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EP0159568A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

The use of higher alkyl modified terpolymeric silicones as fiber or textile finishes

Assignee: Union Carbide Corp
•
Filing: 1985-03-28
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Granted: —
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Expires: 2005-03-28
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Abstract

Abstract Compositions comprising higher alkyl modified epoxy silicone terpolymers having the general formula: MD x D' y D" 2 M wherein M = R 3 SIO 1/2 D = R 2 SiO D' - E-C b H 2b Si(R)O E is either D" = R'Si(R)O R + lower alkyl of 1 to 6 carbon atoms R' - high alkyl of at least 6 carbon atoms r = 0 to 7 b= 2 to 12 x = 20 to 500 y = 4 to 15 z = 4 to 40 = preferably at least 0.01 = preferably at least 0.03 said higher alkyl modified epoxy silicones are formed into aqueous emulsions using anionic and non-ionic emulsifiers. The resulting emulsions are useful as fiber and/or textile finishes.

Inventors

  • 👤 George Homer Greene
  • 👤 Robert Aniello Daniele, Jr.

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-05 18:29
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; D06M15/65; C; C08; C08G; C08G77/00; C08G77/04; C08G77/38; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962; Y10T428/2964; Y10T428/2965; Y10T428/2967; Y10T428/2969

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 156 words
A fiber or a textile treated with a higher alkyl modified epoxy silicone terpolymer having the general formula: MD x D' y D" z M wherein M in each case is an end-blocking unit of the formula: R 3 SiO 1/2 ; D is a siloxy unit of the formula: R 2 SiO: D' is an epoxy containing siloxy unit of the formula: where E is an epoxy containing group selected from either , or where n is from 1 to 12, D" is a siloxy unit of the formula R'Si(R)O; R is a lower alkyl group having 1 to 6 carbon atoms: R' is a higher alkyl group of at least 6 carbon atoms: x is an integer of 20 to 500; y is an integer of 4 to 15: z is an integer of 4 to 40: b is an integer of 2 to 12: and r is an integer of 0 to 7.
Claim 2
Dependent Claim 156 words
A fiber or a textile treated with a higher alkyl modified epoxy silicone terpolymer having the general formula: MD x D' y D" z M wherein M in each case is an end-blocking unit of the formula: R 3 SiO 1/2 ; D is a siloxy unit of the formula: R 2 SiO: D' is an epoxy containing siloxy unit of the formula: where E is an epoxy containing group selected from either , or where n is from 1 to 12, D" is a siloxy unit of the formula R'Si(R)O; R is a lower alkyl group having 1 to 6 carbon atoms: R' is a higher alkyl group of at least 6 carbon atoms: x is an integer of 20 to 500; y is an integer of 4 to 15: z is an integer of 4 to 40: b is an integer of 2 to 12: and r is an integer of 0 to 7.
Claim 3
Dependent Claim 74 words
The fiber or the textile as claimed in claim 1 wherein D' is a siloxy unit of the formula: R is methyl, R' is an alkyl group having 10 to 30 carbon atoms, x is an integer of 30 to 350. y is an integer of 5 to 12, z is an integer of 7 to 30. the ratio of y/x+y+z is at least 0.01 and the ratio of y+z/x+y+z is at least 0.03.
Claim 4
Dependent Claim 56 words
The fiber or textile as claimed in claim 2 wherein R' is an octadecyl group, x is an integer of 100 to 300, y is an integer of 8 to 12, z is an integer of 10 to 28, the ratio of y/x+y+z is 0.01 to 0.2 and the ratio of y+z/x+y+z is 0.03 to 0.5.
Claim 5
Dependent Claim 115 words
The fiber or textile as claimed in claim 1 to 3 wherein the silicone has the general formula: MD 300 D' 12 D" 12 M or MD 3000 D' 9 D" 12 M or MD 247.5 D' 10 D" 10 M or MD 250 D' 8 D" 10 M or MD 250 D' 8 D" 5 M or MD 115D D' 4 D" 11 M or MD 30 D' 8 D" 22 M or MD 250 D' 8 D" 22 M or MD 247.5 D' 10 D" 7.5-10 M or MD 250 D' 8 D" 10 M wherein R' is an octadecyl group or decyl group or a hexacosanyl group, C 26 H 53 .

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