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EP0115950A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

New powder pressed N-type thermoelectric materials and method of making same

Assignee: Energy Conversion Devices Inc
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Filing: 1984-01-27
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Granted: —
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Expires: 2004-01-27
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Abstract

Abstract The disclosure relates to new and improved compacted or pressed powder materials for thermoelectric applications. The materials have commercially high figures of merit in desired temperature ranges. Also disclosed is a method for making the materials. The materials include lead telluride and a modifying element which is capable of forming solid phase alloys with tellurium but incapable of forming solid phase alloys with lead. The materials are multiphase materials having at least three phases including lead telluride, a telluride of the modifying element, and the modifying element. The modifying element preferably is manganese forming, during processing, lead telluride, manganese telluride, and manganese phases. The modifying element can also be aluminium, chromium, or titanium. The materials are made in accordance with the general method of the present invention by forming a particulate mixture containing lead telluride and the modifying element. At least a portion of the particulate mixture is then compressed to form a compacted body of the material. Lastly, the compacted body of material is sintered at a temperature between 400°C and 700°C in a forming gas atmosphere and then cooled to room temperature.

Inventors

  • 👤 Kamran Manteghi
  • 👤 David Dean Allred

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-07 06:33
CPC Classifications
H; H10; H10N; H10N10/00; H10N10/80; H10N10/85; H10N10/851; H10N10/852

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 56 words
A thermoelectric material characterized by: a body formed from lead telluride and a modifying element, said modifying element being capable of forming solid phase alloys with tellurium but incapable of forming solid phase alloys with lead, said body including at least three phases including lead telluride, a telluride of said modifying element, and said modifying element.
Claim 2
Dependent Claim 56 words
A thermoelectric material characterized by: a body formed from lead telluride and a modifying element, said modifying element being capable of forming solid phase alloys with tellurium but incapable of forming solid phase alloys with lead, said body including at least three phases including lead telluride, a telluride of said modifying element, and said modifying element.
Claim 3
Dependent Claim 20 words
A material according to claim 1 further characterized by said body includes a fourth phase, said fourth phase being lead.
Claim 4
Dependent Claim 29 words
A material according to any one of claims 1 or 2 further characterized by said modifying element is one of the group consisting of chromium, titanium, aluminum, and manganese.
Claim 5
Dependent Claim 27 words
A material according to any one of claims 1 through 3 further characterized by said body comprises compressed particles of said lead telluride and said modifying element.
Claim 6
Dependent Claim 23 words
A material according to claim 4 further characterized by said body includes between about one to five weight percent of said modifying element.
Claim 7
Dependent Claim 21 words
A material according to claim 3 further characterized by said at least three phases are lead telluride, manganese telluride, and manganese.
Claim 8
Independent Claim 82 words
A method of making a thermoelectric material characterized by: forming a particulate mixture of about ninety-nine to ninety-five weight percent lead telluride and one to five weight percent of a modifying element, said modifying element being capable of forming solid phase alloys with tellurium but incapable of forming solid phase alloys with lead; compressing at least a portion of said particulate mixture to form a compacted body of material; and thereafter, sintering said compacted body of material to form said thermoelectric material.
Claim 9
Independent Claim 82 words
A method of making a thermoelectric material characterized by: forming a particulate mixture of about ninety-nine to ninety-five weight percent lead telluride and one to five weight percent of a modifying element, said modifying element being capable of forming solid phase alloys with tellurium but incapable of forming solid phase alloys with lead; compressing at least a portion of said particulate mixture to form a compacted body of material; and thereafter, sintering said compacted body of material to form said thermoelectric material.
Claim 10
Dependent Claim 28 words
A method according to claim 7 further characterized by said particulate mixture includes about ninety-seven weight percent lead telluride and about three weight percent of said modifying element.
Claim 11
Independent Claim 29 words
A method according to any one of claims 7 or 8 further characterized by said modifying element is selected from the group consisting of chromium, titanium, aluminum, and manganese.
Claim 12
Independent Claim 30 words
A method according to any one of claims 7 through 9 further characterized by said particulate mixture is compressed at a pressure of five to twenty tons per square centimeter.
Claim 13
Independent Claim 28 words
A method according to any one of claims 7 through 10 further characterized by said compacted body is sintered at a temperature between 400 and 700 degrees centigrade.
Claim 14
Dependent Claim 27 words
A method according to claim 7 further characterized by the modifying element particles of said particulate mixture vary in size up to about 200 micrometers in dimension.
Claim 15
Independent Claim 26 words
A method according to any one of claims 11 or 12 further characterized by said compacted body is sintered for between one and one hundred hours.
Claim 16
Independent Claim 23 words
A method according to any one of claims 11 through 13 further characterized by said compacted body is sintered for about twenty hours.

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