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Process for polymerizing olefins

Assignee: Mitsui Chemicals Inc
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Filing: 1987-09-24
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Granted: 1994-11-30
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Expires: 2007-09-24
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Abstract

Abstract Olefins is polymerisation process utilises a catalyst comprising (A) a solid catalyst component contg. transition metal (gp. (IVB) periodic table) cpds. carried on an inorganic carrier, (B) aluminoxane, (C) an organo-aluminium cpd. contg. hydrocarbon gps. excluding n-alkyl gps. The transition metal is pref. of Ti, Zr or Hf, esp. of formula R1kR2lR3mR4nMe (I) where R1 is a cycloalkadienyl gp., R2, R3 and R4 are the same or different and can be cycloalkadienyl, aryl, alkyl, aralkyl, cycloalkyl, halogen atom, H, ORa, SRb, or NRc2; Ra, Rb and Rc are independently alkyl, cycloalkyl, aryl, aralkyl or organosilyl; Me is Zr, Ti or Hf; k is 1, 2, 3 or 4; l, m, n are independently 0, 1, 2 or 3 and k+l+m+n=4. The aluminoxane is pref. of formula (II) or (III). where R is hydrocarbyl gp; X is halogen; a and b are each 0-80, but not both zero.

Inventors

  • 👤 Toshiyuki Tsutsui
  • 👤 Akinori Toyota
  • 👤 Norio Kashiwa

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-01 09:52
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C08F10/00; C08F110/00; C08F110/02; C08F210/18; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/64; C08F4/659; C08F4/65912; C08F4/65916; C08F4/6592; C08F4/65922

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 97 words
A process for polymerizing olefins, which comprises polymerizing or copolymerizing olefins in the presence of a catalyst composed of (A)' a compound of a transition metal of Group IV of the periodic table containing a ligand having a conjugated π-electron and a ligand containing a hetero atom capable of being bonded to the transition metal and selected from oxygen, sulfur, nitrogen and phosphorus, (B) an aluminoxane, and (C) an organoaluminium compound having a hydrocarbon group other than n-alkyl groups, the concentration of the aluminoxane in the reaction system being not more than 3 milligram-atoms/liter as aluminium atoms.
Claim 2
Dependent Claim 15 words
A process according to claim 1 wherein the transition metal is titanium, zirconium or hafnium.
Claim 3
Dependent Claim 116 words
A process according to claim 2 wherein the transition metal compound is represented by formula (I)' R ​ 11 k R ​ 12 ℓ R ​ 13 m R ​ 14 n Me   (I)' wherein R¹¹ is cycloalkadienyl, R¹² is selected from the class consisting of -OR a , -SR b , -NR c 2 and -PR d 2 , R¹³ and R¹⁴, independently from each other, represent cycloalkadienyl, aryl, aralkyl, alkyl, halogen or hydrogen, R a , R b and R c represent alkyl, cycloalkyl, aryl, aralkyl or organic silyl, Me is zirconium, titanium or hafnium, k and l are 1, 2 or 3, m and n are 0, 1 or 2 and k+l+m+n=4 .
Claim 4
Dependent Claim 56 words
A process according to any one of the preceding claims wherein the aluminoxane is represented by formula (II) wherein R is a hydrocarbon group, X is a halogen atom, and a and b , independently from each other, represent a number from 0 to 80 with the proviso that a and b are not simultaneously zero.
Claim 5
Dependent Claim 32 words
A process according to any one of the preceding claims wherein a or the organic group of the organoaluminium compound is a branched alkyl group, a cycloalkyl group or an aryl group.
Claim 6
Dependent Claim 21 words
A process according to any one of the preceding claims wherein the transition metal compound is treated with an organometallic compound.
Claim 7
Dependent Claim 27 words
A process according to claim 6 wherein the organometallic compound is an organoaluminium compound, an organoboron compound, an organomagnesium compound, an organozinc compound or an organolithium compound.
Claim 8
Dependent Claim 29 words
A process according to any one of the preceding claims wherein the concentration of the aluminoxane is from 0.1 to 2.5 milligram-atoms/liter as aluminium atoms in the reaction system.

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