Patent EP0352882A1 successfully refreshed from Google Patents.
EP0352882A1
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Method for making electrically conductive textile materials
Assignee: Milliken Research Corp
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Filing: 1989-04-27
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Granted: —
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Expires: 2009-04-27
Abstract
Abstract Fabrics are made electrically conductive by contacting the fiber under agitation conditions with an aqueous solution of an aniline compound, oxidizing agent and a doping agent or counter ion and then depositing onto the surface of individual fibers of the fabric a prepolymer of the aniline compound so as to uniformly and coherently cover the fibers with a conductive film of the polymerized aniline compound and wherein, furthermore, the oxidizing agent is a vanadyl compound whereby the reaction rate is controlled such that the prepolymer is uniformly and coherently adsorbed onto the surface of the textile material, thereby providing improved films of electrically conductive polymerized compound on the textile material.
Inventors
- 👤 Hans Heinrich Kuhn
- 👤 William Carl Kimbrell, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-08 04:14
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/06; H01B1/12; H01B1/124; H01B1/128; D; D06; D06M; D06M11/00; D06M11/32; D06M11/36; D06M11/47; D06M13/00; D06M13/322; D06M15/00; D06M15/19; D06M15/37; D06M15/61
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
144 words
A method for imparting electrical conductivity to a textile material, which comprises: (a) contacting the textile material with an aqueous solution of an oxidatively polymerizable aniline compound and a vanadyl compound agent capable of oxidizing said compound to a polymer, said contacting being carried out at a pH of less than about 2 in the presence of a counter ion or doping agent which imparts electrical conductivity to said polymer when fully formed, said contacting being under conditions at which the aniline compound and the vanadyl compound react with each other to form a prepolymer in said aqueous solution; (b) depositing onto the surface of the textile material the prepolymer of the aniline compound; and (c) allowing the prepolymer to polymerize while deposited on the textile material so as to uniformly and coherently cover the textile material with a conductive film of polymerized compound.
Claim 2
Independent Claim
144 words
A method for imparting electrical conductivity to a textile material, which comprises: (a) contacting the textile material with an aqueous solution of an oxidatively polymerizable aniline compound and a vanadyl compound agent capable of oxidizing said compound to a polymer, said contacting being carried out at a pH of less than about 2 in the presence of a counter ion or doping agent which imparts electrical conductivity to said polymer when fully formed, said contacting being under conditions at which the aniline compound and the vanadyl compound react with each other to form a prepolymer in said aqueous solution; (b) depositing onto the surface of the textile material the prepolymer of the aniline compound; and (c) allowing the prepolymer to polymerize while deposited on the textile material so as to uniformly and coherently cover the textile material with a conductive film of polymerized compound.
Claim 3
Dependent Claim
37 words
The method of claim 1 wherein said aniline compound is selected from the group consisting of aniline; meta-substituted anilines, ortho-substituted anilines and ortho-, meta-substituted anilines where the substituents are selected from halogen, alkyl, aryl and oxaryl substituents.
Claim 4
Dependent Claim
19 words
The method of claim 1 wherein said vanadyl compound is selected from sodium vanadate, ammonium vanadate, and vanadium pentoxide.
Claim 5
Dependent Claim
32 words
The method of claim 2 wherein said vanadyl compound is present in a catalytic amount and a "per" compound is continuously added to the aqueous solution over a prolonged period of time.
Claim 6
Dependent Claim
26 words
The method of claim 1 wherein said aniline compound is present in said solution in an amount of from about 0.01 to 5 grams per liter.
Claim 7
Dependent Claim
18 words
The method of claim 1 wherein said textile material comprises a knitted, woven or non-woven fibrous textile fabric.
Claim 8
Dependent Claim
31 words
The method of claim 6 where the fibers of said fabric are uniformly and coherently covered with said conductive film to a thickness of from about 0.05 to about 2 microns.
Claim 9
Dependent Claim
15 words
The method of claim 6 wherein said textile fabric is constructed of continuous filament yarns.
Claim 10
Dependent Claim
23 words
The method of claim 8 wherein said textile fabric comprises synthetic fibers selected from the group consisting of polyester, nylon and acrylic fibers.
Claim 11
Dependent Claim
22 words
The method of claim 8 wherein said textile fabric comprises high modulus fibers selected from aromatic polyester, aromatic polyamide and polybenzimidazole fibers.
Claim 12
Dependent Claim
20 words
The method of claim 8 wherein said textile material comprises high modulus inorganic fibers selected from glass and ceramic fibers.
Claim 13
Dependent Claim
22 words
The method of claim 6 wherein said treated textile fabric has a resistivity from about 50 to about 500,000 ohms per square.
Claim 14
Dependent Claim
18 words
The process of claim 9 wherein said textile material is or is comprised of basic dyeable polyester fibers.
Claim 15
Dependent Claim
16 words
The process of claim 1 wherein said textile material comprises a wound yarn, filament or fiber.
Claim 16
Dependent Claim
31 words
An electrically conductive textile material which is the product of the process of claim 1, having a resistivity in the range of from about 50 to about 10⁶ ohms per square.
Claim 17
Dependent Claim
21 words
The electrically conductive material of claim 15 which is a fabric comprised of fibers, filaments or yarns of polyester or polyamide.
Claim 18
Dependent Claim
26 words
The electrically conductive material of claim 15 wherein the aniline compound is aniline and the polyaniline film has a thickness of less than about 2 microns.
Claim 19
Dependent Claim
23 words
An electrically conductive textile material which comprises a textile material onto which has been deposited a film of an electrically conductive aniline polymer.
Claim 20
Dependent Claim
23 words
An electrically conductive textile material which comprises a textile material onto which has been deposited a film of an electrically conductive aniline polymer.
Claim 21
Dependent Claim
24 words
The electrically conductive textile material of claim 18 having a resistivity in the range of from about 50 to about 10⁶ ohms per square.
Claim 22
Dependent Claim
21 words
The electrically conductive material of claim 19 which is a fabric comprised of fibers, filaments or yarns of polyester or polyamide.
Claim 23
Dependent Claim
20 words
The electrically conductive material of claim 18 wherein said polyaniline film has a thickness of less than about 2 microns.
References Cited (Backward Citations)
GB2125076A
Cited
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