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EP0344504A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Article comprising a polyimide and a metal layer and methods of making such articles

Assignee: International Business Machines Corp
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Filing: 1989-05-13
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Granted: —
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Expires: 2009-05-13
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Abstract

Abstract The article comprises a polyimide layer and a layer of a metal benzotriazole above said polyimide layer wherein said metal is selected from the group of copper, silver, and gold, and a layer of metal adjoining said metal benzotriazole layer. The method for forming such an article comprises the steps: providing a layer of a metal benzotriazole adjoining a polyamic acid layer that may be a layer of a polyimide substrate being converted to polyamic acid, wherein said metal is selected from the group of copper, silver and gold; providing a layer of metal adjoining said layer of metal benzotriazole and converting said polyamic acid to polyimide.

Inventors

  • 👤 Morris Anschel

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 17:35
CPC Classifications
H; H10; H10W; H10W70/00; H10W70/60; H10W70/67; H10W70/69; H05; H05K; H05K3/00; H05K3/38; H05K3/389; H10W99/00; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/032; H05K1/0346; H05K2201/00; H05K2201/01; H05K2201/0137; H05K2201/0154; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31721

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 39 words
Article comprising a polyimide layer and a layer of a metal benzotriazole above said polyimide layer wherein said metal is selected from the group of copper, silver, and gold, and a layer of metal adjoining said metal benzotriazole layer.
Claim 2
Dependent Claim 39 words
Article comprising a polyimide layer and a layer of a metal benzotriazole above said polyimide layer wherein said metal is selected from the group of copper, silver, and gold, and a layer of metal adjoining said metal benzotriazole layer.
Claim 3
Dependent Claim 52 words
Article according to claim 1 wherein the mtal contained in the metal benzotriazole and preferably the metal forming the metal layer is selected from the group of copper, silver and gold with the most preferred metal benzotriazole being copper benzotriazole and the most preferred metal to form the metal layer is copper.
Claim 4
Dependent Claim 22 words
Article according to claim 1 or 2 wherein said layer of copper benzotriazole is about 20 nm to about 60 nm thick.
Claim 5
Dependent Claim 55 words
Article according to any one of claims 1 to 3 wherein said layer of metal benzotriazole is adjoining said polyimide layer with preferably a layer of polyamic acid being intermediate said layer of metal benzotriazole and said polyimide layer where the layer of polyamic acid is preferably about 5 nm to about 20 nm thick.
Claim 6
Dependent Claim 51 words
Method for forming an article comprising the steps: providing a layer of a metal benzotriazole adjoining a polyamic acid layer wherein said metal is selected from the group of copper, silver, and gold; providing a layer of metal adjoining said layer of metal benzotriazole and converting said polyamic acid to polyimide.
Claim 7
Dependent Claim 51 words
Method for forming an article comprising the steps: providing a layer of a metal benzotriazole adjoining a polyamic acid layer wherein said metal is selected from the group of copper, silver, and gold; providing a layer of metal adjoining said layer of metal benzotriazole and converting said polyamic acid to polyimide.
Claim 8
Dependent Claim 55 words
Method for forming an article comprising the steps: providing a polyimide substrate converting a layer on said substrate to polyamic acid; providing a layer of metal benzotriazole adjoining said polyamic acid, wherein said metal is selected from the group of copper, silver, and gold; providing a layer of metal adjoining said layer of metal benzotriazole.
Claim 9
Dependent Claim 55 words
Method for forming an article comprising the steps: providing a polyimide substrate converting a layer on said substrate to polyamic acid; providing a layer of metal benzotriazole adjoining said polyamic acid, wherein said metal is selected from the group of copper, silver, and gold; providing a layer of metal adjoining said layer of metal benzotriazole.
Claim 10
Dependent Claim 47 words
Method according to claim 6 wherein said polyamic acid is provided by converting polyimide by contact with an aqueous alkali metal - preferably sodium or potassium - hydroxide solution of up to about 50 % concentration by weight and preferably of about 10 % concentration by weight.
Claim 11
Dependent Claim 23 words
Method according to claim 6 or 7 wherein said polyamic acid is a layer of about 5 nm to about 20 nm thickness.
Claim 12
Dependent Claim 57 words
Method according to any one of claims 5 to 8 wherein the metal contained in the metal benzotriazole and preferably the metal forming the metal layer is selected from the group of copper, silver and gold with the most preferred metal benzotriazole being copper bezotriazole and the most preferred metal to form the metal layer is copper.
Claim 13
Dependent Claim 42 words
Method according to any one of claims 5 to 9 wherein said layer of metal benzotriazole is provided by coating said polyamic acid with a layer of metal and then with a solution of benzotriazole preferably in an alcohol or aromatic hydrocarbon.
Claim 14
Dependent Claim 34 words
Method according to any one of claims 5 to 9 wherein said layer of metal benzotriazole is provided by coating said polyamic acid with a solution of benzotriazole and with a layer of metal.
Claim 15
Dependent Claim 23 words
Method according to any one of claims 5 to 11 wherein said layer of metal benzotriazole is about 20 to about 60 nm.

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