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EP0107211A2
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Polysiloxanes and process for preparing same
Assignee: Union Carbide Corp
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Filing: 1981-09-29
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Granted: —
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Expires: 2001-09-29
Abstract
Abstract Polysiloxanes produced by polymerizing a monomeric silane in the presence of an organo metallic polymerisation catalyst, e.g. a metal carboxylate, and the use of the polysiloxanes to react with alkylene-alkyl acrylate copolymers to produce silane-modified, water-curable polymers. The polysiloxanes have the general formula: wherein R is a hydrocarbon radical or an oxy-substituted hydrocarbon radical, R 1 is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of at least 2.
Inventors
- 👤 Michael John Keogh
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-08 12:38
CPC Classifications
C; C08; C08G; C08G81/00; C08G81/02; H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/46; A; A61; A61K; A61K36/00; A61K36/18; A61K36/185; A61K36/68; A61K9/00; A61K9/14; A61K9/16; A61K9/1605; A61K9/1629; A61K9/1635; A61K9/1641; A61K9/48; A61K9/50; A61K9/5005; A61K9/5021; A61K9/5026; A61K9/5031; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C08F; C08F8/00; C08F8/42; C08G77/00; C08G77/60; C08G81/024; C08L; C08L83/00; C08L83/16; H01B3/44; H01B3/441
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
70 words
A polysiloxane having the general formula: wherein R is a hydrocarbon radical or an oxy-substituted hydrocarbon radical, R 1 is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of at least 2.
Claim 2
Dependent Claim
70 words
A polysiloxane having the general formula: wherein R is a hydrocarbon radical or an oxy-substituted hydrocarbon radical, R 1 is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of at least 2.
Claim 3
Dependent Claim
94 words
A polysiloxane as claimed in claim 1, wherein R is an alkylene radical having one to 18 carbon atoms inclusive, R 1 is an alkyl radical having one to 18 carbon atoms inclusive or an alkylene radical having 2 to 18 carbon atoms inclusive, each V is an alkoxy radical having one to 18 carbon atoms inclusive, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of 5 to 25 inclusive.
Claim 4
Dependent Claim
14 words
A polysiloxane as claimed in claim 1 or claim 2 derived from acetooxyethyltrimethoxy silane.
Claim 5
Dependent Claim
21 words
A polysiloxane as claimed in claim 1 or claim 2 derived frcm a mixture of acetooxyethyltrimethoxy silane and α-methacryloxypropy- ltrimethoxy silane.
Claim 6
Dependent Claim
92 words
A process of preparing a polysiloxane which comprises reacting a mixture containing an organo metallic polymerisaticn catalyst other than an organo titanate and a silane having the general formula: wherein R is a hydrocarbon radical or an oxy-substituted hydrocarbon radical, R 1 is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value.of one to 18 inclusive and x is an integer having a value of at least two.
Claim 7
Dependent Claim
92 words
A process of preparing a polysiloxane which comprises reacting a mixture containing an organo metallic polymerisaticn catalyst other than an organo titanate and a silane having the general formula: wherein R is a hydrocarbon radical or an oxy-substituted hydrocarbon radical, R 1 is a hydrocarbon radical, each V is hydrogen, a hydrocarbon radical or a hydrolyzable group, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value.of one to 18 inclusive and x is an integer having a value of at least two.
Claim 8
Dependent Claim
14 words
A process as claimed in claim 5 wherein the catalyst is a metal carboxylate.
Claim 9
Dependent Claim
97 words
A process as claimed in claim 5 or claim 6 wherein R is an alkylene radical having one to 18 carbon atoms inclusive, R 1 is an alkyl radical having one to 18 carbon atoms inclusive or an alkylene radical having 2 to 18 carbon atoms inclusive, each V is an alkoxy radical having one to 18 carbon atoms inclusive, Z is an alkoxy radical having one to 18 carbon atoms inclusive, n is an integer having a value of one to 18 inclusive and x is an integer having a value of 5 to 25 inclusive.
Claim 10
Dependent Claim
26 words
A process as claimed in any one of claims 5 to 7 wherein the reaction is carried out at a temperature of from 70°C to 130°C.
Claim 11
Dependent Claim
14 words
A process as claimed in claim 6 wherein the metal carboxylate is stannous octoate.
Claim 12
Dependent Claim
14 words
A process as claimed in claim 6 wherein the metal carboxylate is dibutyltin dilaurate.
Claim 13
Dependent Claim
18 words
A process as claimed in any one of claims 5 to 10 wherein the silane is acetooxyethyltrimethoxy silane.
Claim 14
Dependent Claim
27 words
12 . A process as claimed in any one of claims 5 to 10 wherein the silane is a mixture of acetooxyethyltrimethoxy silane and a-methacry- loxyprcpyltrimethoxy silane.
Claim 15
Dependent Claim
38 words
13 . A process as claimed in any one of claims 5 to 12 wherein the catalyst is present in an amount of from 0.001 to 25 percent by weight based on the weight of the monomeric silane.
Claim 16
Dependent Claim
33 words
A process of preparing a polysiloxane which comprises reacting a mixture containing aluminum isopropoxide or zirconium n-propoxide and a silane having the general formula: wherein the variables are as defined in claim 1.
References Cited (Backward Citations)
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