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EP0115967A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Thermotropic liquid crystalline polymer blend with reduced surface abrasion

Assignee: Celanese Corp
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Filing: 1984-02-07
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Granted: —
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Expires: 2004-02-07
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Abstract

Abstract A thermotropic liquid crystalline polymer matrix having wollastonite fibres incorporated therein for reinforcement to prepare a moulding compound. The wollastonitefibres have an average aspect ratio of greater than 3 to 1, and may be coated on their surface with a coupling agent to produce better bonding between the fibres and the thermotropic liquid crystalline polymer. The surface abrasion of an article produced from a blend of wollastonite with a thermotropic liquid crystalline polymer is reduced as compared to that of unfilled polymer.

Inventors

  • 👤 Nancy C. Eickman

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 23:13
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/34; C08K7/00; C08K7/02; C08K7/04; C08K7/10; C08K9/00; C08K9/04; C08K2201/00; C08K2201/016

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 28 words
A moulding compound comprising a thermotropic liquid crystalline polymer matrix having wollastonite fibres incorporated therein, the wollastonite fibres having an average aspect ratio greater than 3 to 1.
Claim 2
Dependent Claim 28 words
A moulding compound comprising a thermotropic liquid crystalline polymer matrix having wollastonite fibres incorporated therein, the wollastonite fibres having an average aspect ratio greater than 3 to 1.
Claim 3
Dependent Claim 21 words
The moulding compound of claim 1 wherein the wollastonite fibres have an average aspect ratio of at least 10 to 1.
Claim 4
Dependent Claim 20 words
The moulding compound of claim 2 wherein the wollastonite fibres have-an average aspect ratio of at least 20 to 1.
Claim 5
Dependent Claim 36 words
The moulding compound of any of claims 1 - 3 wherein the wollastonite fibres are treated with a titanate coupling agent prior to being blended with the thermotropic liquid crystalline polymer to produce the moulding compound.
Claim 6
Dependent Claim 29 words
The moulding compound of any of claims 1 - 4 wherein the wollastonite fibres are present in the moulding compound in an amount of 10 to 70% by volume.
Claim 7
Dependent Claim 24 words
The moulding compound of claim 5 wherein the wollastonite fibres are present.in the moulding compound in an amount of 10 to 40% by volume.
Claim 8
Dependent Claim 40 words
The moulding compound of any of claims 1 - 6 wherein the thermotropic liquid crystalline polymer has an inherent viscosity of between 1.0 and 15 dl./g. when dissolved in a concentration of 0.1 percent by weight of pentafluorophenol at 60°C.
Claim 9
Dependent Claim 36 words
The moulding compound of any of claims 1 - 7 wherein the thermotropic liquid crystalline polymer is selected from wholly aromatic polyesters, aromatic-aliphatic polyesters, wholly aromatic poly(ester-amide)s, aromatic-aliphatic poly(ester-amide)s, aromatic polyazomethines, aromatic polyester-carbonates and mixtures thereof.
Claim 10
Dependent Claim 202 words
The moulding compound of claim 8, wherein the thermotropic liquid crystalline polymer is a melt processable poly(ester-amide) capable of forming an anisotropic melt phase at a temperature below 400°C. consisting essentially of recurring moieties I, II, III and optionally IV wherein: is II is - -A- -, where A is a divalent radical comprising at least one aromatic ring or a divalent trans-1,4-cyclohexylene radical ; III is -Y-Ar-Z, where Ar is a divalent radical comprising at least one aromatic ring, Y is 0, NH or NR and Z is NH or NR, where R is an alkyl group of 1 to 6 carbon atoms or an aryl group; and IV is -O-Ar'-O-, where Ar' is a divalent radical comprising at least one aromatic ring; wherein at least some of the hydrogen atoms present upon the rings may optionally be replaced by substituents selected from alkyl groups of 1 to 4 carbon atoms, alkoxy groups of 1 to 4 carbon atoms, halogen, phenyl and mixtures -thereof, and wherein said poly(ester-amide) comprises 10 to 90 mole percent of moiety I, 5 to 45 mole percent of moiety II, 5 to 45 mole percent of moiety III and O.to 40 mole percent of moiety IV.
Claim 11
Dependent Claim 167 words
The moulding compound of claim 8, wherein the thermotropic liquid crystalline polymer is a melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below 400°C. consisting essentially of the recurring moieties I, II and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is II is a dioxy aryl moiety of the formula -0-Ar-O-where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxy aryl moiety of the formula where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substituents if present being selected from alkyl groups of 1 to 4 carbon atoms, alkoxy groups of 1 to 4 carbon atoms, halogen, phenyl groups and mixtures of the foregoing, and wherein said polyester comprises 10 to 90 mole percent of moiety I, 5 to 45 mole percent of moiety II and 5 to 45 mole percent of moiety III.
Claim 12
Dependent Claim 117 words
The moulding compound of claim 8, wherein the thermotropic liquid crystalline polymer is a melt processable wholly aromatic polyester capable of forming a thermotropic melt phase at a temperature below 350°C. consisting essentially of the recurring moieties I and II which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is II is and with said optional substituents if present being selected from alkyl groups of 1 to 4 carbon atoms, alkoxy groups of 1 to 4 carbon atoms, halogen, phenyl and mixtures of the foregoing, and wherein said polyester comprises 10 to 90 mole percent of moiety I and 10 to 90 mole percent of moiety II.
Claim 13
Dependent Claim 15 words
A moulded article produced from the moulding compound of any of claims 1 - 11.
Claim 14
Dependent Claim 15 words
An extruded article produced from the moulding compound of any of claims 1 - 11.

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