 15 µm, a fine-powder content (particle diameter: 6.35 µm or smaller) of not more than 30 % by number, a coarse-powder content (particle diameter: 20.2 µm or larger) of not more than 4 % by weight, and an MI (melt index) value of not more than 10.
Claim 69
Dependent Claim 116 words
The apparatus unit according to Claim 41, wherein said toner comprises a binder resin, magnetic particles and a charge control agent; said binder resin having i) a polymerizable monomer unit contained in an amount of from 2 parts by weight to 30 parts by weight based on the total weight of the resin, said monomer unit having an acid group comprised of a carboxyl group or an acid anhydride thereof, and ii) an acid value of from 1 to 70 as that of the whole resin; said magnetic particles having a bulk density of not less than 0.35 g/cm³; and said charge control agent comprises a metal complex salt type monoazo dye having a hydrophilic group.
Claim 70
Dependent Claim 16 words
The apparatus unit according to Claim 41, wherein said toner contains a cross-linked styrene type copolymer.
Claim 71
Dependent Claim 17 words
The apparatus unit according to Claim 69, wherein said binder resin contains a cross-linked styrene type copolymer.
Claim 72
Dependent Claim 23 words
The apparatus unit according to Claim 41, wherein said toner has a weight average particle diameter D₄ of 5 µm to 15 µm.
Claim 73
Dependent Claim 15 words
The apparatus unit according to Claim 41, wherein said toner contains a low-molecular weight polyalkylene.
Claim 74
Dependent Claim 23 words
The apparatus unit according to Claim 73, wherein said toner shows two or more maximum peaks in a chromatogram in gel permeation chromatography.
Claim 75
Dependent Claim 25 words
The apparatus unit according to Claim 41, wherein said developer comprises an insulative magnetic toner and a fine silica powder pretreated with a silicone oil.
Claim 76
Dependent Claim 30 words
The apparatus unit according to Claim 41, wherein said developer comprises an insulative magnetic toner and a fine silica powder pretreated with a silane coupling agent and a silicone oil.
Claim 77
Dependent Claim 23 words
The apparatus according to Claim 41, wherein said developer comprises an insulative magnetic toner and an alumina powder pretreated with a silicone oil.
Claim 78
Dependent Claim 19 words
The apparatus according to Claim 41, wherein said developer-carrying member is equipped with a means for applying a bias.
Claim 79
Dependent Claim 18 words
The apparatus according to Claim 41, wherein said electrostatic latent image bearing member has a digital latent image.
Claim 80
Dependent Claim 29 words
The apparatus according to Claim 79, wherein said electrostatic latent image bearing member has an OPC photosensitive layer and a digital latent image formed by exposure to laser light.
Claim 81
Dependent Claim 141 words
A facsimile apparatus comprising an electrophotographic apparatus and a receiver means for receiving image information from a remote terminal, wherein said electrophotographic apparatus comprises an electrostatic latent image bearing member and a developing apparatus for developing an electrostatic latent image; said developing apparatus comprising a developer container in which a developer is held, and a developer-carrying member for carrying thereon the developer and transporting the developer to a developing zone; said developer-carrying member having a surface layer of a resin containing at least conductive fine particles and a solid lubricant, said surface layer having in its relative load curve (Abbot's load curve) a cutting depth C v of not more than 5 µm when a relative load length t p is 5 %; and said developer containing a toner and a fine powder pretreated with a silicone oil or silicone varnish.
Claim 82
Dependent Claim 25 words
The facsimile apparatus according to Claim 81, wherein said electrophotographic apparatus comprises the image forming apparatus according to any one of Claims 2 to 40.

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