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Process for producing polyalkylene oxide derivatives

Assignee: AGC Inc
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Filing: 1990-05-03
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Granted: —
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Expires: 2010-05-03
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Abstract

Abstract A process for producing an unsaturated group-­terminated polyalkylene oxide, which comprises subjecting a monoepoxide having at least 3 carbon atoms to ring-­opening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst, followed by converting terminal hydroxyl groups of the resulting hydroxyl group-terminated polyalkylene oxide to unsaturated groups.

Inventors

  • 👤 Toshihiko Higuchi
  • 👤 Shigeyuki Kozawa

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 12:35
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/02; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2642; C08G65/2645; C08G65/2663; C08G65/32; C08G65/329; C08G65/336; C08G65/337

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 53 words
A process for producing an unsaturated group-­terminated polyalkylene oxide, which comprises subjecting a monoepoxide having at least 3 carbon atoms to ring-­opening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst, followed by converting terminal hydroxyl groups of the resulting hydroxyl group-terminated polyalkylene oxide to unsaturated groups.
Claim 2
Dependent Claim 53 words
A process for producing an unsaturated group-­terminated polyalkylene oxide, which comprises subjecting a monoepoxide having at least 3 carbon atoms to ring-­opening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst, followed by converting terminal hydroxyl groups of the resulting hydroxyl group-terminated polyalkylene oxide to unsaturated groups.
Claim 3
Dependent Claim 35 words
The process according to Claim 1, wherein the hydroxyl group-terminated polyalkylene oxide obtained by the ring-opening addition polymerization of the monoepoxide is a compound having a molecular weight of at least 4,000 per terminal group.
Claim 4
Dependent Claim 67 words
A process for producing a hydrolyzable silyl group-­terminated polyalkylene oxide, which comprises subjecting a monoepoxide having at least 3 carbon atoms to ring-­opening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst, followed by converting terminal hydroxyl groups of the resulting hydroxyl group-terminated polyalkylene oxide to unsaturated groups, and reacting a hydrosilicon compound having a hydrolyzable group to the unsaturated groups.
Claim 5
Dependent Claim 67 words
A process for producing a hydrolyzable silyl group-­terminated polyalkylene oxide, which comprises subjecting a monoepoxide having at least 3 carbon atoms to ring-­opening addition polymerization to an initiator in the presence of a double metal cyanide complex catalyst, followed by converting terminal hydroxyl groups of the resulting hydroxyl group-terminated polyalkylene oxide to unsaturated groups, and reacting a hydrosilicon compound having a hydrolyzable group to the unsaturated groups.
Claim 6
Dependent Claim 35 words
The process according to Claim 3, wherein the hydroxyl group-terminated polyalkylene oxide obtained by the ring-opening addition polymerization of the monoepoxide is a compound having a molecular weight of at least 4,000 per terminal group.
Claim 7
Dependent Claim 45 words
The process according to Claim 3, wherein the hydroxyl group-terminated polyalkylene oxide obtained by the ring-opening addition polymerization of the monoepoxide is a compound having more than 2 and at most 6 terminal groups on average and a molecular weight of from 20,000 to 50,000.
Claim 8
Dependent Claim 28 words
The process according to Claim 3, wherein the unsaturated group-terminated polyalkylene oxide has more than 2 terminal groups on average and at least 1.5 unsaturated groups on average.
Claim 9
Dependent Claim 21 words
The process according to Claim 3, wherein all of the terminal-unsaturated groups of the unsaturated group-­terminated polyalkylene oxide are allyl groups.
Claim 10
Dependent Claim 47 words
The process according to Claim 3, wherein the hydrosilicon compound is a compound of the formula: HSiX′ 3-k R′ k wherein R′ is a monovalent hydrocarbon group or a halogenated hydrocarbon group, X′ is a hydrolyzable group, and k is a integer of 0, 1 or 2.
Claim 11
Dependent Claim 30 words
The process according to Claim 3, wherein the hydrolyzable silyl group-terminated polyalkylene oxide has more than 2 terminal groups on average and at least 1.5 hydrolyzable silyl groups on average.
Claim 12
Dependent Claim 22 words
A moisture-curable resin composition containing a hydrolyzable silyl group-terminated polyalkylene oxide produced by the process of Claim 3 as a curable component.

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