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EP0277038A2
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Multi-color transfer image forming method
Assignee: Mitsubishi Chemical Corp
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Filing: 1988-01-29
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Granted: —
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Expires: 2008-01-29
Abstract
Abstract Disclosed is a multi-color transfer image forming method, which comprises subjecting a colored image forming material having a coloration recording layer comprising at least two layers and containing a photosensitive material and a colorant on a support to aqueous development after imagewise exposure, thereby forming a colored image, transferring the colored image to an image receiving member through the outermost surface of the coloration recording layer and then transferring at least one colored image with different hue onto the same image receiving member in conformity with the colored image, characterized in that the layer of the coloration recording layer remotest from the support is a layer adherable to the image receiving member, and only the colored image portion is transferred onto the image receiving member to have the image receiving member surface exposed at the non-image portion of the multi-color image. According to the present invention, the treating process of multi-color transfer image becomes simpler and also a transferred image approximate to a printed matter can be obtained.
Inventors
- 👤 Kunio Shimizu
- 👤 Nobumasa Sasa
- 👤 Manabu Watanabe
- 👤 Hiroshi Ide
- 👤 Shinya Mayama
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-09 04:41
CPC Classifications
G; G03; G03F; G03F3/00; G03F3/10
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
139 words
A multi-color transfer image forming method, which comprises subjecting a colored image forming material having a coloration recording layer comprising at least two layers and containing a photosensitive material and a colorant on a support to aqueous development after imagewise exposure, thereby forming a colored image, transferring the colored image to an image receiving member through the outermost surface of the coloration recording layer and then transferring at least one colored image with different hue onto the same image receiving member in conformity with said colored image, characterized in that the layer of said coloration recording layer remotest from the support is a layer adherable to the image receiving member, and only the colored image portion is transferred onto the image receiving member to have the image receiving member surface exposed at the non-image portion of said multi-color image.
Claim 2
Dependent Claim
139 words
A multi-color transfer image forming method, which comprises subjecting a colored image forming material having a coloration recording layer comprising at least two layers and containing a photosensitive material and a colorant on a support to aqueous development after imagewise exposure, thereby forming a colored image, transferring the colored image to an image receiving member through the outermost surface of the coloration recording layer and then transferring at least one colored image with different hue onto the same image receiving member in conformity with said colored image, characterized in that the layer of said coloration recording layer remotest from the support is a layer adherable to the image receiving member, and only the colored image portion is transferred onto the image receiving member to have the image receiving member surface exposed at the non-image portion of said multi-color image.
Claim 3
Dependent Claim
74 words
The multi-color transfer image forming method according to Claim l, wherein said photosensitive material is a photocrosslinkable type photosensitive resin system; a system comprising a mixture of a diazonium salt or its condensate with polyvinyl alcohol, polyvinyl pyrrolidone or polyacrylamide; a system in which an aromatic azide compound is used as the photocrosslinkable agent and mixed with a binder; a photosensitive resin utilizing photoradical polymerization or photoionic polymerization; and a photosolubilizing type resin system.
Claim 4
Dependent Claim
17 words
The multi-color transfer image forming method according to Claim l, wherein the photosensitive material is quinonediazide compounds.
Claim 5
Dependent Claim
36 words
The multi-color transfer image forming method according to Claim 3, wherein the photosensitive material is compounds obtained by condensation of l,2-benzoquinonediazide-4-sulfonyl chloride, l,2-naphthoquinonediazide-4-sulfonyl chloride, l,2-naphthoquinonediazide-6-sulfonyl chloride or l,2-naphthoquinonediazide-6-sulfonyl chloride with hydroxyl group- and/or amino group-containing compounds.
Claim 6
Dependent Claim
44 words
The multi-color transfer image forming method according to Claim 4, wherein said hydroxyl group-containing compound is trihydroxybenzopheone, dihydroxyanthraquinone, Bisphenol A, phenol novolac resin, resorcin benzaldehyde condensed resin or pyrogallol acetone condensed resin, and said amino group-containing compound is aniline, p-aminodiphenylamine, p-aminobenzophenone, 4,4ʹ-diaminodiphenylamine or 4,4-diaminobenzophenone.
Claim 7
Dependent Claim
19 words
The multi-color transfer image forming method according to Claim l, wherein said coloration recording layer further contain a binder.
Claim 8
Dependent Claim
36 words
The multi-color transfer image forming method according to Claim 6, wherein said binder is poymeric compounds which can form a film and is soluble in a solvent, and can be dissolved or swelled in the developer.
