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High strength feldspathic porcelain and method for producing the same

Assignee: NGK Insulators Ltd
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Filing: 1986-01-10
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Granted: —
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Expires: 2006-01-10
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Abstract

Abstract High strength porcelain having an unglazed bending strength of more than 1,400 kg/cm 2 and consisting essentially of 22-85% by weight of SiO 2 , 10-75% by weight of Aℓ 2 O 3 , and 1.5-6.5% by weight of K 2 0 and/or Na 2 0. The porcelain has a total degree of crystallinity of more than 40% by weight, and a crystalline grain size of not greater than 20 µm, and it is free from defects of larger than 40 µm. The porcelain is produced by pulverizing a starting material mixture of quartz- feldspar-alumina system so that 85-95% by weight of particles thereof have a grain size of not greater than 10 µm, calcining the mixture, adding clay-mineral material therein, pulverizing so that the clay-mineral-added mixture contains less than 85% by weight of particles with a grain size of not greater than 10 µm, forming, drying, and firing at 1,000-1,400°C.

Inventors

  • 👤 Isao Oda

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-04 22:42
CPC Classifications
C; C04; C04B; C04B33/00; C04B33/24; C04B33/26

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 161 words
High strength feldspathic porcelain with an unglazed bending strength of more than 1,400 kg/cm 2 , the porcelain consisting essentially of 22-85% by weight of Si0 2 , 10-73% by weight of Aℓ 2 O 3 , and 1.5-6.5% by weight of at least one oxide selected from the group consisting of K 2 0 and Na 2 0; the porcelain having a crystal phase formed of at least one kind crystals selected from the group consisting of corundum, mullite, cristobalite, and quartz, a total degree of crystallinity of said crystal phase being more than 40% by weight, degree of crystallization for said crystals being selected in ranges of not greater than 60% by weight for corundum, 5-50% by weight for mullite, not greater than 40% by weight for cristobalite, and not greater than 10% by weight for quartz, grain size of said crystals being not greater than 20 µm, and said porcelain being free from defects larger than 40 µm.
Claim 2
Dependent Claim 161 words
High strength feldspathic porcelain with an unglazed bending strength of more than 1,400 kg/cm 2 , the porcelain consisting essentially of 22-85% by weight of Si0 2 , 10-73% by weight of Aℓ 2 O 3 , and 1.5-6.5% by weight of at least one oxide selected from the group consisting of K 2 0 and Na 2 0; the porcelain having a crystal phase formed of at least one kind crystals selected from the group consisting of corundum, mullite, cristobalite, and quartz, a total degree of crystallinity of said crystal phase being more than 40% by weight, degree of crystallization for said crystals being selected in ranges of not greater than 60% by weight for corundum, 5-50% by weight for mullite, not greater than 40% by weight for cristobalite, and not greater than 10% by weight for quartz, grain size of said crystals being not greater than 20 µm, and said porcelain being free from defects larger than 40 µm.
Claim 3
Dependent Claim 114 words
High strength feldspathic porcelain as set forth in claim 1, wherein said unglazed bending strength is more than 1,800 kg/cm 2 , and the porcelain consists essentially of 30-60% by weight of Si0 2 , 30-73% by weight of Aℓ 2 O 3 , not greater than 1.5% by weight of Fe 2 0g, not greater than 1.5% by weight of Ti0 2 , not greater than 0.7% by weight of CaO, not greater than 0.5% by weight of MgO, and 1.5-6.5% by weight of at least one oxide selected from the group consisting of K 2 0 and Na 2 0; and content of corundum in said crystal phase is 20-60% by weight.
Claim 4
Dependent Claim 123 words
High strength feldspathic porcelain as set forth in claim 2, wherein said porcelain consists essentially of 30-60% by weight of Si0 2 , 30-73% by weight of A2 2 O 3 , not greater than 1.5% by weight of Fe 2 O 3 , not greater than 1.5% by weight of Ti0 2 , not greater than 0.7% by weight of CaO, not greater than 0.5% by weight of MgO, 1.5-6.5% by weight of at least one oxide selected from the group consisting of K 2 0 and Na 2 0, and not greater than 20% by weight of at least one oxide selected from the group consisting of Ti0 2 , BaO, Zr0 2 , B 2 O 3 , and ZnO.
Claim 5
Dependent Claim 20 words
High strength feldspathic porcelain as set forth in claim 1, 2 or 3, wherein said porcelain is for porcelain insulators.
Claim 6
Dependent Claim 19 words
High strength feldspathic porcelain as set forth in claim 1, 2 or 3, wherein said porcelain is acid resisting.
Claim 7
Independent Claim 177 words
A method for producing high strength feldspathic porcelain having an unglazed bending strength of more than 1,400 kg/cm 2 and being free from defects larger than 40 µm, comprising steps of preparing a starting material selected from the group consisting of quartz type material, feldspathic material, and alumina type material; pulverizing the starting material so as to make 85-95% by weight thereof into particles with effective diameters not greater than 10 pm; calcining the pulverizing material at 900-1,400°C; mixing clay-mineral material with the calcined material; pulverizing mixture thus produced so as to make not greater than 85% by weight thereof into particles with effective diameters not greater than 10 µm; forming and drying the pulverized mixture; and firing the formed and dried mixture at 1,000-1,400°C, whereby said porcelain thus produced contains a crystal phase formed of at least one kind crystals selected from the group consisting of corundum, mullite, cristobalite, and quartz, said crystal phase having a grain size of not greater than 20 µm and a total degree of crystallinity of more than 40% by weight.
