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Lubricating oil composition

Assignee: Afton Chemical Corp
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Filing: 1989-03-30
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Granted: —
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Expires: 2009-03-30
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Abstract

Abstract Lubricant compositions comprising an oil of lubricating viscosity and a cosulfurized blend of (a) a carboxylic acid ester material and (b) an ester, amide, ester-amide or fatty amine derivative which contains at least one polar substituent group such as amino and hydroxyl.

Inventors

  • 👤 Armgard Kohler Everett
  • 👤 Edmund Frank Perozzi

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 13:38
CPC Classifications
C; C10; C10M; C10M163/00; C10M129/00; C10M129/02; C10M129/68; C10M133/00; C10M133/02; C10M133/16; C10M135/00; C10M135/02; C10M135/06; C10M137/00; C10M137/02; C10M137/04; C10M137/10; C10M141/00; C10M141/10; C10M159/00; C10M159/12; C10M159/20; C10M159/24; C10M2207/00; C10M2207/28; C10M2207/287; C10M2207/289; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042; C10M2215/08; C10M2215/082; C10M2215/086; C10M2215/12; C10M2215/122; C10M2215/24; C10M2215/26; C10M2215/28; C10M2217/00; C10M2217/04; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/02; C10M2219/024; C10M2219/04; C10M2219/044; C10M2219/046; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/045; C10M2223/06; C10M2223/061; C10M2223/065; C10M2227/00; C10M2227/06; C10M2227/061; C10N; C10N2010/00; C10N2010/04; C10N2040/00; C10N2040/25; C10N2040/251; C10N2040/255; C10N2040/28; C10N2070/00; C10N2070/02