Claim 9
Dependent Claim
57 words
The multi-color transfer image forming method according to Claim 7, wherein said binder is at least one of acrylic acid or methacrylic acid and alkyl ester or sulfoalkylester thereof; phenol resin; polyvinyl butyral; polyacrylamide; cellulose derivatives; poystyrene, polyvinyl chloride, chlorinated rubber, polyisobutylene, polybutadiene and polyvinyl acetate and their copolymers; cellulose acetate; cellulose propionate; and cellulose acetate phthalate.
Claim 10
Dependent Claim
85 words
The multi-color transfer image forming method according to Claim 7, wherein the binder which constitutes the upper layer of at least two layers constituting the coloration recording layer is (l) a novolac resin having a weight average molecular weight (Mw) of 3,500 to 500 and a number averave molecular weight (Mn) of l,000 to 200; (2) a copolymer containing at least one of phenolic hydroxyl group, alcoholic hydroxyl group and carboxylic group; or (3) compounds comprising a heat-fusible polymer, having water permeability and water insolubility.
Claim 11
Dependent Claim
19 words
l0. The multi-color transfer image forming method according to Claim 9, wherein said novolac resin is a phenol resin.
Claim 12
Dependent Claim
31 words
The multi-color transfer image forming method accoding to Claim l, wherein said support is a polyester film, an acetate film, a polyvinyl chloride film, a polystyrene film or a polypropyrene film.
Claim 13
Dependent Claim
28 words
The multi-color transfer image forming method accoding to Claim l, wherein the support is subjected to mold release treatment with oil reppelent substance or provided a subbing layer.
Claim 14
Dependent Claim
26 words
The multi-color transfer image forming method accoding to Claim l2, wherein said oil reppelent substance is silicone oil, fluorine resin, fluorine type surfactant, polyolefine or polyamide.
Claim 15
Dependent Claim
66 words
The multi-color transfer image forming method accoding to Claim l2, wherein said subbing layer is made of alcohol-soluble polyamide, alcohol-soluble nylon, a blend of a partially esterified resin of a copolymer of styrene and maleic anhydride with a methoxymethylated nylon, polyvinyl acetate, polyacrylate, copolymer of vinyl chloride and vinyl acetate, polyvinyl butyrate, cellulose acetate phthalate, methyl cellulose, ethyl cellulose, cellulose dicetate, cellulose triacetate or polyvinyl alcohol.
Claim 16
Dependent Claim
39 words
The multi-color transfer image forming method accoding to Claim l, wherein an upper layer of at least two layers constituting the coloration recording layer contains a binder and a lower layer thereof contains the photosnsitive material and the colorant.
Claim 17
Dependent Claim
23 words
The multi-color transfer image forming method according to Claim l4, wherein said binder comprising a heat-fusible polymer, having water permeability and water insolubility.
Claim 18
Dependent Claim
17 words
The multi-color transfer image forming method according to Claim l6, wherein said binder is a water-dispersible emulsion.
Claim 19
Dependent Claim
30 words
The multi-color transfer image forming method according to Claim l7, wherein said water-dispersible emulsion is a single component polymers or copolymers of acrylic and methacrylic acid esters or vinyl esters.
Claim 20
Dependent Claim
61 words
The multi-color transfer image forming method according to Claim l8, wherein said water-dispersible emulsion is at least one of methyl ester, ethyl ester, butyl ester, isobutyl ester, hexyl ester, decyl ester, lauryl ester, stearyl ester, cyclohexyl ester, vinyl acetate, vinyl propionate, vinyl isononanate, vinyl benzathate, ethylene, dibutylmaleinate, styrol, vinyl chloride, vinyl isobutyl ether, isobutylene, butadiene, paraffin, vinyl acetate and vinyl butyral.
Claim 21
Dependent Claim
30 words
The multi-color transfer image forming method according to Claim l9, wherein said water-dispersible emulsion is added with a water-soluble polymer in an amount of l to 50 % by weight.
Claim 22
Dependent Claim
37 words
2l. The multi-color transfer image forming method accoding to Claim l, wherein an upper layer of at least two layers constituting the coloration recording layer contains the photosensitive material and a lower layer thereof contains the colorant.
Claim 23
Dependent Claim
40 words
The multi-color transfer image forming method accoding to Claim l, wherein an upper layer of at least two layers constituting the coloration recording layer contains the photosensitive material and a lower layer thereof contains the photosnsitive material and the colorant.
References Cited (Backward Citations)
No citation records indexed.
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