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EP0149190A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Flame retardant copolyetherester elastomers

Assignee: General Electric Co
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Filing: 1984-12-20
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Granted: —
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Expires: 2004-12-20
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Abstract

Abstract Flame retardant copolyetherester resins and blend compositions are provided for by incorporating therein specific halogenated organic flame retardants.

Inventors

  • 👤 Surendra Hukamchand Agarwal

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-25 09:46
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L67/025

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 253 words
A flame retardant low-modulus copolyetherester composition comprising: (i) a low-modulus copolyetherester resin; (ii) a flame retarding amount of a flame retarding agent selected from the group consisting essentially of (a) an aromatic carbonate copolymer in which from 25 to 75 weight percent of the repeating units comprise chloro- or bromo-substituted dihydric phenol units and the remainder of the repeating units comprise dihydric phenol, glycol or dicarboxylic acid units; (b) an aromatic carbonate polymer derived from dihydric phenols and containing terminal brcmine-substituted aromatic radicals, said polymer being represented by the following formula: wherein n is an integer of 2 - 4, R 1 and R 2 are independently halogen, alkyl or aralkyl, X 1 and X 2 are bromo- or chloro-, p and g are integers of from 0 to 4, and m is an integer of from 2 to about 400; (c) a high-molecular weight brominated epoxy having aromatically bound bromine; and (d) brominated polyphenylene oxides having repeating units of the following structure: wherein X 6 is independently a hydrocarbon radical, a halo-hydrocarbon radical having at least two carbon atoms between the halogen and the phenol nucleus, a hydrocarbonoxy radical, and a halohydrocarbonoxy radical having at least two carbon atoms between the halogen and the phenol nucleus, r is an integer of from 1 to 4, b is an integer of from 0 to 3 provided r + b is less than or equal to 4; (iii) optionally, an effective amount of a flame retardant synergist; and (iv) optionally, a second thermoplastic polymer.
Claim 2
Dependent Claim 253 words
A flame retardant low-modulus copolyetherester composition comprising: (i) a low-modulus copolyetherester resin; (ii) a flame retarding amount of a flame retarding agent selected from the group consisting essentially of (a) an aromatic carbonate copolymer in which from 25 to 75 weight percent of the repeating units comprise chloro- or bromo-substituted dihydric phenol units and the remainder of the repeating units comprise dihydric phenol, glycol or dicarboxylic acid units; (b) an aromatic carbonate polymer derived from dihydric phenols and containing terminal brcmine-substituted aromatic radicals, said polymer being represented by the following formula: wherein n is an integer of 2 - 4, R 1 and R 2 are independently halogen, alkyl or aralkyl, X 1 and X 2 are bromo- or chloro-, p and g are integers of from 0 to 4, and m is an integer of from 2 to about 400; (c) a high-molecular weight brominated epoxy having aromatically bound bromine; and (d) brominated polyphenylene oxides having repeating units of the following structure: wherein X 6 is independently a hydrocarbon radical, a halo-hydrocarbon radical having at least two carbon atoms between the halogen and the phenol nucleus, a hydrocarbonoxy radical, and a halohydrocarbonoxy radical having at least two carbon atoms between the halogen and the phenol nucleus, r is an integer of from 1 to 4, b is an integer of from 0 to 3 provided r + b is less than or equal to 4; (iii) optionally, an effective amount of a flame retardant synergist; and (iv) optionally, a second thermoplastic polymer.
Claim 3
Dependent Claim 183 words
The composition of claim 1 wherein the copolyetherester resin consists essentially of a multiplicity of recurring intralinear long-chain and short-chain ester units connected head to tail through ester linkages, said long-chain ester units being represented by the following structure: and said short-chain ester units being represented by the following structure: wherein G is a divalent radical remaining after . removal of terminal hydroxyl groups from poly(alkylene oxide)glycols having a carbon-to-carbon ratio of from 2.0 - 4.3 and a molecular weight between about 400 to 6000; R is a divalent radical remaining after the removal of carboxy groups from one or more dicarboxylic acids having a molecular weight of less than about 300; and D is a divalent radical remaining after the removal of hydroxyl groups from one or more saturated and/or unsaturated, low-molecular weight diols having a molecular weight less than about 250, with the provisons that the short-chain ester units constitute anout 15-95% by weight, preferably from about 25-90% by weight, of the copolyetherester and, ergo, the long-chain ester units constitute about 5-85% by weight, preferably 10-75% by weight of the copolyetherester.
Claim 4
Dependent Claim 18 words
The composition of claim 2 wherein the copolyetherester is derived from butanediol, poly(tetramethylene oxide) glycol and dimethyl terephthalate.
Claim 5
Dependent Claim 18 words
The composition of claim 2 wherein the copolyetherester is derived from butanediol, hexanediol, poly(tetramethylene oxide) glycol and dimethylterephthalate.