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 47 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of a cosulfurized blend which includes (a) a carboxylic acid ester material and (b) an ester, amide, ester-amide or fatty amine derivative which contains at least one polar substituent group.
Claim 2
Dependent Claim 47 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of a cosulfurized blend which includes (a) a carboxylic acid ester material and (b) an ester, amide, ester-amide or fatty amine derivative which contains at least one polar substituent group.
Claim 3
Dependent Claim 89 words
A composition according to Claim 1 wherein the ester, amide, and ester-amide derivative according to (b) is derived from an organic acid selected from fatty acids, dialkyl phosphorus acids, thiophosphorus acids, and alkyl­sulfonic acids, the ester derivative according to (b) is derived from an oxyalkylated amine or a polyhydric alco­hol, the amide derivative according to (b) is derived from an oxyalkylated amine or a polyamine, the ester-amide derivative according to (b) is derived from an oxyalky­lated amine and the fatty amine derivative according to (b) is an oxyalkylated amine.
Claim 4
Dependent Claim 17 words
A composition of Claim 1 or 2 which also contains a minor amount of an ashless dispersant.
Claim 5
Dependent Claim 34 words
A composition of Claim 1, 2, or 3 which also contains minor amounts of an overbased alkaline earth metal sulfonate having a total base number of at least 100 and a zinc dihydrocarbyl dithiophosphate.
Claim 6
Dependent Claim 74 words
An additive concentrate adapted for addition to a lubricating oil to provide a formulated lubricating oil suitable for use in the crankcase of an internal combus­tion engine said which contains from 2.0 to 25 percent by weight based on the total weight of concentrate of a cosulfurized blend which includes (a) a carboxylic acid ester material and (b) an ester, amide, ester-amide or fatty amine derivative which contains at least one polar substituent group.
Claim 7
Dependent Claim 74 words
An additive concentrate adapted for addition to a lubricating oil to provide a formulated lubricating oil suitable for use in the crankcase of an internal combus­tion engine said which contains from 2.0 to 25 percent by weight based on the total weight of concentrate of a cosulfurized blend which includes (a) a carboxylic acid ester material and (b) an ester, amide, ester-amide or fatty amine derivative which contains at least one polar substituent group.
Claim 8
Dependent Claim 26 words
The concentrate of Claim 5 which also contains from 40 to 60 percent by weight based on the total weight of concentrate of an ashless dispersant.
Claim 9
Dependent Claim 60 words
The concentrate of Claim 5 or 6 which also contains from 10 to 20 percent by weight based on the total weight of concentration of an overbased alkaline earth metal sulfonate having a total base number of at least 100 and from 10 to 20 percent by weight based on the total weight of concentrate of a zinc dihydrocarbyl dithiophosphate.
Claim 10
Independent Claim 50 words
A method of reducing sludge in an internal combustion engine said method comprising (a) adding to a lubricating oil composition a sludge inhibiting amount of a cosulfurized blend according to any of Claims 1 to 4, and (b) placing said lubricating oil in the crankcase of an internal combustion engine.
Claim 11
Dependent Claim 217 words
A composition comprising a cosulfurized blend of a carboxylic acid ester material and an organic acid ester, amide, or ester-amide derivative which contains at least one polar group and which is selected from the group consisting of: A. a fatty acid amide of a polyamine of the formula: NH₂(CH₂) n -(NH(CH₂) n ) m -NH₂ wherein n = 2 or 3, and m is 0 to 10; B. a fatty acid partial ester of a polyhydric alcohol; C. a phosphoramide, of an oxy- or thio-alkyl phosphorous acid with an oxyalkylated amine or a polyamine; D. an ester of an oxy- or thio-alkyl phosphorous acid with an oxyalkylated amine or a poly­hydric alcohol; E. an ester-amide of an oxy- or thioalkyl phos­phorous acid with an oxyalkylated amine; F. a sulfonamide of an alkylsulfonic acid with an oxyalkylated amine or a polyamine; G. an ester of an alkylsulfonic acid with a polyhydric alcohol; H. a compound of the formula: wherein X is selected from sulfur and oxygen including various combinations thereof; R and R′ are independently selected from hydro­carbyl radicals containing from about 4 to 20 carbons; R˝ and R‴ are divalent aliphatic hydrocarbon radicals containing 1-4 carbon atoms, n is an integer from 0 to 20 and R˝˝ is selected from hydrogen and the group -RO(R‴O) n -H.
Claim 12
Dependent Claim 217 words
A composition comprising a cosulfurized blend of a carboxylic acid ester material and an organic acid ester, amide, or ester-amide derivative which contains at least one polar group and which is selected from the group consisting of: A. a fatty acid amide of a polyamine of the formula: NH₂(CH₂) n -(NH(CH₂) n ) m -NH₂ wherein n = 2 or 3, and m is 0 to 10; B. a fatty acid partial ester of a polyhydric alcohol; C. a phosphoramide, of an oxy- or thio-alkyl phosphorous acid with an oxyalkylated amine or a polyamine; D. an ester of an oxy- or thio-alkyl phosphorous acid with an oxyalkylated amine or a poly­hydric alcohol; E. an ester-amide of an oxy- or thioalkyl phos­phorous acid with an oxyalkylated amine; F. a sulfonamide of an alkylsulfonic acid with an oxyalkylated amine or a polyamine; G. an ester of an alkylsulfonic acid with a polyhydric alcohol; H. a compound of the formula: wherein X is selected from sulfur and oxygen including various combinations thereof; R and R′ are independently selected from hydro­carbyl radicals containing from about 4 to 20 carbons; R˝ and R‴ are divalent aliphatic hydrocarbon radicals containing 1-4 carbon atoms, n is an integer from 0 to 20 and R˝˝ is selected from hydrogen and the group -RO(R‴O) n -H.
Claim 13
Dependent Claim 24 words
A composition comprising a cosulfurized blend of a carboxylic acid ester material and a fatty amine derivative which contains at least one polar group.
Claim 14
Dependent Claim 24 words
A composition comprising a cosulfurized blend of a carboxylic acid ester material and a fatty amine derivative which contains at least one polar group.

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