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EP0123935A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Use of alkoxysilyl polyorganosiloxanes for treating textiles

Assignee: Union Carbide Corp
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Filing: 1984-03-30
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Granted: —
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Expires: 2004-03-30
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Abstract

Abstract Novel alkoxysilyl functional silicones capable of imparting satisfactory lubricity and other properties such as softness to a variety of textile fabrics over an extended period of time under normal usage. The alkoxysilyl functional silicones include at least one functional group of the formula: wherein R is an alkyl or an acyl hydrocarbon radical having from one to four carbon atoms; R, is an alkyl radical of from one to two carbon atoms or a mixture thereof; and w is an interger of from 2 to about 20.

Inventors

  • 👤 George Edward Totten
  • 👤 Arthur Noah Pines

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 00:05
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/643; C; C08; C08G; C08G77/00; C08G77/48; C08G77/50

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 299 words
A method for preparing an alkoxysilyl functional silicone represented by a formula selected from the group consisting of: and wherein R is an alkyl or an acyl hydrocarbon radical having from one to four carbon atoms, preferably a methyl radical; R i is an alkyl radical of from one to two carbon atoms or a mixture thereof, preferably a methyl radical; R 2 is an alkyl radical having from one to three carbon atoms, mixtures thereof, or an aryl radical selected from the group consisting of phenyl, benzyl and phenylethyl, mixtures thereof, or a mixture of said alkyl and aryl radicals, preferably methyl radical; w is an integer of from 2 to about 20, preferably either 2 or 3; x is an integer of from 0 to 2, preferably either 0 or 1; y is an integer of an average of at least 6, preferably of an average of from 6 to about 1000 and z is an integer of an average of at least 1, preferably of an average of from 1 to about 100, comprising reacting in a first step a silanic hydrogen functional silicone precursor selected from the group consisting of and wherein R 1 , R 2 , y and z have the same meaning as in formulas I and II above with a cyclic [(R 2 ) 2 SiO] 4 , or linear HO[(R 2 ) 2 SiO] n H, compound, or with a hexaalkyl disiloxane in the case of compounds of formula II, and then in a second step carrying out a hydrosilylation reaction according to one of the general reactions identified as V and VI respectively: and wherein R, R 1 , R 21 w, x, y and z have the same meaning as they have in formulas I and II above.
Claim 2
Independent Claim 299 words
A method for preparing an alkoxysilyl functional silicone represented by a formula selected from the group consisting of: and wherein R is an alkyl or an acyl hydrocarbon radical having from one to four carbon atoms, preferably a methyl radical; R i is an alkyl radical of from one to two carbon atoms or a mixture thereof, preferably a methyl radical; R 2 is an alkyl radical having from one to three carbon atoms, mixtures thereof, or an aryl radical selected from the group consisting of phenyl, benzyl and phenylethyl, mixtures thereof, or a mixture of said alkyl and aryl radicals, preferably methyl radical; w is an integer of from 2 to about 20, preferably either 2 or 3; x is an integer of from 0 to 2, preferably either 0 or 1; y is an integer of an average of at least 6, preferably of an average of from 6 to about 1000 and z is an integer of an average of at least 1, preferably of an average of from 1 to about 100, comprising reacting in a first step a silanic hydrogen functional silicone precursor selected from the group consisting of and wherein R 1 , R 2 , y and z have the same meaning as in formulas I and II above with a cyclic [(R 2 ) 2 SiO] 4 , or linear HO[(R 2 ) 2 SiO] n H, compound, or with a hexaalkyl disiloxane in the case of compounds of formula II, and then in a second step carrying out a hydrosilylation reaction according to one of the general reactions identified as V and VI respectively: and wherein R, R 1 , R 21 w, x, y and z have the same meaning as they have in formulas I and II above.
Claim 3
Independent Claim 27 words
A method according to claim wherein the synthesis is carried out at elevated temperatures of from about 25°C to about 175°C, preferably from about 80 to 110°C.
Claim 4
Dependent Claim 64 words
A method according to claim 1 or 2 wherein the alkoxysilyl functional silicone is represented by a formula selected from the group consisting of: and wherein R is methyl, ethyl or acetyl; x is an integer of from 0 to 2; y is an integer of an average of at least 6 and z is an integer of an average of at least 1.
Claim 5
Dependent Claim 25 words
A method according to claim 3 wherein the alkoxysilyl functional silicone is defined as in claim 3 wherein R is methyl and x is zero.
Claim 6
Dependent Claim 39 words
A textile material treated with at least one alkoxysilyl functional silicone as prepared according to anyone of claims 1 to 4,said functional silicone being present in cured form in an amount sufficient to impart lubricity to said textile material.
Claim 7
Dependent Claim 26 words
The textile material as defined in Claim 5 wherein said textile material is a polyester fiberfill or a cotton or a blend of polyester and cotton.
Claim 8
Dependent Claim 95 words
A textile material treated to impart durable press properties to said textile and also treated with at least one alkoxysilyl functional silicone as prepared according to claim 1, preferably with at least one functional silicone of the empirical formula (CH 3 O) 3 Si(CH 2 ) 2 Si(CH 3 ) 2 O[(CH 3 ) 2 SiO] y Si(CH 3 ) 2 (CH 2 ) 2 Si(OCH 3 ) 3 wherein y is at least about 100, said functional silicone being present in cured form in an amount sufficient to impart softness to said textile material.
Claim 9
Dependent Claim 64 words
A solution for treating a textile material comprising the alkoxysilyl functional silicone as prepared according to claim 1 or 3, a catalyst and water, said catalyst and said water both being present in an amount sufficient to allow hydrolysis and condensation to take place upon curing, said functional silicone being present in an amount sufficient to impart lubricity to the textile material upon curing.
Claim 10
Dependent Claim 66 words
An aqueous emulsion for treating textile material comprising the alkoxysilyl functional silicone as prepared according to claim 1 or 3 and a catalyst, said water and said catalyst both being present in an amount sufficient to allow hydrolysis and condensation to take place upon curing, said functional silicone being present in said emulsion in an amount sufficient to impart lubricity to the textile material upon curing.

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