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Novel liquid crystal compounds

Assignee: Showa Shell Sekiyu KK
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Filing: 1989-02-24
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Granted: —
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Expires: 2009-02-24
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Abstract

Abstract The invention lies particularly in novel compounds represented by the general formula; in which Z means CF₃ CHF₂ CH₂F, CClF₂ CCl₂F, CHClF, CCl₃ C₂F₂ or a perfluoroalkyl group of 3 or more carbon atoms, m and n are same or different with each other and represent an integral of 1 - 20, which are ferroelectric and chiral smectic liquid crystals of a large spontaneous polarization, a high speed of response and a good orientation, and showing a liquid crystal phase of tristable state and an electoclinic effect to be used as an liquid crystal element superior in an image display response.

Inventors

  • 👤 Yoshiichi C/O Showa Shell Sekiyu K.K. Suzuki
  • 👤 Ichiro C/O Showa Shell Sekiyu K.K. Kawamura
  • 👤 Hiroyuki C/O Showa Shell Sekiyu K.K. Mogamiya

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 13:50
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/02; C09K19/0266; C09K19/04; C09K19/06; C09K19/08; C09K19/10; C09K19/20

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 92 words
Liquid crystal compounds having a benzyl phenyl ether skeleton represented by the general formula, R-(A)-X-(B)-Y-R * in which R means an alkyl or alkoxy group of 1 - 20 carbon atoms, R * means an optically active radical having an assymetric carbon atom, X means -() l -O- or -O-() l - (l is an integral of 1 - 3 and R′ means hydrogen or a lower alkyl), Y means -COO- or -O-, A and B represent respectively and in case where (A) means (B) and X mean respectively a single bond.
Claim 2
Dependent Claim 92 words
Liquid crystal compounds having a benzyl phenyl ether skeleton represented by the general formula, R-(A)-X-(B)-Y-R * in which R means an alkyl or alkoxy group of 1 - 20 carbon atoms, R * means an optically active radical having an assymetric carbon atom, X means -() l -O- or -O-() l - (l is an integral of 1 - 3 and R′ means hydrogen or a lower alkyl), Y means -COO- or -O-, A and B represent respectively and in case where (A) means (B) and X mean respectively a single bond.
Claim 3
Dependent Claim 57 words
The liquid crystal compounds as set forth in Claim 1, in which R * represents -H-R˝ in which Z means CF₃ CHF₂ CH₂F, CClF₂, CCl₂F, CHClF, CCl₃, C₂F₅ or a perfluoroalkyl group of 3 or more carbon atoms, and R˝ means an alkyl, aralkyl, alkenyl, alkynyl, cycloalkyl, benzyl or phenethyl group of 1 - 20 carbon atms.
Claim 4
Dependent Claim 45 words
The liquid crystal compounds as set forth in Claim 1, in which said optically active radical R * is derived from an alcohol such as 1,1,1-trifluoro-2-C₆-C₁₆ alkanol, 1,1-difluoro-2-C₆-C₁₆ alkanol, 1-monofluoro-2-C₆-C₁₆ alkanol, 1,1,1,2,2-pentafluoro-3-C₆-C₁₆ alkanol, 1-monofluoro-1,1-dichloro-2-C₆-C₁₆ alkanol, 1,1,1,-trichloro-2-C₆-C₁₆ alkanol, 1,1-difluoro-1-monochloro-2-C₆-C₁₆ alkanol 1,1,1-trifluoro-methyl-1-phenylmethanol, 1,1,1-trifluoro-methyl-2-phenylethanol, 1,1,1-trifluoro-methyl-3-phenylpropanol, 1,1,1-trifluoro-3-decene-2-ol and 1,1,1-trifluoro-3-heptine-2-ol.
Claim 5
Dependent Claim 64 words
The liquid crystal compounds as set forth in Claim 1, which is represented by tne general formula; in which Z means CF₃, CHF₂ CH₂F, CClF₂ CHClF, CCl₃, C₂F₅ or a perfluoroalkyl of 3 or more carbon atoms, m and n are same or different with each other and represent an integral of 1 - 20, and showing a liquid crystal phase of tristable state.
Claim 6
Dependent Claim 15 words
The liquid crystal compound as set forth in Claim 1, which is (+)-1,1,1-trifluoro-2-decyl-4-(4′-­octyloxybiphenyl-4˝-methyleneoxy)benzoate represented by
Claim 7
Dependent Claim 31 words
The liquid crystal compound as set forth in Claim 1, which is (+)-1,1,1-trifluoro-2-decyl-4-(4′-­octloxybiphenyl-4˝-methyleneoxy)benzoate showing a liquid crystal phase of tristable state and having an optical response according to an electroclinic effect.

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