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Silane derivatives which improve the properties of polyphenylene oxide-polyamide compositions

Assignee: General Electric Co
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Filing: 1985-10-31
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Granted: —
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Expires: 2005-10-31
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Abstract

Abstract Novel polyphenylene ether-polyamide compositions having improved compatibility, elongation and impact properties as well as improved processability are prepared comprising one or more polyphenylene ethers, one or more polyamides and a property improving silane derivative compound having in the molecule both (a) at least one silicon bonded to a carbon through an oxygen link and (b) at least one ethylenic carbon-carbon double bond or carbon-carbon triple bond and/or functional group selected from the group consisting of an amine group or a mercapto group, with the proviso that the functional group is not directly bonded to a silicon atom. These compositions may further comprise a polymeric impact modifier therefore and/or an inorganic reinforcing additive and/or other polymers including alkenyl aromatic polymers.

Inventors

  • 👤 Robert Russell Gallucci
  • 👤 Robert W. Avakian

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 10:43
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L75/00; C08L81/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 92 words
A resin composition comprising one or more polyphenylene ethers, one or more polyamides and a property improving amount of a silane derivative compound having in the molecule both (a) at least one silicon bonded to carbon through an oxygen link and (b) at least one ethylenic carbon-carbon double bond or carbon-carbon triple bond and/or functional group selected from the group consisting of an amine group or a mercapto group with the proviso that the functional group is not directly bonded to a silicon atom, for improved impact strength, compatibility, elongation and/or processability.
Claim 2
Dependent Claim 92 words
A resin composition comprising one or more polyphenylene ethers, one or more polyamides and a property improving amount of a silane derivative compound having in the molecule both (a) at least one silicon bonded to carbon through an oxygen link and (b) at least one ethylenic carbon-carbon double bond or carbon-carbon triple bond and/or functional group selected from the group consisting of an amine group or a mercapto group with the proviso that the functional group is not directly bonded to a silicon atom, for improved impact strength, compatibility, elongation and/or processability.
Claim 3
Dependent Claim 39 words
The resin composition of Claim 1 wherein the property improving silane derivative is selected from the group consisting of gamma aminopropyl triethoxy silane; 2-(3-cyclohexenyl)ethyl trimethoxy silane; 1,3-divinyl tetraethyoxy silane; vinyl-tris-(2-methoxy thoxy)silane; 5-(bicyclo hextenyl)triethoxy silane and gamma mercapto-propyl trimethoxy silane.
Claim 4
Dependent Claim 33 words
The resin composition of Claim 1 wherein the property improving amount of the silane derivative compound is an amount up to about 4% by weight based on the weight of the total composition.
Claim 5
Dependent Claim 36 words
The resin composition of Claim 1 wherein the property improving amount of the silane derivative compound is an amount of from about 0.05 to about 2% by weight based on the weight of the total composition.
Claim 6
Dependent Claim 39 words
The resin composition of Claim 1 wherein the weight ratio of polyphenylene ether to polyamide is from about 5 to about 95% by weight of the former to from about 95 to about 5% by weight of the latter.
Claim 7
Dependent Claim 39 words
The resin composition of Claim 1 wherein the weight ratio of polyphenylene ether to polyamide is from about 30 to about 70% by weight of the former to from about 70 to about 30% by weight of the latter.
Claim 8
Dependent Claim 105 words
The composition of Claim 1 wherein the polyphenylene ether is a homopolymer or a copolymer having units with the repeating structural formula: wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next joining unit, and n is a positive integer and is at least 50, and each Q is independently a monovalent substituent selected from a group consisting of hydrogen, halogen, hydrocarbon and ' hydrocarbonoxy groups free of a tertiary alpha-carbon atom and halohydrocarbon and halohydrocarbonoxy groups free of a tertiary alpha-carbon atom and having at least 2 carbon atoms between the halogen atom and the phenyl nucleus.
Claim 9
Dependent Claim 30 words
The composition of Claim 1 wherein the polyamide is selected from the group consisting of polyamide 6; polyamide 6,6; polyamide 12; polyamide 6/10, polyamide 4/6; polyamide 6/I and mixtures thereof.
Claim 10
Dependent Claim 11 words
The composition of Claim 8 wherein the polyamide is polyamide 6.
Claim 11
Dependent Claim 11 words
The composition of Claim 8 wherein the polyamide is polyamide 6/6.
Claim 12
Dependent Claim 11 words
The composition of Claim 8 wherein the polyamide is polyamide 4/6.
Claim 13
Dependent Claim 26 words
The composition of Claim 1 which further comprises not more than about 50% by weight based on the total composition of a rubbery high-molecular weight polymer.
Claim 14
Dependent Claim 29 words
The composition of Claim 11 wherein the rubbery high-molecular weight polymer is present in an amount of not more than about 35% by weight based on the total composition.
Claim 15
Dependent Claim 20 words
The composition of Claim 11 wherein the rubbery high-molecular weight polymer is an hydrogenated or non-hydrogenated styrene-butadiene diblock- or triblock-copolymer.
Claim 16
Dependent Claim 25 words
The composition of Claim 1 which further comprises not more than about 50% by weight based on the total composition of a alkenyl aromatic polymer.
Claim 17
Dependent Claim 16 words
The composition of Claim 14 wherein the alkenyl aromatic compound is a styrene homopolymer or copolymer.
Claim 18
Dependent Claim 17 words
The composition of Claim 15 wherein the alkenyl aromatic compound is a rubber modified high impact polystyrene.

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