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Catalyst for polymerization of olefins

Assignee: Tonen General Sekiyu KK
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Filing: 1986-06-18
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Granted: —
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Expires: 2006-06-18
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Abstract

Abstract A catalyst for polymerization of olefins which comprises a vanadium compound of the formula:(where R<sup>1</sup> is an alkyl group or aryl group having 1 to 8 carbon atoms; and R<sup>2</sup> is an alkyl group or aryl group having from 1 to 8 carbon atoms, or hydrogen) and the organoaluminum compound of the formula R<sub>2</sub>AIX (where R is a hydrocarbon group having 1 to 8 carbon atoms, and X is a halogen atom).

Inventors

  • 👤 Shigeo Suzuki
  • 👤 Yoshiharu Doi
  • 👤 Kazuo Soga

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 20:11
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 14 words
A catalyst system comprising a vanadium chelate of a beta-ketoaldehyde and an organoaluminum compound.
Claim 2
Dependent Claim 14 words
A catalyst system comprising a vanadium chelate of a beta-ketoaldehyde and an organoaluminum compound.
Claim 3
Dependent Claim 78 words
The catalyst system of claim 1 wherein the vanadium chelate is of the formula: wherein R 1 , is an alkyl or aryl group having 1 to 8 carbon atoms and R 2 is an alkyl or aryl group having from 1 to 8 carbon atoms or hydrogen and the organoaluminum compound is represented by the formula R 2 AlX wherein R is a hydrocarbyl group having from 1 to 8 carbon atoms and X is a halogen.
Claim 4
Dependent Claim 23 words
The catalyst system of claim 2 wherein the vanadium chelate is one of V(2-methyl-3-oxobutanalate) 3 , V(3-oxobutanalate)3, V(2-ethyl-3-oxopentanalate) 3 and Y(2-phenyi-3-oxobutanalate) 3 .
Claim 5
Dependent Claim 28 words
The catalyst system in accordance with claim 2 wherein the organoaluminum compound is one of dimethyl aluminum chloride, diethyl aluminum chloride, diethyl aluminum bromide and diisobutyl aluminum chloride.
Claim 6
Dependent Claim 25 words
The catalyst system of claim 2 wherein the range of organoaluminum compound to vanadium chelate is in the range of 10-1,000:1 on a mol basis.
Claim 7
Dependent Claim 26 words
A living polymerization process comprising polymerizing one or more olefins in the presence of a catalyst system as claimed in any of claims 1 to 5.

References Cited (Backward Citations)

US3349064A Cited

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