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EP0220578A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

A photoresist composition and a process using that photoresist composition

Assignee: International Business Machines Corp
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Filing: 1986-10-10
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Granted: —
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Expires: 2006-10-10
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Abstract

Abstract A photoresist composition comprising a matrix resin and two photoactive additives, one of which causes acceleration of dissolution upon irradiation and one of which causes deceleration of dissolution upon irradiation, the photoactive additives being such that the dissolution-accelerating additive is activated by at least one narrow bandwidth of radiation which does not activate the dissolution-decelerating additive. Self aligned multilayer or multi-level structures can be made by a process using that photoresist composition.

Inventors

  • 👤 William Dinan Hinsberg
  • 👤 Carlton Grant Willson

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 19:27
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/095; G03F7/008; G03F7/022; G03F7/0226

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 56 words
A photoresist composition comprising a matrix resin and two photo­active additives, one of which causes acceleration of dissolution upon irradiation and one of which causes deceleration of dissolution upon irradiation, the photoactive additives being such that the dissolution-­accelerating additive is activated by at least one narrow bandwidth of radiation which does not activate the dissolution-decelerating additive.
Claim 2
Dependent Claim 56 words
A photoresist composition comprising a matrix resin and two photo­active additives, one of which causes acceleration of dissolution upon irradiation and one of which causes deceleration of dissolution upon irradiation, the photoactive additives being such that the dissolution-­accelerating additive is activated by at least one narrow bandwidth of radiation which does not activate the dissolution-decelerating additive.
Claim 3
Dependent Claim 16 words
A photoresist composition as claimed in claim 1, wherein the matrix resin is a phenol-formaldehyde resin.
Claim 4
Dependent Claim 14 words
A photoresist composition as claimed in claim 1, wherein the matrix resin is p-hydroxystyrene.
Claim 5
Dependent Claim 16 words
A photoresist composition as claimed in any preceding claim, wherein the dissolution-accelerating additive is a diazoketone.
Claim 6
Dependent Claim 20 words
A photoresist composition as claimed in any of claims 1 to 3, wherein the dissolution-accelerating additive is a 1-oxo-2-diazonaphtho­quinone-5-sulfonate ester.
Claim 7
Dependent Claim 17 words
A photoresist composition as claimed in any preceding claim, wherein the dissolution-decelerating additive is a mono-or bis-azide.
Claim 8
Dependent Claim 21 words
A photoresist composition as claimed in any of claims 1 to 5, wherein the dissolution-decelerating additive is a diazido diphenyl sulfone.
Claim 9
Dependent Claim 21 words
A photoresist composition as claimed in any of claims 1 to 5, wherein the dissolution decelerating additive is a monoaryl azide.
Claim 10
Dependent Claim 19 words
A photoresist composition as claimed in any of claims 1 to 5, wherein the dissolution-decelerating additive is an azidochalcone.
Claim 11
Dependent Claim 114 words
A process for producing self-aligned structures, the process comprising the steps of: (1) coating a substrate with photoresist composition as claimed in any preceding claim, (2) exposing said composition to radiation through a mask which has opaque areas and two types of transparent areas, one of which is opaque to the bandwidth that activates the dissolution-decelerating additive, (3) developing by treatment with a solvent, (4) transferring the resulting image to the substrate, (5) flood exposing with radiation of a bandwidth that activates the dissolution-accelerating additive but does not activate the dissolution-decelerating additive, (6) developing by treatment with a solvent, (7) transferring the image to the substrate, and (8) stripping the resist from the substrate.
Claim 12
Dependent Claim 17 words
A process as claimed in claim 10, in which the image transfer steps are done by etching.

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