Light-sensitive silver halide photographic material

Claim 1

A light-sensitive silver halide photographic material, which comprises containing at least one coupler represented by the formula (I) shown below, at least one of the compounds represented by the formulae (XI), (XII) and (XIII) shown below and at least one of the compounds represented by the formulae (XXI), (XXII) and (XXIII): wherein Z represents a group of non-metallic atoms necessary for forming a nitrogen-containing heterocyclic ring which may have a substituent; X represents a hydrogen atom or a substituent eliminable through the reaction with the oxidized product of a color developing agent; and R represents a hydrogen atom or a substituent, wherein M represents a metal atom; X 1 and X 2 each represent an oxygen atom, a sulfur atom or - NR 5- (R 5 represents a hydrogen atom, an alkyl group, an aryl group or a hydroxyl group); X 3 represents a hydroxyl group or a mercapto group; Y represents an oxygen atom or a sulfur atom; R 1 , R 2 , R 3 and R each represent a hydrogen atom, a halogen atom, a cyano group, or an alkyl group, an aryl group, a cycloalkyl group or a heterocyclic group each of which are bonded to carbon atom directly or via a divalent linking group, provided that at least one of combination of R 1 and R 2 , and R 3 and R 4 may be formed a 5- or 6-membered ring with a carbon atom which is linked and bonded to each other; and Z 0 represents a compound capable of coordinating to M or its residual group, wherein, in the formulae (XXI) and (XXII), R 1) represents a hydrogen atom, an alkyl group, an acyl group, a sulfonyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or a trialkylsilyl group; J represents a group of non-metallic atoms necessary for forming a 5- or 6-membered ring with a carbon atom or an oxygen atom to be bonded and each of 5- or 6-membered ring may have a bis-spiro bond; R2), R 3) and R 4) each represent a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group, an alkenyl group, an alkenoxy group, an acylamino group, a halogen atom, an alkylthio group, an arylthio group, an alkoxycarbonyl group, an acyloxy group, an acyl group or a sulfonamide group, and these groups represented by the R 2) , R 3) and R 4 ) may be the same or different from each other; R 5) , R 6) and R7) each represent a hydrogen atom, a hydroxy group, an alkyl group, an alkenyl group, an alkoxy group, an aryl group, an aryloxy group, an acyloxy group or an alkoxycarbonyl group, provided that the total carbon number of R 5) to R 7) is 8 or more, and these groups represented by the R5) , R6) and R 7) may be the same or different from each other; in the formula (XXIII), R 8) represents an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an R 12) -CO- group, an R 13) -S0 2 - group or an R 14) -NHCO- group; R 9) and R 10) each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkoxy group or an alkenoxy group; R 11) represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group; and R 12) , R 13) and R 14) each represent an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.