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EP0187692A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Dental compositions, fired dental porcelains and processes for making and using same

Assignee: Excelco International Inc
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Filing: 1986-01-02
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Granted: —
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Expires: 2006-01-02
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Abstract

Abstract A composition for making a fired dental porcelain is disclosed which composition comprises a powder dental porcelain frit material and a second material. The second material is selectively etchable from a fired dental porcelain prepared from the composition and the second material can, upon such firing of the composition, maintain a separate phase so that, when the composition is formed into a fired dental porcelain having a dental porcelain surface to be bonded to a dental substrate and the dental porcelain surface is etched to remove second material therefrom, the porosity and surface area of the dental porcelain surface will be increased to provide enhanced bonding to the dental porcelain surface the dental substrate. Also disclosed are fired dental porcelains prepared therefrom and methods of making and using same.

Inventors

  • 👤 Irving Klaus
  • 👤 Warren Herbstman
  • 👤 Juan Jairo Lopez

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 03:40
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/009; A; A61; A61K; A61K6/00; A61K6/15; A61K6/17; A61K6/70; A61K6/78; A61K6/80; A61K6/802; A61K6/807; A61K6/818; C04B33/00; C04B33/24; C04B41/53; C04B41/5338; C04B41/80; C04B41/91

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 168 words
A process for making a fired, etched dental porcelain for bonding to a dental substrate, said process being characterized by the steps of providing a dental porcelain composition comprised of a powder dental porcelain frit material and a second material which is selectively chemically etchable from a fired dental porcelain prepared from the composition and which, upon firing of the composition, maintains a separate phase with respect to said powder dental frit material; forming said dental porcelain composition into a predetermined shape having a dental porcelain surface for attachment to a dental substrate; firing the dental porcelain composition in the predetermined shape so that the second material in the composition is maintained in the fired dental porcelain as said separate phase; and chemically etching said dental porcelain surface with a chemical etching material which selectively removes said second material from said dental porcelain surface to increase the porosity of such dental porcelain surface so as to provide enhanced bonding of said dental porcelain surface to a dental substrate.
Claim 2
Dependent Claim 168 words
A process for making a fired, etched dental porcelain for bonding to a dental substrate, said process being characterized by the steps of providing a dental porcelain composition comprised of a powder dental porcelain frit material and a second material which is selectively chemically etchable from a fired dental porcelain prepared from the composition and which, upon firing of the composition, maintains a separate phase with respect to said powder dental frit material; forming said dental porcelain composition into a predetermined shape having a dental porcelain surface for attachment to a dental substrate; firing the dental porcelain composition in the predetermined shape so that the second material in the composition is maintained in the fired dental porcelain as said separate phase; and chemically etching said dental porcelain surface with a chemical etching material which selectively removes said second material from said dental porcelain surface to increase the porosity of such dental porcelain surface so as to provide enhanced bonding of said dental porcelain surface to a dental substrate.
Claim 3
Dependent Claim 30 words
A process according to Claim 1, characterized in that said powder dental porcelain frit material comprises feldspar and at least one of glass, kaolin, silica, boric oxide or mixtures thereof.
Claim 4
Dependent Claim 35 words
A process according to Claim 1 or 2, characterized in that said powder dental porcelain includes at least one additive selected from the group consisting of pigment, opaquing agent, binder, fluxing agent, and mixtures thereof.
Claim 5
Dependent Claim 38 words
A process according to Claim 3, characterized in that the fluxing agent is selected from .the group consisting of lithium oxide, sodium oxide, potassium oxide, strontium oxide, calcium oxide, magnesium oxide, precursers of such oxides and mixtures thereof.
Claim 6
Dependent Claim 29 words
A process according to Claim 1, characterized in that said powder dental porcelain frit material comprises potassium feldspar, glass, and lithium carbonate which has been fired, cooled and powdered.
Claim 7
Dependent Claim 45 words
