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EP0204575A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Ultraviolet curable ink compositions

Assignee: Mitsubishi Chemical Corp
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Filing: 1986-06-05
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Granted: —
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Expires: 2006-06-05
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Abstract

Abstract An ultraviolet curable ink composition comprising, as main components, (A) a polyurethane poly(meth)acrylate obtained by reacting a polyisocyanate compound of the formula: wherein R, is a hydrogen atom or a methyl group, and n is an integer of from 1 to 20, with a hydroxyl group-containing (meth)acrylate, and having, in one molecule, at least two (meth)acryloyl groups and at least two urethane bonds, (B) a radical polymerizable low molecular weight compound, and (C) a photopolymerization initiator.

Inventors

  • 👤 Hideo Nakamoto
  • 👤 Fumito Aosai
  • 👤 Hiroshi Fukushima
  • 👤 Eriko Suda

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:06
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/101; C08; C08F; C08F299/00; C08F299/02; C08F299/06; C08F299/065

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 88 words
An ultraviolet curable ink composition comprising, as main components, (A) a polyurethane poly (meth) acrylate obtained by reacting a polyisocyanate compound with a hydroxyl group containing (meth) acrylate and having, in one molecule, at least two (meth) acryloyl groups and at least two urethane bonds, (B) a radical polymerisable low molecular weight compound, and (C) a photopolymerisation initiator, characterised in that the polyisocyanate compound has the formula wherein R I is a hydrogen atom or a methyl group and n is an integer of from 1 to 20.
Claim 2
Dependent Claim 88 words
An ultraviolet curable ink composition comprising, as main components, (A) a polyurethane poly (meth) acrylate obtained by reacting a polyisocyanate compound with a hydroxyl group containing (meth) acrylate and having, in one molecule, at least two (meth) acryloyl groups and at least two urethane bonds, (B) a radical polymerisable low molecular weight compound, and (C) a photopolymerisation initiator, characterised in that the polyisocyanate compound has the formula wherein R I is a hydrogen atom or a methyl group and n is an integer of from 1 to 20.
Claim 3
Dependent Claim 40 words
The ink composition according to claim 1, which comprises from 10 to 80 parts by weight of component (A), from 20 to 90 parts by weight of component (B), and from 0.1 to 15 parts by weight of component (C).
Claim 4
Dependent Claim 41 words
The ink composition according to claim 1, wherein the molar ratio of the isocyanate groups to the hydroxyl groups in the polyisocyanate compound and the hydroxyl group-containing (meth) acrylate constituting the polyurethane poly (meth) acrylate (A), is from 1:1 to 1:1.2.
Claim 5
Dependent Claim 16 words
The ink composition according to claim 1, wherein the hydroxyl group-containing (meth) acrylate is 2-hydroxyethyl acrylate.
Claim 6
Dependent Claim 27 words
The ink composition according to Claim 1, wherein the polyisocyanate compound is a compound of the formula: wherein n' is an integer of from 1 to 5.
Claim 7
Dependent Claim 21 words
The ink composition according to Claim 1, wherein the radical polymerizable low molecular weight compound (B) contains a phosphorus-containing vinyl monomer.
Claim 8
Dependent Claim 17 words
The ink composition according to Claim 1, wherein the photopolymerization initiator (C) is anthraquinone or its derivative.
Claim 9
Dependent Claim 64 words
The ink composition according to Claim 1, wherein the photopolymerization initiator (C) is a combination of a) anthraquinone or its derivative, b) a compound of the formula: wherein each of R 1 and R 2 is a hydrogen atom or an alkyl group, and c) a compound of the formula: wherein each of R3 and R4 is a hydrogen atom or an alkyl group.

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