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EP0247734A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Piezoelectric composite materials and method of making

Assignee: Lockheed Martin Corp
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Filing: 1987-04-28
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Granted: —
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Expires: 2007-04-28
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Abstract

Abstract A piezoelectric composite material having increased sensitivity and stability with time is described. The composite includes a volume fraction of from 20 to 60 percent of piezoelectric crystals having a size distribution of from 1 to 300 microns dispersed in a polymer matrix. The composite matrix is characterized by a shear modulus of at least 50 psi.

Inventors

  • 👤 William P. Krug
  • 👤 Meredith A. Aronson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:38
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08G18/28; C08G18/67; C08G18/69; H; H10; H10N; H10N30/00; H10N30/01; H10N30/09; H10N30/092; H10N30/80; H10N30/85; H10N30/852

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 50 words
A composite piezoelectric material comprising particles of a piezoelectric material dispersed in a polymer matrix; the piezoelectric particles having a volume fraction of at least 20 percent and particle size distribution in the range of 1-300 micron; and the polymer matrix having a Young's modulus of at least 150 psi.
Claim 2
Dependent Claim 50 words
A composite piezoelectric material comprising particles of a piezoelectric material dispersed in a polymer matrix; the piezoelectric particles having a volume fraction of at least 20 percent and particle size distribution in the range of 1-300 micron; and the polymer matrix having a Young's modulus of at least 150 psi.
Claim 3
Dependent Claim 18 words
The composite of claim 1 wherein said polymer matrix has a Young's modulus of at least 500 psi.
Claim 4
Dependent Claim 62 words
The composite of claim 1 wherein the piezoelectric crystal is selected from the group consisting of tartaric acid, mono- saccharides and di- saccharides and carboxylate salts that do not substantially change hydration level or crystal phase in the desired temperature range of application and which are members of the crystal class 1, 2, 3, 4, 6, m, 2mm, 4mm, 3m, and 6mm.
Claim 5
Dependent Claim 20 words
The composite of claim 3 wherein the polymer is selected from the group of medium to high molecular weight polyurethanes.
Claim 6
Dependent Claim 13 words
The composite of claim 3 wherein the polymer is a polybutadiene based polyurethane.
Claim 7
Dependent Claim 21 words
The composite of claim 1 wherein the volume percent of piezoelectric crystals is in the range of 20 to 60 percent.
Claim 8
Dependent Claim 16 words
The composite of claim 1 wherein the volume percent of piezoelectric crystals is approximately 50 percent.
Claim 9
Dependent Claim 17 words
The composite of claim 1 wherein said composite has a Young's modulus of at least 5,000 psi.
Claim 10
Dependent Claim 17 words
The composite of claim 1 wherein said composite has a Young's modulus of at least 15,000 psi.
Claim 11
Dependent Claim 17 words
The composite of claim 1 wherein said composite has a Young's modulus of at least 30,000 psi.
Claim 12
Independent Claim 48 words
A method of making a composite piezoelectric material comprising the steps of: a) dispersing a quantity of particles of a piezoelectric material in a prepolymer mixture containing a plasticizer to form a composite; b) poling the composite; c) curing the composite; d) removing the plasticizer from the composite;
Claim 13
Independent Claim 48 words
A method of making a composite piezoelectric material comprising the steps of: a) dispersing a quantity of particles of a piezoelectric material in a prepolymer mixture containing a plasticizer to form a composite; b) poling the composite; c) curing the composite; d) removing the plasticizer from the composite;
Claim 14
Dependent Claim 22 words
wherein the composite contains at least 20 volume percent of piezoelectric particles having a size distribution in the range of 1-300 microns.
Claim 15
Dependent Claim 22 words
wherein the composite contains at least 20 volume percent of piezoelectric particles having a size distribution in the range of 1-300 microns.
Claim 16
Dependent Claim 23 words
The method of claim 11 wherein the piezoelectric material is selected from the group consisting of tartaric acids, mono- saccharides and di- ­saccharides.
Claim 17
Dependent Claim 13 words
The method of claim 12 wherein the composite is degassed prior to poling.
Claim 18
Dependent Claim 19 words
The method of claim 13 wherein the plasticizer is removed from the composite by submersion in a silicone fluid.
Claim 19
Dependent Claim 17 words
Th method of claim 14 wherein the prepolymer mixture comprises a medium to high molecular weight polyurethane.
Claim 20
Dependent Claim 14 words
The method of claim 14 wherein the prepolymer mixture comprises a polybutadiene based polyurethane.
Claim 21
Dependent Claim 19 words
The method of claim 8 wherein the volume percent of piezoelectric crystals is in the range of 20-60 percent.
Claim 22
Dependent Claim 16 words
The method of claim 8 wherein the volume percent of piezoelectric crystals is approximately 50 percent.

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