Patent US823569A successfully refreshed from Google Patents.
Patent EP0240162A2 successfully refreshed from Google Patents.
← Back to Patent Explorer
EP0240162A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Liquid curable polyorganosiloxane compositions

Assignee: Dow Silicones Corp
•
Filing: 1987-03-02
•
Granted: —
•
Expires: 2007-03-02
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The curable polyorganosiloxane compositions of this invention comprise at least one vinyl-terminated liquid polydiorganosiloxane, a resinous organosiloxane reinforcing agent that includes diorganovinylsiloxy, triorganosiloxy and SiO₂ units, an organosiloxane curing agent containing an average of at least three silicon-bonded hydrogen atoms per molecule, a diorganohydrogensiloxy terminated polydiorganosiloxane as a chain extender in an amount sufficient to provide from 10 to 85 percent of the silicon-bonded hydrogen atoms in the composition, and a platinum-containing hydrosilation catalyst. The compositions contain at least 1.5 vinyl radicals for each silicon-bonded hydrogen atom present in the composition. The cured elastomer is compressible, resilient and exhibits a hardness value of up to 100 on the Shore 00 durometer scale.

Inventors

  • 👤 Beth Irene Gutek

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 03:51
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/20; C08G77/22; C08G77/24; C08G77/70

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 224 words
A curable composition yielding an optically transparent polyorganosiloxane elastomer, said composition comprising the product obtained by blending the following ingredients to homogeneity: A. at least one liquid polydiorganosiloxane exhibiting a viscosity of from 0.1 to 40 Pa.s at 25°C. and containing a vinyl radical at each of the two terminal positions; B. from 5 to about 40 percent, based on the total weight of said composition, of a benzene soluble resinous copolymer consisting essentially of triorganosiloxy units of the general formula R′′₃ SiO 1/2 , diorganovinylsiloxy units of the general formula CH₂=CH(R′′′)₂SiO 1/2 , and SiO₂ units, where R′′ and R′′′ are individually monovalent hydrocarbon or halohydrocarbon radicals containing from 1 to about 20 carbon atoms and free of ethylenic unsaturation, the molar ratio of combined triorganosiloxy units and diorganovinylsiloxy units to SiO₂ units is from 0.7 to 1.2 and said copolymer contains from 0.1 to 8 weight percent of silicon-bonded vinyl radicals; C. an organohydrogensiloxane curing agent containing at least three silicon-bonded hydrogen atoms per molecule, D. a diorganohydrogensiloxy terminated polydiorganosiloxane containing two silicon-­bonded hydrogen atoms and an average of up to 50 diorganosiloxane units per molecule in an amount sufficient to provide from l0 to 85 percent of the silicon-bonded hydrogen atoms present in said composition, and E. a platinum-containing hydrosilation catalyst in an amount sufficient to promote curing of said composition;
Claim 2
Dependent Claim 224 words
A curable composition yielding an optically transparent polyorganosiloxane elastomer, said composition comprising the product obtained by blending the following ingredients to homogeneity: A. at least one liquid polydiorganosiloxane exhibiting a viscosity of from 0.1 to 40 Pa.s at 25°C. and containing a vinyl radical at each of the two terminal positions; B. from 5 to about 40 percent, based on the total weight of said composition, of a benzene soluble resinous copolymer consisting essentially of triorganosiloxy units of the general formula R′′₃ SiO 1/2 , diorganovinylsiloxy units of the general formula CH₂=CH(R′′′)₂SiO 1/2 , and SiO₂ units, where R′′ and R′′′ are individually monovalent hydrocarbon or halohydrocarbon radicals containing from 1 to about 20 carbon atoms and free of ethylenic unsaturation, the molar ratio of combined triorganosiloxy units and diorganovinylsiloxy units to SiO₂ units is from 0.7 to 1.2 and said copolymer contains from 0.1 to 8 weight percent of silicon-bonded vinyl radicals; C. an organohydrogensiloxane curing agent containing at least three silicon-bonded hydrogen atoms per molecule, D. a diorganohydrogensiloxy terminated polydiorganosiloxane containing two silicon-­bonded hydrogen atoms and an average of up to 50 diorganosiloxane units per molecule in an amount sufficient to provide from l0 to 85 percent of the silicon-bonded hydrogen atoms present in said composition, and E. a platinum-containing hydrosilation catalyst in an amount sufficient to promote curing of said composition;
Claim 3
Dependent Claim 36 words
with the proviso that the composition contains at least l.5 vinyl radicals for each silicon-bonded hydrogen atom, and the combined concentration of said curing agent and said diorganohydrogensiloxy terminated polydiorganosiloxane is sufficient to cure said composition.
Claim 4
Dependent Claim 36 words
with the proviso that the composition contains at least l.5 vinyl radicals for each silicon-bonded hydrogen atom, and the combined concentration of said curing agent and said diorganohydrogensiloxy terminated polydiorganosiloxane is sufficient to cure said composition.
Claim 5
Dependent Claim 53 words
A composition according to claim 1 where the vinyl-containing polydiorganosiloxane is represented by the general formula where R represents a monovalent hydrocarbon radical or a monovalent halohydrocarbon radical, Vi represents a vinyl radical, and n represents a degree of polymerization equivalent to a viscosity of from 0.1 to about 40 Pa.s at 25°C.
Claim 6
Dependent Claim 83 words
A composition according to claim 2 where R represents a monovalent hydrocarbon or halogenated hydrocarbon radical containing from 1 to 10 carbon atoms, said organohydrogensiloxane contains at least three repeating units per molecule that are selected from the group consisting of HSiO 1.5 , R′HSiO and R′₂HSiO 0.5 , where R′ represents a monovalent hydrocarbon or halogenated hydrocarbon radical containing from l to 10 carbon atoms, and any remaining repeating units are selected from the group consisting of monoorganosiloxane, diorganosiloxane, triorganosiloxy and SiO₂.
Claim 7
Dependent Claim 31 words
A composition according to claim 3 where the viscosity of said composition does not exceed 100 Pa.s at 25°C. and where R, R′, R′′ and R′′′ are methyl, phenyl or 3,3,3-trifluoropropyl.
Claim 8
Dependent Claim 87 words
A composition according to claim 4 where R, R′, R′′ and R′′′ are methyl, the curing agent comprises a dimethylsiloxane/methylhydrogensiloxane copolymer containing an average of from 10 to 50 repeating units and from 3 to 5 silicon-bonded hydrogen atoms per molecule, the composition contains from two to four moles of vinyl radicals per mole of silicon-bonded hydrogen atoms, the silicon-bonded hydrocarbon radicals of the diorganohydrogensiloxy terminated polydi­organosiloxane are methyl and said platinum-containing hydrosilation catalyst is a reaction product of hexachloro­platinic acid and a vinyl containing organosiloxane compound.
Claim 9
Dependent Claim 68 words
A composition according to claim 5 where said composition contains two of said liquid polydiorgano­siloxanes, the first of which exhibits a viscosity of from 0.1 to 3 Pa.s at 25°C. and the second of which exhibits a viscosity of from 20 to 40 Pa.s at 25°C , and the dimethylhydrogensiloxy terminated polydimethylsiloxane contains from 30 to 70 mole percent of the silicon-bonded hydrogen atoms present in said composition.
Claim 10
Dependent Claim 12 words
A composition according to claim 6 that contains a platinum catalyst inhibitor.
Claim 11
Dependent Claim 15 words
A composition according to claim 7 where said platinum catalyst inhibitor is an acetylenic alcohol.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Maintenance schedule is calculated for granted US utility patents.

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag