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EP0274757A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Bilayer lithographic process

Assignee: Eastman Kodak Co
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Filing: 1987-12-31
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Granted: —
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Expires: 2007-12-31
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Abstract

Abstract A method for producing high resolution patterned resist images having excellent etch resistance and superior thermal and dimensional stability comprises the steps of: (a) forming a planarizing layer resistant to silicon uptake on a substrate, (b) providing a positive-working photoresist composition containing -OH or -NH- groups over the planarizing layer, (c) imagewise exposing the resist to activating radiation, (d) developing the exposed resist, (e) contacting the developed resist with a vapor comprising a silicon-containing compound to effect silylation thereof and thereby impart etch resistance, the silicon-containing compound having the structural formula: wherein X¹ and X² are individually chloro or wherein R³ and R⁴ are individually H or alkyl; and R¹ and R² are individually H or alkyl; and (f) contacting the planarizing layer with an oxygen-containing plasma so as to preferentially remove portions thereof.

Inventors

  • 👤 William Carey C/O Eastman Kodak Company Mccolgin
  • 👤 Thomas Brownell C/O Eastman Kodak Company Brust
  • 👤 Robert Curtis C/O Eastman Kodak Company Daly
  • 👤 Joseph Jr. C/O Eastman Kodak Company Jech
  • 👤 Robert Derwood C/O Eastman Kodak Company Lindholm

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 22:28
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/40; G03F7/405; G03F7/004; G03F7/09; G03F7/094

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 140 words
A method for producing a patterned resist image on a substrate comprising the steps of: (a) forming a planarizing layer resistant to silicon uptake on a substrate, (b) providing a positive-working photoresist composition containing -OH or -NH- groups over said planarizing layer, (c) imagewise exposing said resist to activating radiation, (d) developing said exposed resist, (e) contacting said developed resist with a vapor comprising a silicon-containing compound to effect silylation thereof and thereby impart etch resistance, said silicon-containing compound having the structural formula: wherein: X¹ and X² are individually chloro or wherein R³ and R⁴ are individually H or alkyl containing from 1 to 3 carbon atoms; and R¹ and R² are individually H or alkyl containing from 1 to 3 carbon atoms; and (f) contacting said planarizing layer with an oxygen-containing plasma so as to preferentially remove portions thereof.
Claim 2
Independent Claim 140 words
A method for producing a patterned resist image on a substrate comprising the steps of: (a) forming a planarizing layer resistant to silicon uptake on a substrate, (b) providing a positive-working photoresist composition containing -OH or -NH- groups over said planarizing layer, (c) imagewise exposing said resist to activating radiation, (d) developing said exposed resist, (e) contacting said developed resist with a vapor comprising a silicon-containing compound to effect silylation thereof and thereby impart etch resistance, said silicon-containing compound having the structural formula: wherein: X¹ and X² are individually chloro or wherein R³ and R⁴ are individually H or alkyl containing from 1 to 3 carbon atoms; and R¹ and R² are individually H or alkyl containing from 1 to 3 carbon atoms; and (f) contacting said planarizing layer with an oxygen-containing plasma so as to preferentially remove portions thereof.
Claim 3
Dependent Claim 25 words
The method of claim 1 wherein said developed resist is exposed to a UV light source prior to contacting said resist with said silicon-containing compound.
Claim 4
Dependent Claim 17 words
The method of claim 1 wherein at least one of R¹, R², R³ and R⁴ is H.
Claim 5
Dependent Claim 25 words
The method of claim 1 wherein said silicon-containing compound is selected from the group consisting of dichlorodimethylsilane, dichloromethylsilane, bis(dimethylamino)dimethylsilane, bis(dimethylamino)methylsilane, dimethylamino chlorodimethylsilane, and dimethylamino chloromethylsilane.
Claim 6
Dependent Claim 21 words
The method of claim 1 wherein said silicon-containing compound is selected from the group consisting of dichloromethylsilane, bis(dimethylamino)methylsilane, and dimethylamino chloromethylsilane.
Claim 7
Dependent Claim 18 words
The method of claim 1 wherein said resist has a glass transition temperature of less than about 75°C.
Claim 8
Dependent Claim 12 words
The method of claim 1 wherein said resist comprises a novolac resin.
Claim 9
Dependent Claim 20 words
The method of claim 1 wherein portions of said planarizing layer are preferentially removed by an oxygen reactive ion etch.

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