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EP0120575A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Organic fluorine compounds

Assignee: Nippon Shokubai Co Ltd
•
Filing: 1984-02-14
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Granted: —
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Expires: 2004-02-14
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Abstract

Abstract Compounds such as pentafluorobenzonitrile, tetra- fluorophthalonitriles, and pentafluoropyridine are produced by halogen exchange with a chloro- or bromo-organic compound fluorinating agent such as an alkali metal fluoride using benzonitrile as a solvent as from 190° to 400°C.

Inventors

  • 👤 Osamu Kaieda
  • 👤 Masaru Awashima
  • 👤 Isao Okitaka
  • 👤 Toshiaki Nakamura

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-02 09:30
CPC Classifications
C; C07; C07D; C07D213/00; C07D213/02; C07D213/04; C07D213/60; C07D213/78; C07D213/84; C07B; C07B39/00; C07C; C07C17/00; C07C17/093; C07C17/20; C07C17/202; C07C17/208; C07C201/00; C07C201/06; C07C201/12; C07C253/00; C07C253/30; C07D213/61

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 42 words
A method of manufacturing an organic fluorine compound from an organic chloro- or bromo-compound by a halogen exchange reaction with a fluorinating agent characterized in that the method is carried out using benzonitrile as a solvent and at from 190° to 400°C.
Claim 2
Independent Claim 42 words
A method of manufacturing an organic fluorine compound from an organic chloro- or bromo-compound by a halogen exchange reaction with a fluorinating agent characterized in that the method is carried out using benzonitrile as a solvent and at from 190° to 400°C.
Claim 3
Dependent Claim 15 words
A method according to claim 1 characterized in that the chloro- or bromo-compound is aromatic.
Claim 4
Dependent Claim 26 words
A method according to claim 1 or claim 2 characterized in that the fluorinating agent is an alkali metal fluoride or an alkaline earth metal fluoride.
Claim 5
Dependent Claim 15 words
A method according to claim 3 characterized in that the fluorinating agent is potassium fluoride.
Claim 6
Independent Claim 34 words
A method according to any preceding claim characterized in that the chloro- or bromo-compound is used in an amount of from 5 to 50 parts by weight basedon 100 parts by weight of benzonitrile.
Claim 7
Independent Claim 39 words
A method according to any preceding claim characterized in that the fluorinating agent is an alkali metal fluoride in an amount of from 1 to 2 mols relative to the chlorine or bromine atoms in the organic compound treated.
Claim 8
Independent Claim 18 words
A method according to any preceding claim characterized in that it is carried out under spontaneously generated pressure.
Claim 9
Independent Claim 22 words
A method according to any preceding claim characterized in that it is carried out in the presence of a phase transfer catalyst.
Claim 10
Dependent Claim 31 words
A method according to claim 8 characterized in that the phase transfer catalyst is used in an amount of from 0.01 to 0.25 mol per mol of the organic compound treated.

References Cited (Backward Citations)

FR2096028A5 Cited
GB1340421A Cited
EP0003344A1 Cited

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