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EP0111342A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Non-melt-fabricable granular modified terafluoroethylene polymer

Assignee: EIDP Inc
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Filing: 1983-12-13
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Granted: —
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Expires: 2003-12-13
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Abstract

Abstract A non-melt-fabricable granular modified polytetrafluoroethylene in which the modifying comonomer is a fluorinated alkyl ethylene of the formula R f - CH = CH 2 . The polymer is useful in ram extrusion and in making molded articles.

Inventors

  • 👤 Satish Chandra Malhotra

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 21:50
CPC Classifications
C; C08; C08F; C08F214/00; C08F214/18; C08F214/26

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 92 words
A non-melt-fabricable granular modified polytetrafluoroethylene composition comprising tetrafluoroethylene polymer containing polymerized units of at least one copolymerizable monomer of the formula present in an amount which does not cause the melt viscosity to be less than about 1 X 10 8 PaS at 380°C., wherein R f is a fluorinated alkyl radical of 2-10 carbon atoms which is either perfluorinated or which is perfluorinated except for the presence of one substituent attached to a carbon atom of the R f radical which substituent is selected from hydrogen or halogen other than fluorine.
Claim 2
Dependent Claim 92 words
A non-melt-fabricable granular modified polytetrafluoroethylene composition comprising tetrafluoroethylene polymer containing polymerized units of at least one copolymerizable monomer of the formula present in an amount which does not cause the melt viscosity to be less than about 1 X 10 8 PaS at 380°C., wherein R f is a fluorinated alkyl radical of 2-10 carbon atoms which is either perfluorinated or which is perfluorinated except for the presence of one substituent attached to a carbon atom of the R f radical which substituent is selected from hydrogen or halogen other than fluorine.
Claim 3
Dependent Claim 27 words
The composition of Claim 1 wherein the copolymerizable monomer of the formula R f - CH = CH 2 is one in which R f is perfluorinated.
Claim 4
Dependent Claim 22 words
The composition of Claim 1 wherein the copolymerizable monomer of the formula R f - CH = CH 2 is perfluorobutyl ethylene.
Claim 5
Dependent Claim 34 words
The composition of Claim 1, 2 or 3 wherein the copolymerizable monomer is present in an amount of less than 2% by weight, preferably less than 0.5% by weight, based on weight of polymer.
Claim 6
Dependent Claim 23 words
The composition of Claim 1, 2 or 3 in the form of a molding resin or in the form of a molded article.
Claim 7
Dependent Claim 46 words
In the process for polymerizing tetrafluoroethylene and at least one comonomer to make a non-melt-fabricable granular modified polytetrafluoroethylene composition by carrying out the suspension polymerization of tetrafluoroethylene and at least one said comonomer, the improvement comprising (1) employing as the comonomer a monomer of the formula
Claim 8
Dependent Claim 46 words
In the process for polymerizing tetrafluoroethylene and at least one comonomer to make a non-melt-fabricable granular modified polytetrafluoroethylene composition by carrying out the suspension polymerization of tetrafluoroethylene and at least one said comonomer, the improvement comprising (1) employing as the comonomer a monomer of the formula
Claim 9
Dependent Claim 59 words
wherein R f is a fluorinated alkyl radical of 2-10 carbon atoms which is either perfluorinated or which is perfluorinated except for the presence of one substituent attached to a carbon atom of the R f radical which substituent is selected from hydrogen or halogen other than fluorine, and (2) adding said comonomer throughout the course of the polymerization.
Claim 10
Dependent Claim 59 words
wherein R f is a fluorinated alkyl radical of 2-10 carbon atoms which is either perfluorinated or which is perfluorinated except for the presence of one substituent attached to a carbon atom of the R f radical which substituent is selected from hydrogen or halogen other than fluorine, and (2) adding said comonomer throughout the course of the polymerization.
Claim 11
Dependent Claim 25 words
Process for shaping a molding resin in which the resin is made of a composition defined in Claim 1, which comprises ram extruding said resin.

References Cited (Backward Citations)

US3804817A Cited
US4123602A Cited
EP0043948A1 Cited
GB2084593A Cited

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