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EP0123726A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method for fabricating DEIS structure between two polysilicon gate electrodes and memories resulting therefrom

Assignee: International Business Machines Corp
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Filing: 1983-12-01
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Granted: —
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Expires: 2003-12-01
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Abstract

Abstract A process for placing non-continuous Dual Electron Injection Structures (DEIS) between two layers of polysilicon used to form an array of poly devices on an integrated circuit substrate. Separate masks are used to define Poly 1 and Poly 2 devices, respectively. The DEIS structure is disposed above the poly 1 devices. A silicon nitride (Si 3 N 4 ) layer is used to mask the DEIS structure and prevents it from oxidizing during certain processing steps. A thin layer of poly x is placed between the DEIS structure and the Si 3 N 4 . The poly x layer forms a buffer and protects the DEIS during an etching step which removes the Si 3 N 4 layer.

Inventors

  • 👤 Anthony John Hoeg, Jr.
  • 👤 Charles Thomas Kroll
  • 👤 Geoffrey Brownell Stephens

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-25 06:49
CPC Classifications
H; H10; H10B; H10B41/00; H10B69/00; H10D; H10D30/00; H10D30/60; H10D30/68; H10D30/681; H10D30/682

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 262 words
Method for fabricating a DEIS structure between two layers of polysilicon in an array of devices embedded in an integrated circuit substrate characterized in that it comprises the following steps: (a) fabricating a silicon substrate with at least one thin oxide region surrounded by thick oxide region; (b) depositing a first polysilicon gate interconnect layer on the substrate; (c) depositing on said first polysilicon gate interconnect layer, a composite DEIS structure of three layers : a first layer of silicon rich oxide, a layer of silicon dioxide, a second layer of silicon rich oxide; a second layer of polysilicon and a layer of non-oxidizing material with the layers being deposited in the order of recitation; (d) patterning a first photoresist mask on the layer of non-oxidizing material with said photoresist defining a profile for the DEIS structure; (e) etching the exposed areas through the said non-oxidizing material, through the said second layer of polysilicon; (f) etching the exposed DEIS areas; (g) stripping the first photoresist mask; (h) patterning a second photoresist mask on the layer of the non-oxidizing material; said second photoresist mask being operable to define at least one polysilicon floating gate electrode and polysilicon interconnections; (i) etching the exposed polysilicon areas; (j) stripping the second photoresist mask; (k) thermally oxidizing the structure for isolating at least one floating gate; (1) removing the layer of non-oxidizing material; (m) depositing a third layer of polysilicon on the second layer of polysilicon previously laid down in step (b) above; and (n) forming electrical interconnections and gate electrodes in said third layer of polysilicon.
Claim 2
Dependent Claim 262 words
Method for fabricating a DEIS structure between two layers of polysilicon in an array of devices embedded in an integrated circuit substrate characterized in that it comprises the following steps: (a) fabricating a silicon substrate with at least one thin oxide region surrounded by thick oxide region; (b) depositing a first polysilicon gate interconnect layer on the substrate; (c) depositing on said first polysilicon gate interconnect layer, a composite DEIS structure of three layers : a first layer of silicon rich oxide, a layer of silicon dioxide, a second layer of silicon rich oxide; a second layer of polysilicon and a layer of non-oxidizing material with the layers being deposited in the order of recitation; (d) patterning a first photoresist mask on the layer of non-oxidizing material with said photoresist defining a profile for the DEIS structure; (e) etching the exposed areas through the said non-oxidizing material, through the said second layer of polysilicon; (f) etching the exposed DEIS areas; (g) stripping the first photoresist mask; (h) patterning a second photoresist mask on the layer of the non-oxidizing material; said second photoresist mask being operable to define at least one polysilicon floating gate electrode and polysilicon interconnections; (i) etching the exposed polysilicon areas; (j) stripping the second photoresist mask; (k) thermally oxidizing the structure for isolating at least one floating gate; (1) removing the layer of non-oxidizing material; (m) depositing a third layer of polysilicon on the second layer of polysilicon previously laid down in step (b) above; and (n) forming electrical interconnections and gate electrodes in said third layer of polysilicon.
Claim 3
Dependent Claim 31 words
The method of claim 1 wherein the semiconductor structure is being fabricated through a technique including the steps of formation of Recessed Oxide regions (ROX), gate oxidation and polysilicon gate deposition.
Claim 4
Dependent Claim 15 words
The method of claim 1 wherein the non-oxidizing material of step (c) includes silicon nitride.
Claim 5
Dependent Claim 34 words
The method of claim 1 wherein an in situ chemical vapor deposition (CVD) technique is used to deposit the first and second layers of silicon rich oxide and the first layer of silicon dioxide.
Claim 6
Dependent Claim 42 words
The method of claim 4 wherein the first layer of silicon rich oxide is approximately 20 nm thick, the first layer of silicon dioxide is approximately 15 nm thick and the second layer of silicon rich oxide is approximately 20 nm thick.
Claim 7
Dependent Claim 51 words
The method of claim 5 wherein the silicon rich oxide is being deposited with a low pressure CVD reactor having a flow rate of 20 cc/minute of 100% silane (SiH 4 ) , 100 cc/minute of nitrous oxide (N 2 O), a temperature of 750°C. and a pressure of 750 millitorr.
Claim 8
Dependent Claim 31 words
The method of claim 5 wherein the second layer of silicon dioxide is being deposited at 7 cc/minute of SiH 4 , 300 cc/minute of N20 at 750 millitorr and 750°C.
Claim 9
Dependent Claim 20 words
The method of claim 1 wherein the non-oxidizing material of step (d) defines a non-continuous profile for the DEIS structure.
Claim 10
Dependent Claim 19 words
The method of claim 1 wherein steps (e),(i) and (1) are being etched in a plasma etch using DE-100.
Claim 11
Dependent Claim 16 words
The method of claim 1 wherein step (f) is being etched in a buffered HF solution.
Claim 12
Dependent Claim 22 words
The method recited in claim 1 wherein the photoresist mask defines a coincident profile for the DEIS structure and the floating gate.

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