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Multilayer coated cemented carbides

Assignee: Sumitomo Electric Industries Ltd
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Filing: 1985-05-14
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Granted: —
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Expires: 2005-05-14
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Abstract

Abstract Multilayer coated cemented carbides of high wear resistance and toughness are provided comprising a substrate of cemented carbide, an inner layer contacted with the surface of the substrate, and an outer layer contacted with the inner layer, the inner layer being a single layer and/or laminated layers consisting of at least one member selected from the group consisting of carbides, nitrides, carbonitrides, carboxynitrides, oxynitrides, boronitrides and borocarbonitrides of Ti, and the outer layer being a multilayer with a total thickness of 5 to 20 µm, consisting of a plurality of Al 2 O 3 layer each having a thickness of 0.01 to 2 µm, each consisting of an Al 2 O 3 film in which titanium oxide is dissolved or at most 30 vol % of titanium oxide is coexistent and being respectively divided by interlayers each having a thickness of 0.01 to 2 µm and each consisting of TiC, TiN, TiCN,TiCNO, TiNO, Ti oxides, Ti(B, N), Ti(B, N, C), SiC, AIN and AION. The carbides may be used for cutting tools.

Inventors

  • 👤 Minoro Nakano

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 13:09
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/32; C23C30/00; C23C30/005; C23C16/02; C23C16/0272; C23C28/00; C23C28/04; C23C28/042; Y; Y10; Y10S; Y10S428/00; Y10S428/922; Y10S428/9265; Y10S428/932; Y10T; Y10T428/00; Y10T428/12; Y10T428/12493; Y10T428/12535; Y10T428/12576; Y10T428/24; Y10T428/24942; Y10T428/2495; Y10T428/24967; Y10T428/24975; Y10T428/24983

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 176 words
A multilayer coated cemented carbide comprising a substrate of cemented carbide, an inner layer contacted with the surface of the substrate and an outer layer contacted with the inner layer, the said inner layer being at least one layer consisting of at least one member selected from the group consisting of carbides, nitrides, carbonitrides, carboxynitrides, oxynitrides, boronitrides and borocarbonitrides of Ti, and the said outer layer being a multilayer with a total thickness of 3 µm to 20 µm, preferably of 5 to 20 µm, consisting of a plurality of A1 2 0 3 layers each having a thickness of 0.01 to 2 µm, each consisting of an Al 2 0 3 film in which titanium oxide is dissolved or at most 30 vol % of titanium oxide is coexistent and being respectively divided by interlayers each having a thickness of 0.01 to 2 µm and each consisting of at least one member selected from the group consisting of TiC, TiN, TiCN, TiCNO, TiCO, TiNO, Ti oxides, Ti(B, N), Ti(B, N, C), SiC, A1N and A10N.
Claim 2
Dependent Claim 176 words
A multilayer coated cemented carbide comprising a substrate of cemented carbide, an inner layer contacted with the surface of the substrate and an outer layer contacted with the inner layer, the said inner layer being at least one layer consisting of at least one member selected from the group consisting of carbides, nitrides, carbonitrides, carboxynitrides, oxynitrides, boronitrides and borocarbonitrides of Ti, and the said outer layer being a multilayer with a total thickness of 3 µm to 20 µm, preferably of 5 to 20 µm, consisting of a plurality of A1 2 0 3 layers each having a thickness of 0.01 to 2 µm, each consisting of an Al 2 0 3 film in which titanium oxide is dissolved or at most 30 vol % of titanium oxide is coexistent and being respectively divided by interlayers each having a thickness of 0.01 to 2 µm and each consisting of at least one member selected from the group consisting of TiC, TiN, TiCN, TiCNO, TiCO, TiNO, Ti oxides, Ti(B, N), Ti(B, N, C), SiC, A1N and A10N.
Claim 3
Dependent Claim 50 words
A multilayer coated cemented carbide as claimed in claim 1, wherein the outer layer is further coated with an outermost layer with a thickness of 0.1 to 5 µm, consisting of at least one member selected from the group consisting of nitrides of Ti, Zr and Hf, BN and A1N.
Claim 4
Dependent Claim 29 words
A multilayer coated cemented carbide as claimed in claim 2, wherein the outermost layer is a hard BN film with an Hv hardness of at least 3000 kg/mm .
Claim 5
Dependent Claim 41 words
A multilayer coated cemented carbide as claimed in any one of claims I to 3, wherein the titanium oxide is dissolved in the Al 2 O 3 film in a proportion of 0.01 to 0.1 vol to form a solid solution.
Claim 6
Dependent Claim 57 words
A process for the preparation of a multilayer coated cemented carbide as claimed in any one of claims 1 to 4, wherein the Al 2 O 3 film containing titanium oxide dissolved or coexistent is prepared by feeding simultaneously a titanium halide or organo titanium compound when Al 2 O 3 is formed by chemical vapor deposition.
Claim 7
Dependent Claim 18 words
A cutting tool comprising a multilayer coated cemented carbide as claimed in any one of the preceding claims.

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