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Developer for electrostatic image

Assignee: Kao Corp SA
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Filing: 1989-07-12
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Granted: —
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Expires: 2009-07-12
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Abstract

Abstract A developer for electrostatic photography comprises toner and carrier coated with a composition comprising a silicone resing having (II) and (II min ) and another silicone resin having (III), (IV) or (V). <CHEM> v

Inventors

  • 👤 Toshio Honjo
  • 👤 Yuji Sato
  • 👤 Yoshihiro Fukushima
  • 👤 Masayoshi Nawa
  • 👤 Shinichiro Yasuda

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 10:58
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/10; G03G9/107; G03G9/1075; G03G9/113; G03G9/1132; G03G9/1135; G03G9/1136; Y; Y10; Y10S; Y10S430/00; Y10S430/001; Y10S430/105

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 317 words
A developer for electrostatic images comprising a toner and a carrier, characterized in that said carrier is made of a magnetic powder having a composition represented by the following formula (I) and has surfaces coated with a resin composition comprising a silicone resin in the form of a combination of segments represented by the following general formula (II) and segments represented by the following general formula (II′) and at least one member selected from the group consisting of compounds represented by the following general formula (III), (IV) or (V): (M0) x (Fe₂O₃)y      (I) (wherein M stands for at least one metal selected from the group consisting of Li, Mg, Mn Fe(II), Co, Ni, Cu, Zn, Cd, Sr, and Ba; and the molar ratio of x to y is at most 1.0); wherein R, R′, R˝ and R‴ each stand for a hydrogen atom, a halogen atom, a hydroxyl group, a methoxy group, a lower alkyl group having 1 to 4 carbon atoms, or a phenyl group); (wherein m is 2 or 3, R₁ and R₂ are each an alkyl group having 1 to 3 carbon atoms, R₃ is an alkylene group having 1 to 8 carbon atoms, and R₄ is a glycidoxy group or an epoxycyclohexyl group); (wherein n is 2 or 3; R₅ and R₆ are each an alkyl group having 1 to 3 carbon atoms; R₇ is an alkylene group having 1 to 3 carbon atoms; R₈ and R₉ are each a hydrogen atom, a methyl group, an ethyl group, a phenyl group, an aminomethyl group, or an aminoethyl group); and (wherein R₁₀ is an alkyl group having 1 to 3 carbon atoms or a vinyl group; and R₁₁ is a substituent selected from among R₁₂COO-, R₁₂-NH-, R₁₂-O-, wherein R₁₂ and R₁₃ are each an alkyl group having 1 to 3 carbon atoms, and R₁₄ is an alkylene group having 1 to 3 carbon atoms).
Claim 2
Dependent Claim 317 words
A developer for electrostatic images comprising a toner and a carrier, characterized in that said carrier is made of a magnetic powder having a composition represented by the following formula (I) and has surfaces coated with a resin composition comprising a silicone resin in the form of a combination of segments represented by the following general formula (II) and segments represented by the following general formula (II′) and at least one member selected from the group consisting of compounds represented by the following general formula (III), (IV) or (V): (M0) x (Fe₂O₃)y      (I) (wherein M stands for at least one metal selected from the group consisting of Li, Mg, Mn Fe(II), Co, Ni, Cu, Zn, Cd, Sr, and Ba; and the molar ratio of x to y is at most 1.0); wherein R, R′, R˝ and R‴ each stand for a hydrogen atom, a halogen atom, a hydroxyl group, a methoxy group, a lower alkyl group having 1 to 4 carbon atoms, or a phenyl group); (wherein m is 2 or 3, R₁ and R₂ are each an alkyl group having 1 to 3 carbon atoms, R₃ is an alkylene group having 1 to 8 carbon atoms, and R₄ is a glycidoxy group or an epoxycyclohexyl group); (wherein n is 2 or 3; R₅ and R₆ are each an alkyl group having 1 to 3 carbon atoms; R₇ is an alkylene group having 1 to 3 carbon atoms; R₈ and R₉ are each a hydrogen atom, a methyl group, an ethyl group, a phenyl group, an aminomethyl group, or an aminoethyl group); and (wherein R₁₀ is an alkyl group having 1 to 3 carbon atoms or a vinyl group; and R₁₁ is a substituent selected from among R₁₂COO-, R₁₂-NH-, R₁₂-O-, wherein R₁₂ and R₁₃ are each an alkyl group having 1 to 3 carbon atoms, and R₁₄ is an alkylene group having 1 to 3 carbon atoms).
Claim 3
Dependent Claim 218 words
A developer for electrostatic images as claimed in claim 1, wherein said toner comprises as a main component a binder resin composed of a polyester resin comprising main constituent units of polybasic carboxylic acids represented by the following general formula (VI) and a diol represented by the following general formula (VII) and having a softening point of 120 to 180°C as measured with a flow tester, and/or a styrene copolymer comprising main constituent units of a styrene represented by the following general formula (VIII) and an acrylic or methacrylic ester represented by the following general formula (IX) and having a number-average molecular weight of at least 5,000, a width of molecular weight distribution of at least 10 and a softening point of at most 180°C as measured with the flow tester: (wherein L ≧ 1, R₁₅ is a benzene ring, R₁₆ is a hydrogen atom or a lower alkyl group, and R₁₇ is a bivalent group containing a bisphenol group or an alkylene group having 2 to 6 carbon atoms; and wherein the acid component contains 0.06 to 0.60 mol % of a polybasic carboxylic acid(s) with L ≧ 2); and (wherein Ph is a phenyl group, R₁₈ is a hydrogen atom or a methyl group, and R₁₉ is an alkyl group having 4 to 18 carbon atoms).
Claim 4
Dependent Claim 30 words
A developer for electrostatic images as claimed in claim 2, wherein the main component of said at least dibasic carboxylic acid(s) is terephthalic acid or a lower alkyl ester thereof.
Claim 5
Dependent Claim 28 words
A developer for electrostatic images as claimed in claim 2, wherein at least tribasic carboxylic acid is trimellitic acid, or an anhydride or a lower alkyl ester thereof.
Claim 6
Dependent Claim 7 words
The carrier as defined in Claim 1.

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