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EP0344870A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Polymetallosilazanes useful in the manufacture of silicon nitride based ceramic fibers

Assignee: Tonen General Sekiyu KK
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Filing: 1989-03-03
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Granted: —
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Expires: 2009-03-03
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Abstract

Abstract Polymetallosilazanes, useful as precursors in the production of metal-containing silicon nitride ceramic fibers are obtained by reaction (i) a polysilazane having a number molecular weight of 100-50,000 and having a main skeletal structure containing the following recurring unit: wherein R¹, R² and R³ are the same or different and each is hydrogen, a hydrocarbyl group, a group other than a hydrocarbyl group and having a carbon atom bonded to the silicon atom of the above formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with (ii) a metal alkoxide of the formula: M(OR⁴) n wherein M is a metal, each R₄ is the same or different and is hydrogen, an alkyl group having 1-20 carbon atoms or an aryl group, and n is the valence of the metal M with the proviso that at least one of the R₄ groups is an alkyl or aryl group.

Inventors

  • 👤 Hiroyuki Aoki
  • 👤 Tadashi Suzuki
  • 👤 Toshio Katahata
  • 👤 Mutsuo Haino
  • 👤 Genshiro Nishimura
  • 👤 Hiroshi Kaya
  • 👤 Takeshi Isoda
  • 👤 Yuuji Tashiro
  • 👤 Osamu Funayama
  • 👤 Mikiro Arai

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 01:49
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/71; C04B35/78; C04B35/80; C04B35/515; C04B35/58; C04B35/584; C04B35/589; C04B35/622; C04B35/62227; C04B35/626; C04B35/63; C04B35/632; C04B35/6325; C08; C08G; C08G77/00; C08G77/60; C08G77/62; C08G79/00; D; D01; D01F; D01F9/00; D01F9/08; D01F9/10

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 143 words
A polymetallosilazane having a number molecular weight of 200-500,000, obtained by reacting (i) a polysilazane having a number molecular weight of 100-50,000 and having a main skeletal structure containing the following recurring unit: wherein R¹, R² and R³ are the same or different and each is hydrogen, a hydrocarbyl group, a group other than a hydrocarbyl group and having a carbon atom bonded to the silicon atom of the above formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with (ii) a metal alkoxide of the formula: M(OR⁴) n wherein M is a metal, each R₄ is the same or different and is hydrogen, an alkyl group having 1-20 carbon atoms or an aryl group, and n is the valence of the metal M with the proviso that at least one of the R₄ groups is an alkyl or aryl group.
Claim 2
Dependent Claim 143 words
A polymetallosilazane having a number molecular weight of 200-500,000, obtained by reacting (i) a polysilazane having a number molecular weight of 100-50,000 and having a main skeletal structure containing the following recurring unit: wherein R¹, R² and R³ are the same or different and each is hydrogen, a hydrocarbyl group, a group other than a hydrocarbyl group and having a carbon atom bonded to the silicon atom of the above formula, an alkylsilyl group, an alkylamino group or an alkoxy group, with (ii) a metal alkoxide of the formula: M(OR⁴) n wherein M is a metal, each R₄ is the same or different and is hydrogen, an alkyl group having 1-20 carbon atoms or an aryl group, and n is the valence of the metal M with the proviso that at least one of the R₄ groups is an alkyl or aryl group.
Claim 3
Dependent Claim 31 words
A polymetallosilazane as set forth in Claim 1, wherein said metal M is selected from metals of the groups IIa, IIIa, IIIb, IVa, IVb, Va and Vb of the Periodic Table.
Claim 4
Dependent Claim 44 words
A polymetallosilazane as set forth in Claim 2, wherein said metal M is selected from Be, Mg, Ca, Sr, Ba, Sc, Y, lanthanoid elements, actinoid elements, B, Al, Ga, In, Tl, Ti, Zr, Hf, Ge, Sn, Pb, V, Nb, Ta, As, Sb and Bi.
Claim 5
Dependent Claim 21 words
A polymetallosilazane as set forth in Claim 3, wherein said metal M is selected from Y, B, Al, Ti and Zr.
Claim 6
Dependent Claim 22 words
A polymetallosilazane as set forth in any preceding claim, wherein said hydrocarbyl group is an alkyl, alkenyl, aryl, cycloalkyl or aralkyl group.
Claim 7
Dependent Claim 29 words
A polymetallosilazane as set forth in any preceding claim, wherein R¹, R², R³ are independently selected from hydrogen and C₁-C₅ alkyl groups, and R⁴ is a C₁-C₁₀ alkyl group.
Claim 8
Dependent Claim 28 words
A polymetallosilazane as set forth in Claim 6, wherein R¹, R² and R³ are independently selected from hydrogen, methyl or ethyl, and R⁴ is a C₁-C₄ alkyl group.

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