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EP0318196A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Colloidal metals in monomers or polymers

Assignee: 3M Co
•
Filing: 1988-11-14
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Granted: —
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Expires: 2008-11-14
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Abstract

Abstract A polymeric composition of matter comprises a polymer having dispersed therein at least one of colloidal metal and metal oxide particles in the submicrometer size range, said composition being aqueous-free and free of aliphatic hydrocarbon polymers and their halogenated derivatives. Methods for preparing the dispersions of the invention are also disclosed.

Inventors

  • 👤 William M. C/O Minnesota Mining And Lamanna
  • 👤 Fred B. C/O Minnesota Mining And Mccormick
  • 👤 Robin E. C/O Minnesota Mining And Wright

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 08:00
CPC Classifications
C; C08; C08L; C08L101/00; B; B22; B22F; B22F9/00; B22F9/02; B22F9/12; B22F1/00; B22F1/10; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/22; C08G18/222; C08J; C08J3/00; C08J3/20; C08J3/205; C08J3/2053; C08K; C08K3/00; C08K3/02; C08K3/08; C08K3/18; C08K3/20; C08K3/22; B22F2998/00

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 46 words
A composition of matter comprising a polymer having dispersed therein at least one of colloidal metal and metal oxide particles in the submicrometer size range, said composition being aqueous-free and free of aliphatic hydrocarbon polymers and their halogenated derivatives, said composition optionally comprising a non-aqueous diluent.
Claim 2
Dependent Claim 46 words
A composition of matter comprising a polymer having dispersed therein at least one of colloidal metal and metal oxide particles in the submicrometer size range, said composition being aqueous-free and free of aliphatic hydrocarbon polymers and their halogenated derivatives, said composition optionally comprising a non-aqueous diluent.
Claim 3
Dependent Claim 27 words
The composition according to claim 1 wherein said metal is selected from the group consisting of metals having atomic numbers in the range of 11 and 106.
Claim 4
Dependent Claim 40 words
The composition according to claims 1 and 2 wherein said metal is selected from the group consisting of copper, palladium, platinum, gold, silver, cobalt, nickel, iron, manganese, indium, tin, rhodium, iridium, ruthenium, osmium, gadolinium, dysprosium, europium, chromium, tungsten, and samarium.
Claim 5
Dependent Claim 47 words
4 The composition according to claims 1 to 3 wherein said polymer is selected from the group consisting of a poly(alkylene) glycol, a polyamide, a polyurea, a polyurethane, a polyester, a vinyl polymer, a polyanhydride, a polyester, a polysiloxane, a polycarbodiimide, a cyclic polyhydrocarbon, or a polysaccharide.
Claim 6
Independent Claim 158 words
A method for preparing a colloidal metal-containing composition according to claims 1 to 4 comprising the steps of Method I, Method II, or Method III; Method I: a) providing, by the metal atom technique, a metal colloid in a polymerizable liquid monomer and optionally a non-aqueous diluent, b) effecting polymerization of said monomer, and c) isolating the resultant colloidal metal-­containing polymer; Method II: a) providing a non-polymerizable, non-aqueous organic liquid, performing in either order steps b) and c), b) forming a colloidal metal dispersion by the metal atom technique in said liquid, said dispersion optionally containing a non-aqueous diluent, c) dissolving into or swelling by said liquid a solid polymer, and d) isolating the resultant colloidal metal-­containing polymer; and Method III: a) providing a colloidal metal dispersion, by the metal atom technique, in a liquid polymer, said dispersion optionally containing a non-aqueous diluent, b) effecting further polymerization of the polymer, and c) isolating the resulting colloidal metal-containing polymer.
Claim 7
Dependent Claim 57 words
A method according to claim 5 for preparing a colloidal metal-containing polyurethane comprising the steps: a) providing a colloidal metal dispersion in a polyglycol using the metal atom technique, b) reacting the resulting colloidal metal-containing polyglycol with a polyisocyanate, optionally in the presence of a catalyst, to provide a polyurethane, and c) isolating the resulting metal-containing polyurethane.
Claim 8
Dependent Claim 24 words
The method according to claim 6 wherein said catalyst is 1) an amine or 2) a colloidal metal dispersion of cobalt, tin, or samarium.
Claim 9
Independent Claim 25 words
The method according to claims 5 to 7 further comprising the step of exposing said colloidal metal to air to effect oxidation of said metal.
Claim 10
Dependent Claim 14 words
The composition according to claims 1 to 4 which is useful as a catalyst.
Claim 11
Dependent Claim 13 words
The composition according to claims 1 to 4 which is a self-supporting film.

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