A process according to Claim 1, characterized in that said second material comprises an etchable material selected from the group consisting of flint, vitreous silica, fused silica, fumed silica, quartz, CaSiF 4 2H20, tridymite, natural opal, Zr0 2 , ZrSi0 4 , and mixtures thereof.
Claim 8
Dependent Claim 31 words
A process according to Claim 1 or 6, characterized in that said second material has an average particle size in the range of from about 0.1 microns to about 200 microns.
Claim 9
Dependent Claim 31 words
A process according to Claim 1 or 6, characterized in that said second material is present in said composition in an amount of from about 0.01 to about 5% by weight.
Claim 10
Dependent Claim 31 words
A process according to Claim 1, characterized in that said second material is a hydrofluoric acid etchable material and said dental porcelain surface is etched with a hydrofluoric acid containing composition.
Claim 11
Dependent Claim 25 words
A process according to Claim 1, characterized in that the composition is fired in the form of a dental veneer, inlay, crown, denture or jacket.
Claim 12
Dependent Claim 147 words
A process for tooth repair being characterized by the steps of providing a fired dental porcelain comprising a fired composition including a powder dental porcelain frit material and a second material which is selectively chemically etchable from said fired dental porcelain and which maintains a separate phase with respect to said powder dental powder frit material upon such firing, wherein said fired dental porcelain has a dental porcelain surface shaped to be bonded to a surface of a tooth to be repaired and said dental porcelain surface is chemically etched with a chemical etching material to remove second material therefrom to increase the porosity of said dental porcelain surface and thereby provide enhanced bonding of said dental porcelain surface to such a surface of a tooth; and bonding said etched dental porcelain surface of the fired dental porcelain to a surface of a tooth to be repaired.
Claim 13
Dependent Claim 147 words
A process for tooth repair being characterized by the steps of providing a fired dental porcelain comprising a fired composition including a powder dental porcelain frit material and a second material which is selectively chemically etchable from said fired dental porcelain and which maintains a separate phase with respect to said powder dental powder frit material upon such firing, wherein said fired dental porcelain has a dental porcelain surface shaped to be bonded to a surface of a tooth to be repaired and said dental porcelain surface is chemically etched with a chemical etching material to remove second material therefrom to increase the porosity of said dental porcelain surface and thereby provide enhanced bonding of said dental porcelain surface to such a surface of a tooth; and bonding said etched dental porcelain surface of the fired dental porcelain to a surface of a tooth to be repaired.
Claim 14
Dependent Claim 30 words
A process according to Claim 11, characterized in that said powder dental porcelain frit material comprises feldspar and at least one of glass, kaolin, silica, boric oxide or mixtures thereof.
Claim 15
Dependent Claim 35 words
A process according to Claim 11 or 12, characterized in that said powder dental porcelain includes at least one additive selected from the group consisting of pigment, opaquing agent, binder, fluxing agent, and mixtures thereof.
Claim 16
Dependent Claim 38 words
A process according to Claim 13, characterized in that the fluxing agent is selected from the group consisting of lithium oxide, sodium oxide, potassium oxide, strontium oxide, calcium oxide, magnesium oxide, precursers of such oxides and mixtures thereof.
Claim 17
Dependent Claim 29 words
A process according to Claim 11, characterized in that said powder dental porcelain frit material comprises potassium feldspar, glass, and lithium carbonate which has been fired, cooled and powdered.
Claim 18
Dependent Claim 45 words
A process according to Claim 11, characterized in that said second material comprises an etchable material selected from the group consisting of flint, vitreous silica, fused silica, fumed silica, quartz, CaSiF 4 2H20, tridymite, natural opal, ZrO 2 , ZrSi0 4 , and mixtures thereof.
Claim 19
Dependent Claim 31 words
A process according to Claim 11 or 16, characterized in that said second material has an average particle size in the range of from about 0.1 microns to about 200 microns.
Claim 20
Dependent Claim 31 words
A process according to Claim 11 or 16, characterized in that said second material is present in said composition in an amount of from about 0.01 to about 5% by weight.
Claim 21
Dependent Claim 32 words
A ' process according to Claim 11, characterized in that said second material is a hydrofluoric acid etchable material and said dental porcelain surface is etched with a hydrofluoric acid containing composition.
Claim 22
Dependent Claim 24 words
A process according to Claim 11, characterized in that the fired dental porcelain is in the form of dental veneer, inlay, crown or jacket.

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