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EP0121656A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Alkaline aqueous coating solution and process

Assignee: Pennwalt Corp
•
Filing: 1984-01-18
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Granted: —
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Expires: 2004-01-18
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Abstract

Abstract An aqueous alkaline coating bath for forming clear, corrosion and tarnish-resistant coatings on metals such as aluminum and steel includes divalent metal ions such as calcium and magnesium, a volatile complexing agent for the metal ions, water soluble salts of an acrylic polymer which contains carboxyl groups and a defoaming agent.

Inventors

  • 👤 Richard George Adams
  • 👤 Kurt Goltz
  • 👤 Frederick John Spaeth

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 13:50
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/064

Claims Analysis

Total Claims: 34
Claim 1
Independent Claim 50 words
An aqueous, alkaline coating composition comprising greater than about 0.25 gm/liter and less than about 5.0 gm/liter of composition of a water soluble salt of an acrylic polymer which contains carboxyl groups, a divalent metal ion which is effective to crosslink the acrylic polymer, a volatile base, and a defoamer.
Claim 2
Dependent Claim 50 words
An aqueous, alkaline coating composition comprising greater than about 0.25 gm/liter and less than about 5.0 gm/liter of composition of a water soluble salt of an acrylic polymer which contains carboxyl groups, a divalent metal ion which is effective to crosslink the acrylic polymer, a volatile base, and a defoamer.
Claim 3
Dependent Claim 23 words
The coating composition of claim 1 wherein the composition includes a divalent metal ion selected from the group consisting of magnesium and calcium.
Claim 4
Dependent Claim 13 words
The coating composition of claim 1 wherein the volatile base is ammonium hydroxide.
Claim 5
Dependent Claim 14 words
The coating composition of claim 1 wherein the defoamer is a a-hydro-omega-hydroxy-poly(oxyethylene)poly--(oxypropylene)poly(oxyethylene) block copolymer.
Claim 6
Dependent Claim 16 words
The coating composition of claim 1 which includes a volatile amine as a film forming aid.
Claim 7
Dependent Claim 18 words
The coating composition of claim 5 which contains from about 2.9 gm/liter to about 47 gm/liter of amine.
Claim 8
Dependent Claim 12 words
The coating composition of claim 1 which includes a glycol ether solvent.
Claim 9
Dependent Claim 21 words
The coating composition of claim 7 which contains from about 3.0 gm/liter to about 54 gm/liter of said glycol ether solvent.
Claim 10
Dependent Claim 21 words
The coating composition of claim 1 which contains from about 0.018 gm/liter to about 0.452 gm/liter of said divalent metal ion.
Claim 11
Dependent Claim 20 words
The coating composition of claim 1 which contains from about 0.240 gm/liter to about 2.0 gm/liter of said volatile base.
Claim 12
Dependent Claim 16 words
The coating composition of claim 1 having a pH of from about 8.5 to about 11.0.
Claim 13
Dependent Claim 41 words
The coating composition of claim 1 wherein the acrylic polymer is a terpolymer of ethyl acrylate, methyl methacrylate and methacrylic acid having from about 3 to 15 weight percent of carboxyl functionality and a molecular weight from about 30,000 to 260,000.
Claim 14
Dependent Claim 25 words
The coating composition of claim 1 wherein the defoamer is present in an amount of from about 0.67 gm/liter to about 5.3 gm/liter of composition.
Claim 15
Dependent Claim 20 words
The coating composition of claim 1 which contains from about 0.50 gm/liter to about 2.5 gm/liter of said acrylic polymer.
Claim 16
Dependent Claim 81 words
A process for forming a corrosion-resistant coating on a metal substrate comprising coating the surface of the substrate with an aqueous alkaline composition comprising greater than about 0.25 gm/liter to less than about 5.0 gm/liter of composition of a water soluble salt of an acrylic polymer which contains carboxyl groups, a divalent metal ion which is effective to crosslink the acrylic polymer, a volatile base and a defoamer so as to form a dry, crosslinked acrylic polymer coating on said surface.
Claim 17
Dependent Claim 81 words
A process for forming a corrosion-resistant coating on a metal substrate comprising coating the surface of the substrate with an aqueous alkaline composition comprising greater than about 0.25 gm/liter to less than about 5.0 gm/liter of composition of a water soluble salt of an acrylic polymer which contains carboxyl groups, a divalent metal ion which is effective to crosslink the acrylic polymer, a volatile base and a defoamer so as to form a dry, crosslinked acrylic polymer coating on said surface.
Claim 18
Dependent Claim 16 words
The process of claim 15 wherein the composition is at a temperature of from about 70-120°F.
Claim 19
Dependent Claim 14 words
The process of claim 15 wherein the coating is dried and crosslinked by heating.
Claim 20
Dependent Claim 12 words
The process of claim 15 wherein the substrate is coated by spraying.
Claim 21
Dependent Claim 14 words
The process of claim 15 wherein the metal substrate is aluminum or steel .
Claim 22
Dependent Claim 22 words
The process of claim 15 wherein the composition includes a divalent metal ion selected from the group consisting of magnesium or calcium.
Claim 23
Dependent Claim 12 words
The process of claim 15 wherein the volatile base is ammonium hydroxide.
Claim 24
Dependent Claim 14 words
The process of claim 15 wherein the defoamer is a a-hydro-omega-hydroxy-poly(oxyethylene)poly(oxypropylene) poly(oxyethylene) block copolymer.
Claim 25
Dependent Claim 17 words
The process of claim 15 wherein the composition includes a volatile amine as a film forming aid.
Claim 26
Dependent Claim 19 words
The process of claim 23 wherein the composition contains from about 2.9 gm/liter to about 47 gm/liter of amine.
Claim 27
Dependent Claim 13 words
The process of claim 15 wherein the composition includes a glycol ether solvent.
Claim 28
Dependent Claim 22 words
The process of claim 25 wherein the composition contains from about 3.0 gm/liter to about 54 gm/liter of said glycol ether solvent.
Claim 29
Dependent Claim 22 words
The process of claim 15 wherein the composition contains from about 0.018 gm/liter to about 0.452 gm/liter of said divalent metal ion.
Claim 30
Dependent Claim 21 words
The process of claim 15 wherein the composition contains from about 0.240 gm/liter to about 2.0 gm/liter of said volatile base.
Claim 31
Dependent Claim 15 words
The process of claim 15 having a pH of from about 8.5 to about 11.0.
Claim 32
Dependent Claim 40 words
The process of claim 15 wherein the acrylic polymer is a terpolymer of ethyl acrylate, methyl methacrylate and methacrylic acid having from about 3 to 15 weight percent of carboxyl functionality and a molecular weight from about 30,000 to 260,000.
Claim 33
Dependent Claim 24 words
The process of claim 15 wherein the defoamer is present in an amount of from about 0.67 gm/liter to about 5.3 gm/liter of composition.
Claim 34
Dependent Claim 21 words
The process of claim 15 wherein the composition contains from about 0.50 gm/liter to about 2.5 gm/liter of said acrylic polymer.

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