Claim 6
Dependent Claim 19 words
The composition of claim 2 wherein the copolyetherester is derived from butanediol, butene-diol, poly(tetramethylene oxide) glycol and dimethyl terephthalate.
Claim 7
Dependent Claim 30 words
The composition of claim 1 which further comprises one or more high-molecular weight thermoplastic polymers selected from the group consisting essentially of polyesters, polycarbonates, polyolefins, styrenic resins and copolymers thereof.
Claim 8
Dependent Claim 30 words
The composition of claim 6 wherein the high-molecular weight thermoplastic polymer is a polyester represented by the formula wherein n is an integer of from about 2 to about 10.
Claim 9
Dependent Claim 11 words
The composition of claim 7 wherein the polyester is poly(butylene terephthalate).
Claim 10
Dependent Claim 14 words
The composition of claim 7 wherein the high-molecular weight thermoplastic is an" aromatic polycarbonate.
Claim 11
Dependent Claim 14 words
The composition of claim 9 wherein the polycarbonate is the polycarbonate of bisphenol A.
Claim 12
Dependent Claim 32 words
The composition of claim 1 wherein the second thermoplastic polymer is present in an amount of from about 5 to about 200 parts by weight based on 100 parts by weight copolyetherester.
Claim 13
Dependent Claim 32 words
The composition of claim 1 wherein the second thermoplastic polymer is present in an amount of from about 5 to about 100 parts by weight based on 100 parts by weight copolyetherester.
Claim 14
Dependent Claim 42 words
. The composition of claim 1 wherein the aromatic carbonate copolymer (a) is one in which from 75 to 25 weight percent of the repeating-units comprise tetrabromobisphenol-A units and from 25 to 75 weight percent of the repeating units comprise bisphenol-A units.
Claim 15
Dependent Claim 38 words
The composition of claim 1 wherein the aromatic carbonate copolymer (a) is one in which from 45-30 weight percent of the repeating units comprise tetrabromobisphenol-A and from 55 - 70 weight percent of the repeating units comprise bisphenol-A.
Claim 16
Dependent Claim 51 words
The composition of claim 1 wherein the aromatic carbonate copolymer (a) is one in which about 35 weight percent of the repeating units comprise tetrabromobisphenol-A and about 65 weight percent of the repeating units comprise bisphenol-A and wherein said copolymer has an intrinsic viscosity of from about 0.2 to about 0.7.
Claim 17
Dependent Claim 20 words
The composition of claim 1 wherein the aromatic carbonate polymer (b) has from about 2 to about 20 repeating units.
Claim 18
Dependent Claim 20 words
The composition of claim 1 wherein the aromatic carbonate polymer (b) has from about 3 to about 7 repeating units.
Claim 19
Dependent Claim 15 words
The composition of claim 1 wherein the aromatic carbonate polymer (b) is end-capped with tribromophenol.
Claim 20
Dependent Claim 34 words
The composition of claim 1 wherein the high-molecular weight brominated epoxy (c) is a . diglycidyl type polymer having aromatically bound bromine and an epoxy equivalent of from about 1700 to about 2100 g/eq.
Claim 21
Dependent Claim 33 words
The composition of claim 19 wherein the diglycidyl type polymer has about 50% aromatically bound bromine, an epoxy equivalent of about 1900 g/eq and a molecular weight of from about 2000 to 30,000.
Claim 22
Dependent Claim 13 words
The composition of claim 1 wherein the brominated polyphenylene oxide is poly(dibromophenylene oxide).
Claim 23
Dependent Claim 31 words
The composition of claim 1 wherein the flame retardant.(ii) is present in an amount of from about 0.5 to about 50 parts by weight per 100 parts by weight resinous component.
Claim 24
Dependent Claim 32 words
The composition of claim I wherein the flame retardant (ii) is present in an amount of from about 3 to about 50 parts by weight per 100 parts by weight resinous component.
Claim 25
Dependent Claim 31 words
The composition of claim 1 wherein the flame retardant (ii) is present in an amount of from about 8 to 45 parts by weight per 100 parts by weight resinous components.
Claim 26
Dependent Claim 12 words
The composition of claim 1 wherein the synergist is an antimony compound.
Claim 27
Dependent Claim 11 words
The composition of claim 25 wherein the synergist is antimony oxide.
Claim 28
Dependent Claim 29 words
The composition of claim 1 wherein the synergist is present in an amount of from about 1 to about 15 parts by weight per 100 parts resinous . components.
Claim 29
Dependent Claim 30 words
The composition of claim 1 wherein the synergist is present in an amount of from about 2 to about 10 parts by weight per 100 parts by weight resinous components.
Claim 30
Dependent Claim 38 words
The composition of claim 1 which further comprises up to 50 percent by weight of a reinforcing or filler agent selected from the group consisting essentially of carbon black, talc, mica, clay and fiberous glass and the like.
Claim 31
Dependent Claim 35 words
The composition of claim 1 which further comprises up to 25 percent by weight of a reinforcing or filler agent selected from the group consisting essentially of carbon black, talc, mica, clay and fiberous glass.
Claim 32
Dependent Claim 19 words
The composition of claim 1 which further contain an effective amount of non-dripping agent to render said compositicn non-dripping.
Claim 33
Dependent Claim 13 words
The composition of claim 31 wherein the non-dripping agent is a polytetrafluoroethylene resin.

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