Claim 8
Independent Claim 177 words
A method for producing high strength feldspathic porcelain having an unglazed bending strength of more than 1,400 kg/cm 2 and being free from defects larger than 40 µm, comprising steps of preparing a starting material selected from the group consisting of quartz type material, feldspathic material, and alumina type material; pulverizing the starting material so as to make 85-95% by weight thereof into particles with effective diameters not greater than 10 pm; calcining the pulverizing material at 900-1,400°C; mixing clay-mineral material with the calcined material; pulverizing mixture thus produced so as to make not greater than 85% by weight thereof into particles with effective diameters not greater than 10 µm; forming and drying the pulverized mixture; and firing the formed and dried mixture at 1,000-1,400°C, whereby said porcelain thus produced contains a crystal phase formed of at least one kind crystals selected from the group consisting of corundum, mullite, cristobalite, and quartz, said crystal phase having a grain size of not greater than 20 µm and a total degree of crystallinity of more than 40% by weight.
Claim 9
Dependent Claim 52 words
A method for producing high strength feldspathic porcelain as set forth in claim 6, wherein said starting material after calcination consists essentially of not greater than 85% by weight of quartz type material, 15 - 75% by weight of feldspathic material, and not greater than 85% by weight of alumina type material.
Claim 10
Dependent Claim 36 words
A method for producing high strength feldspathic porcelain as set forth in claim 6, wherein said mixture consists essentially of 45-80% by weight of said calcined starting material and 20-55% by weight of the clay-mineral material.
Claim 11
Dependent Claim 24 words
A method for producing high strength feldspathic porcelain as set forth in claim 6, 7 or 8, wherein said porcelain is for porcelain insulators.
Claim 12
Dependent Claim 23 words
A method for producing high strength feldspathic porcelain as set forth in claim 6, 7 or 8, wherein said porcelain is acid resisting.
Claim 13
Independent Claim 177 words
A method for producing high strength feldspathic porcelain having an unglazed bending strength of more than 1,400 kg/cm 2 and being free from defects larger than 40 µm, comprising steps of preparing a starting material selected from the group consisting of quartz type material, feldspathic material, and alumina type material; pulverizing the starting material so as to make 85-95% by weight thereof into particles with effective diameters not greater than 10 µm; calcining the pulverizing material at 900-1,400°C; pulverizing the calcined material: mixing clay-mineral material with the calcined material so as to make not greater than 85% by weight thereof into particles with effective diameters not greater than 10 pm; forming and drying the pulverized mixture; and firing the formed and dried mixture at 1,000-1,400°C, whereby said porcelain thus produced contains a crystal phase formed of at least one kind crystals selected from the group consisting of corundum, mullite, cristobalite, and quartz, said crystal phase having a grain size of not greater than 20 µm and a total degree of crystallinity of more than 40% by weight.
Claim 14
Independent Claim 177 words
A method for producing high strength feldspathic porcelain having an unglazed bending strength of more than 1,400 kg/cm 2 and being free from defects larger than 40 µm, comprising steps of preparing a starting material selected from the group consisting of quartz type material, feldspathic material, and alumina type material; pulverizing the starting material so as to make 85-95% by weight thereof into particles with effective diameters not greater than 10 µm; calcining the pulverizing material at 900-1,400°C; pulverizing the calcined material: mixing clay-mineral material with the calcined material so as to make not greater than 85% by weight thereof into particles with effective diameters not greater than 10 pm; forming and drying the pulverized mixture; and firing the formed and dried mixture at 1,000-1,400°C, whereby said porcelain thus produced contains a crystal phase formed of at least one kind crystals selected from the group consisting of corundum, mullite, cristobalite, and quartz, said crystal phase having a grain size of not greater than 20 µm and a total degree of crystallinity of more than 40% by weight.
Claim 15
Dependent Claim 50 words
A method for producing high strength feldspathic porcelain as set forth in claim 11, wherein said starting material after calcination consists essentially of not greater than 85% by weight of quartz type material, 15-75% by weight of feldspathic material, and not greater than 85% by weight of alumina type material.
Claim 16
Dependent Claim 36 words
A method for producing high strength feldspathic porcelain as set forth in claim 11, wherein said mixture consists essentially of 45-80% by weight of said calcined starting material and 20-55% by weight of the clay-mineral material.
Claim 17
Dependent Claim 24 words
A method for producing high strength feldspathic porcelain as set forth in claim 11, 12 or 13, wherein said porcelain is for porcelain insulators.
Claim 18
Dependent Claim 23 words
A method for producing high strength feldspathic porcelain as set forth in claim 11, 12 or 13, wherein said porcelain is acid resisting.

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