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EP0126426A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Ion selective electrode and flow type ion sensor using the same

Assignee: Toshiba Corp
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Filing: 1984-05-16
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Granted: —
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Expires: 2004-05-16
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Abstract

Abstract There are disclosed an ion selective electrode comprising a polyvinyl chloride series resin plate having a through hole; conductive member disposed along the through hole; ion sensitive membrane of a polyvinyl chloride series resin membrane; and a lead wire connected to the conductive member, and the flow type ion sensor comprises a plurality of the ion selective electrodes mutually integrally associated with each other with the interposition of electrical insulating members so that through holes of the respective ion selective electrodes may define a flow passage for a liquid to be measured, and a flow type ion sensor using the same.The ion selective electrode and flow type ion sensor using the same of this invention allow the measurement in a smaller amount of the sample to be measured and are excellent in the adhesion of the ion sensitive membranes, therefore they have ' effects of a stable potential supply and a prolonged life time, and these industrial merits are highly great.

Inventors

  • 👤 Ken-Ichi Kanno
  • 👤 Tetsuya Gatayama
  • 👤 Masao Koyama

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-01 17:59
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/28; G01N27/30; G01N27/333; G01N27/3335

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 118 words
An ion selective electrode which comprises a polyvinyl chloride series resin plate having a through hole; conductive member disposed along said through hole provided in the polyvinyl chloride series resin plate so as to form at least a part of an inner peripheral surface of said through hole; ion sensitive membrane of a polyvinyl chloride series resin membrane with which said conductive member forming the inner peripheral surface of said through hole is covered on the whole surface thereof and with which said polyvinyl chloride series resin plate adjacent to the surface of said conductive member is covered on at least a part of the inner peripheral surface thereof; and a lead wire connected to said conductive member.
Claim 2
Dependent Claim 118 words
An ion selective electrode which comprises a polyvinyl chloride series resin plate having a through hole; conductive member disposed along said through hole provided in the polyvinyl chloride series resin plate so as to form at least a part of an inner peripheral surface of said through hole; ion sensitive membrane of a polyvinyl chloride series resin membrane with which said conductive member forming the inner peripheral surface of said through hole is covered on the whole surface thereof and with which said polyvinyl chloride series resin plate adjacent to the surface of said conductive member is covered on at least a part of the inner peripheral surface thereof; and a lead wire connected to said conductive member.
Claim 3
Dependent Claim 34 words
The ion selective electrode according to Claim 1, wherein said ion sensitive membrane contains an ion selective substance selected from the group consisting of monensin, valinomycin, a quaternary ammonium salt and a crown ether.
Claim 4
Dependent Claim 29 words
The ion selective electrode according to Claim 1, wherein said conductive member is a metal and its surface is covered with a layer of a compound of said metal.
Claim 5
Dependent Claim 26 words
The ion selective electrode according to Claim 1, wherein said conductive member is silver and its surface is covered with a layer of a silver halide.
Claim 6
Dependent Claim 167 words
A flow type ion sensor which comprises a plurality of ion selective electrodes mutually integrally associated with each other with the interposition of electrical insulating members so that through holes of said respective ion selective electrodes may define a flow passage for a liquid to be measured, the ion selective electrodes each being composed of: a polyvinyl chloride series resin plate having a through hole; conductive member disposed along said through hole provided in the polyvinyl chloride series resin plate so as to form at least a part of an inner peripheral surface of said through hole; ion sensitive membrane of a polyvinyl chloride series resin membrane with which said conductive member forming the inner peripheral surface of said through hole is covered on the whole surface thereof and with which said polyvinyl chloride series resin plate adjacent to the surface of said conductive member is covered on at least a part of the inner peripheral surface thereof; and a lead wire connected to said conductive member.
Claim 7
Dependent Claim 167 words
A flow type ion sensor which comprises a plurality of ion selective electrodes mutually integrally associated with each other with the interposition of electrical insulating members so that through holes of said respective ion selective electrodes may define a flow passage for a liquid to be measured, the ion selective electrodes each being composed of: a polyvinyl chloride series resin plate having a through hole; conductive member disposed along said through hole provided in the polyvinyl chloride series resin plate so as to form at least a part of an inner peripheral surface of said through hole; ion sensitive membrane of a polyvinyl chloride series resin membrane with which said conductive member forming the inner peripheral surface of said through hole is covered on the whole surface thereof and with which said polyvinyl chloride series resin plate adjacent to the surface of said conductive member is covered on at least a part of the inner peripheral surface thereof; and a lead wire connected to said conductive member.
Claim 8
Dependent Claim 52 words
The flow type ion sensor according to Claim 5, wherein a reference electrode is further disposed and is mutually integrally associated with said plurality of ion selective electrodes with the interposition of an electrical insulating member so that respective through holes may define said flow passage for the liquid to be measured.
Claim 9
Dependent Claim 144 words
The flow type ion sensor according to Claim 6, wherein said reference electrode comprises: a polyvinyl chloride series resin plate having a through hole; conductive member disposed along said through hole provided in the polyvinyl chloride series resin plate so as to form at least a part of an inner peripheral surface of said through hole; ion sensitive membrane of a polyvinyl chloride series resin membrane with which said conductive member forming the inner peripheral surface of said through hole is covered on the whole surface thereof and with which said polyvinyl chloride series resin plate adjacent to the surface of said conductive member is covered on at least a part of the inner peripheral surface thereof; silicone series polymer membrane with which said polyvinyl chloride seires resin membrane is covered on the surface thereof; and a lead wire connected to said conductive member.
Claim 10
Dependent Claim 77 words
The flow type ion sensor according to Claim 7, wherein said reference electrode is a silver-silver halide electrode which comprises conductive member consisting of silver; a silver halide layer formed on at least a part of said silver surface; a polyvinyl chloride series resin membrane layer, including potassium chloride, with which said silver halide layer is formed; and a silicone polymer membrane with which said polyvinyl chloride series resin membrane layer is covered on the surface thereof.
Claim 11
Dependent Claim 44 words
The flow type ion sensor according to Claim 6, wherein said reference electrode is a silver-silver halide eletrode forming, along said through hole provided in said polyvinyl chloride series resin plate, at least a part of the inner peripheral surface of said through hole.
Claim 12
Dependent Claim 31 words
The flow type ion sensor according to Claim 5, wherein said conductive member comprises a metal and the surface thereof is covered with a layer of a compound of said metal.
Claim 13
Dependent Claim 27 words
The flow type ion sensor according to Claim 10, wherein said conductive member is silver and its surface is covered with a layer of a silver halide.
Claim 14
Dependent Claim 52 words
The flow type ion sensor according to Claim 5, wherein said flow type ion sensor is surrounded with an outer case having an inlet and an outlet for the liquid to be measured which communicate with said through holes, and having an electrical signal output opening for leading out said lead wires.

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