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EP0449263A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Polysiloxane-composite polymer particles

Assignee: JSR Corp
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Filing: 1991-03-27
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Granted: —
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Expires: 2011-03-27
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Abstract

Abstract Polymer particles in which polysiloxane is composed is disclosed. The polymer particles are prepared by condensing at least one organosilane compound in the presence of organic polymer particles which are prepared from specific monomers and dispersed in an aqueous medium. The polymer particles possess excellent water resistance, weatherability, water repellency, adhesion, and flexing resistance, and thus are useful as water paints, coating agents, carpet packing material, floor polishing agents, cementing medium, and the like.

Inventors

  • 👤 Katsuhiro Nakamura
  • 👤 Minoru Kato
  • 👤 Yasuhisa Watanabe
  • 👤 Yasunori Matsubara
  • 👤 Yorinobu Ikeda
  • 👤 Yoshiaki Yonekawa
  • 👤 Hiroyuki Miki
  • 👤 Akio Hiraharu
  • 👤 Nobuyuki Ito
  • 👤 Osamu Kurita
  • 👤 Yasunobu Kaneko
  • 👤 Shouzou Nishida

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 19:48
CPC Classifications
C; C09; C09G; C09G1/00; C09G1/06; C09G1/14; C09G1/16; C08; C08G; C08G77/00; C08G77/04; C08G77/06; C08L; C08L83/00; C08L83/04; C09D; C09D7/00; C09D7/40; C09D7/65; C09D7/66; C09D7/67; C09D7/68; C09D7/69; Y; Y10; Y10S; Y10S525/00; Y10S525/902

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 33 words
Polymer particles in which polysiloxane is composed, said polymer particle being prepared by condensing at least one organosilane compound in the presence of organic polymer particles which are dispersed in an aqueous medium.
Claim 2
Dependent Claim 42 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by polymerizing monomer or monomers selected from the group consisting of aliphatic conjugated dienes, ethylenically unsaturated carboxylic acid alkyl esters, aromatic vinyl compounds, and ethylenically unsaturated carboxylic acids.
Claim 3
Dependent Claim 86 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 2-99.5% by weight of at least one monomer selected from the group consisting of aliphatic conjugated dienes and ethylenically unsaturated carboxylic acid alkyl esters, (b) 0.5-85% by weight of at least one monomer selected from the group consisting of aromatic vinyl compounds and ethylenically unsaturated carboxylic acids, and (c) 0-97.5% by weight of at least one monomer which is copolymerizable with monomers (a) and (b).
Claim 4
Dependent Claim 54 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 50-99.5% by weight of C₁₋₁₀-alkyl (meth)acrylates, (b) 0.5-15% by weight of ethylenically unsaturated carboxylic acids, and (c) 0-50% by weight of other ethylenically unsaturated monomers which are copolymerizable with monomers (a) and (b).
Claim 5
Dependent Claim 61 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 1-40% by weight of hydroxyalkyl (meth)acrylates, (b) 5-75% by weight of aromatic vinyl compounds, (c) 20-55% by weight of carboxylic acids, and (d) 0-14% by weight of other ethylenically unsaturated monomers which are copolymerizable with monomers (a), (b) and (c).
Claim 6
Dependent Claim 89 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 10-70% by weight of at least one monomer selected from the group consisting of aliphatic conjugated diene monomers and ethylenically unsaturated carboxylic acid C₄₋₁₂-alkyl esters, (b) 30-85% by weight of at least one monomer selected from the group consisting of aromatic vinyl compounds and ethylenically unsaturated carboxylic acid C₁₋₃-alkyl esters, and (c) 0-60% by weight of other ethylenically unsaturated monomers which are copolymerizable with monomers (a) and (b).
Claim 7
Dependent Claim 46 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 30-85% by weight of C₁₋₁₀-alkyl (meth)acrylate monomers, (b) 1-30% by weight of ethylenically unsaturated carboxylic acids, and (c) 0-60% by weight of aromatic vinyl compounds.
Claim 8
Dependent Claim 69 words
Polymer particles according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 2-70% by weight of at least one monomer selected from the group consisting of aliphatic conjugated diene monomers, C₂₋₁₀-alkyl acrylates, and C₆₋₁₄-alkyl methacrylates, (b) 0-8% by weight of ethylenically unsaturated carboxylic acids, and (c) 22-98% by weight of other monomers which are copolymerizable with monomers (a) and (b).
Claim 9
Dependent Claim 58 words
Polymer particles according to Claim 1, wherein said organosilane compound is a compound represented by the following formula (I), R n Si(OR′) 4-n (I) wherein R is an organic group having 1-8 carbon atoms, R′ is an alkyl group having 1-4 carbon atoms or an acyl group having 1-4 carbon atoms, and n is a value of 1-3.
Claim 10
Dependent Claim 41 words
Polymer particles according to Claim 1, wherein said organosilane compound is a compound represented by the following formula (II), R m SiO (4-m)/2 (II) wherein R is the same as defined for formula (I) and m is a value of 0-3.
Claim 11
Dependent Claim 26 words
Polymer particles according to Claim 1, comprising 0.02-500 parts by weight of said organosilane compound for 100 parts by weight of said organic polymer particles .
Claim 12
Dependent Claim 26 words
Polymer particles according to Claim 1, comprising 0.1-200 parts by weight of said organosilane compound for 100 parts by weight of said organic polymer particles .
Claim 13
Dependent Claim 26 words
Polymer particles according to Claim 1, comprising 1-100 parts by weight of said organosilane compound for 100 parts by weight of said organic polymer particles .
Claim 14
Dependent Claim 22 words
Polymer particles according to Claim 1, wherein at least a portion of the organosilane compound is absorbed in the organic polymer particles.
Claim 15
Dependent Claim 23 words
Polymer particles according to Claim 1, wherein at least 50% by weight of the organosilane compound is absorbed in the organic polymer particles.
Claim 16
Dependent Claim 16 words
Polymer particles according to Claim 1 having an average particle size of 5 µm or smaller.
Claim 17
Dependent Claim 64 words
A composition for a water paint which comprises: polymer particles in which polysiloxane is composed, said polymer particle being prepared by condensing at least one organosilane compound in the presence of organic polymer particles which are dispersed in an aqueous medium, and at least one components selected from the group consisting of fillers, dispersing agents, viscosity increasing agents, plasticizers, adjuvants, hardeners, and leveling agents.
Claim 18
Dependent Claim 55 words
The composition according to Claim 1, wherein said organic polymer particles are those prepared by emulsion polymerization of monomers comprising: (a) 50-99.5% by weight of C₁₋₁₀-alkyl (meth)acrylate monomers, (b) 0.5-15% by weight of ethylenically unsaturated carboxylic acids, and (c) 0-50% by weight of other ethylenically unsaturated monomers which are copolymerizable with monomers (a) and (b).

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