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EP0382209A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Photocurable composition

Assignee: Nippon Paint Co Ltd
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Filing: 1990-02-08
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Granted: —
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Expires: 2010-02-08
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Abstract

Abstract The present invention provides a photocurable composition which is rapidly cured. The composition comprises a polymerizable compound having an ethylenically unsaturated double bond and a photopolymerization initiator wherein the photopolymerization initiator comprises; (a) a compound having the following formula [I]; [wherein X represents a sulfur atom or -CO-, R¹, R², R³ and R⁴ respectively represent a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, an alkoxy group, -CH₂COOH, a nitro group, a sulfonyl group, a phosphonyl group, a cyano group, a hydroxyl group and a halogen atom.], or an alpha-diketone compound having the formula [II]; R⁵- - -R⁶      [II] [wherein R⁵ and R⁶ respectively represent an alkyl group, an alkoxy group or an aryl group, provided that neither R⁵ nor R⁶ is an alkoxy group.] (b) carbon tetrachloride or a compound having tribromomethylsulfonyl, and (c) an amine having carbon atoms directly bonded to a nitrogen atom, at least one of which is methylene group.

Inventors

  • 👤 Masahiko Harada

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 06:22
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; G03F7/0295

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 148 words
A photocurable composition comprising a polymerizable compound having an ethylenically unsaturated double bond and a photopolymerization initiator wherein the photopolymerization initiator comprises; (a) a compound having the following formula [I]; [wherein X represents a sulfur atom or -CO-, R¹, R², R³ and R⁴ respectively represent a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, an alkoxy group, -CH₂COOH, a nitro group, a sulfonyl group, a phosphonyl group, a cyano group, a hydroxyl group and a halogen atom.], or an alpha-diketone compound having the formula [II]; R⁵- - -R⁶      [II] [wherein R⁵ and R⁶ respectively represent an alkyl group, an alkoxy group or an aryl group, provided that neither R⁵ nor R⁶ is an alkoxy group.] (b) carbon bromide or a compound having tribromomethylsulfonyl, and (c) an amine having carbon atoms directly bonded to a nitrogen atom, at least one of which is methylene group.
Claim 2
Dependent Claim 148 words
A photocurable composition comprising a polymerizable compound having an ethylenically unsaturated double bond and a photopolymerization initiator wherein the photopolymerization initiator comprises; (a) a compound having the following formula [I]; [wherein X represents a sulfur atom or -CO-, R¹, R², R³ and R⁴ respectively represent a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, an alkoxy group, -CH₂COOH, a nitro group, a sulfonyl group, a phosphonyl group, a cyano group, a hydroxyl group and a halogen atom.], or an alpha-diketone compound having the formula [II]; R⁵- - -R⁶      [II] [wherein R⁵ and R⁶ respectively represent an alkyl group, an alkoxy group or an aryl group, provided that neither R⁵ nor R⁶ is an alkoxy group.] (b) carbon bromide or a compound having tribromomethylsulfonyl, and (c) an amine having carbon atoms directly bonded to a nitrogen atom, at least one of which is methylene group.
Claim 3
Dependent Claim 58 words
The composition according to Claim 1 wherein said component (a) is present in an amount of 0.001 to 0.3 mol, said component (b) is present in an amount of 0.01 to 0.2 mol, and said component (c) is present in an amount of 0.005 to 0.5 mol, the amounts being based on one liter of the polymerizable compound.
Claim 4
Dependent Claim 25 words
The composition according to Claim 1 wherein said component (a) is selected from the group consisting of 2-ethylanthraquinone, 2,4′-diethylthioxanethone, bezil, 1-­phenyl-1,2-propanedione, methylbenzoyl formate and 2,3-­butanediol.
Claim 5
Dependent Claim 15 words
The composition according to Claim 1 wherein said component (b) is carbon tetrabromide or tribromomethylphenylsulfon.
Claim 6
Dependent Claim 12 words
The composition according to Claim 1 wherein said component (c) is N-methyldiethanolamine.
Claim 7
Dependent Claim 13 words
The composition according to Claim 1 further containing polymer components and polymerization inhibitors.

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