Thermal transfer printing

Claim 2

A thermal transfer printing sheet comprising a substrate having a coating comprising a dye of the formula: wherein Ring A is unsubstituted or carries, in the 2- or 4-position with respect to the azo link, at least one group selected from -CX 3 , X 1 , CN, NO 2 , -OCO.Y, -CO.Y, -CO.H, -OSO 2 .Y and -SO 2 .Y, provided that A is substituted when Z is CH 3 and R is C 2-4 -alkyl; X & X are each independently halogen; 2 Y is selected from R 1 , -OR 1 , SR 1 and -NR 1 R 2 ; R is selected from C 1-12 -alkyl, C 1-12 -alkyl interrupted by one or two groups selected from -0-, -CO-, O.CO- and -CO.O-, C 3-7 -cycloalkyl, mono- or bi-cyclic aryl and C 1-3 -alkylene attached to an adjacent carbon atom on Ring A; R 2 is selected from H, C 1-12 -alkyl, C 3-7 -cycloalkyl and mono-or bi-cyclic aryl; Z is C 1-12 -alkyl or phenyl; and R is selected from C 2-12 -alkyl unbranched in the alpha-position, C 2-12 -alkyl unbranched in alpha-position and interrupted by one or two groups selected from -0-, -CO-, O.CO- and -CO.O-, phenyl, C 1-4 -alkylphenyl, biphenyl and biphenyl interrupted by a group selected from -0-, -CO-, O.CO- and -CO.O-, each of which is free from hydrogen atoms capable of intermolecular hydrogen bonding.

Claim 3

A thermal transfer printing sheet comprising a substrate having a coating comprising a dye of the formula: wherein Ring A is unsubstituted or carries one or two substituents selected from -CX 3 , X 1 , CN, NO 2 , -OCO.Y, -CO.Y, -OSO 2 .Y and -SO 2 .Y, provided that A is substituted when Z is CH 3 and R is C 2-4 -alkyl; X & X 1 are each independently halogen; Y is selected from R 1 , -OR 1 and -NR 1 R 2 ; R 1 is selected from C 1-12 -alkyl, C 1-12 -alkyl interrupted by a bridging group selected from -0-, -CO-, O.CO- and -CO.O-, C 3-7 -cycloalkyl and mono- or bi-cyclic aryl; R 2 is selected from H, C 1-12 -alkyl, C 3-7 -cycloalkyl and mono-or bi-cyclic aryl; Z is C 1-12 -alkyl; and R is selected from phenyl, C 2-12 -alkyl unbranched in the alpha- and beta-positions, C 2-12 -alkyl unbranched in alpha-and beta- positions and interrupted by an -0- bridging group. 3. A thermal transfer printing sheet according to Claim I wherein in the defined dye: Ring A carries one or two substituents in the 2, 4 or 2 and 4 positions selected from -CF 3 , F, Cl, CN, NO 2 , -OCO.Y, -CO.Y, CO.H, -OSO 2 .Y and -SO 2 .Y; Y is selected from R 1 , -OR 1 , SR 1 and -NR 1 R 2 ; R 1 is selected from C 1-12 -alkyl, a chain of two or three C 1-4 -alkyl group, containing a total of up to 12 carbon atoms, linked by groups selected from -0-, -CO-, O.CO- and -CO.O-, C 3-7 -cycloalkyl, phenyl and C 1-3 -alkylene attached to an adjacent carbon atom on Ring A; R 2 is selected from C 1-12 alkyl, C 3-7 -cycloalkyl and phenyl; Z is C 1-4 -n-alkyl; and R is selected from C 2-6 -n-alkyl, phenyl and a chain of two or three C 1-4 -alkyl groups, containing a total of up to 12 carbon atoms, linked by -0- bridging groups.

Claim 4

A thermal transfer printing sheet according to Claim 1 or Claim 3 wherein in the defined dye: Ring A carries a substituent in the 2 or 4 position selected from F, Cl, CN, NO 2 , -CO.Y and -CO.H; Y is selected from R , -OR 1 , -SR 1 ; R 1 is C 1-4 -alkyl or a chain of two or three C 1-4 -alkyl group, containing a total of up to 12 carbon atoms, linked -0- groups;

Claim 5

A thermal transfer printing sheet according to Claim 1, Claim 3 or Claim 4 wherein in the defined dye: Ring A is selected from 4-chlorophenyl, 2-fluorophenyl, 2-nitrophenyl, 2-nitro-4-chlorophenyl, 2-cyanophenyl, 4-cyanophenyl, 4-formylphenyl, 4-acetylphenyl, 2-methoxy- carbonylphenyl, 4-(2-methoxyethoxycarbonylphenyl) and 4-ethylthiocarbonylphenyl; Z is methyl; and R is C 2-6 -n-alkyl or C 1-4 alkoxy-C 2-7 -n-alkyl.

Claim 6

A thermal transfer printing sheet according to any one of Claims 1 to 5 wherein R is n-propyl or n-butyl.

Claim 7

A transfer printing process which comprises contacting a transfer sheet according to any one of Claims 1 to 6 with a receiver sheet, so that the dye is in contact with the receiver sheet and selectively heating areas of the transfer sheet whereby dye in the heated areas of the transfer sheet may be transferred to the receiver sheet.

Claim 8

A transfer printing process according to Claim 7 wherein the transfer sheet is heated to a temperature from 300°C to 400°C for a period from 1 to 10 milliseconds while in contact with the receiver sheet.

Claim 9

A transfer printing process according to Claim 7 or Claim 8 wherein the receiver sheet is white polyester film.