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EP0077840A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Curable resin composition

Assignee: Mitsui Toatsu Chemicals Inc
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Filing: 1981-10-23
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Granted: —
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Expires: 2001-10-23
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Abstract

Abstract Disclosed is a curable resin composition comprising a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyllmaleimide derivatives, and dimers and polymers thereof and b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof. The resin composition may contain, besides the above two components, an amino compound as a further component c). The resin composition may comprise a prepolymer of any two components among the three components a), b) and c) and the remaining component.

Inventors

  • 👤 Hikotada Tsuboi
  • 👤 Motoo Kawamata
  • 👤 Masayuki Oba
  • 👤 Nobuhito Koga

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-09 00:27
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G59/50; C08G59/56; C08G73/00; C08G73/06; C08G73/10; C08G73/12

Claims Analysis

Total Claims: 43
Claim 1
Independent Claim 289 words
A curable resin composition comprising: a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyl)maleimides represented by the general formula (I): wherein R 1 -R 6 may be the same or different from one another and denote independently hydrogen, a hydrocarbon group having 1-20 carbon atoms, a halogen, R 0- or R 7 C- group(where R represents a hydrocarbon group having 1-20 carbon atoms or a hydrocarbon group having 1-20 carbon atoms and substituted by one or more halogen atoms of at least one kind), hydroxyl group, cyano group, or a hydrocarbon group substituted by one or more halogens, R 7 0- or group(where R 7 is as defined above), hydroxyl group or cyano group and having 1-20 carbon atoms prior to the substitution, a plurality of R 4 s may be the same or different when m 1 stands for a value of 2 or greater, R 3 may be coupled with either R 1 or R 2 , thereby forming a ring, X denotes at least one atom or group selected from hydrogen, halogens, hydroxyl group, R 7 0-, R 7 C- and R 7 CN- groups(where R is as defined above), cyano group, nitro group and carboxyl group, a plurality of Xs may be the same or different when m 2 stands for a value of 2 or greater, and m 1 , m 2 and m 3 represent independently a positive integer and m l , + m 2 + m 3 = 5, dimers of said maleimides and polymers of said maleimides having a polymerization degree of at least 3; and b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof.
Claim 2
Dependent Claim 289 words
A curable resin composition comprising: a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyl)maleimides represented by the general formula (I): wherein R 1 -R 6 may be the same or different from one another and denote independently hydrogen, a hydrocarbon group having 1-20 carbon atoms, a halogen, R 0- or R 7 C- group(where R represents a hydrocarbon group having 1-20 carbon atoms or a hydrocarbon group having 1-20 carbon atoms and substituted by one or more halogen atoms of at least one kind), hydroxyl group, cyano group, or a hydrocarbon group substituted by one or more halogens, R 7 0- or group(where R 7 is as defined above), hydroxyl group or cyano group and having 1-20 carbon atoms prior to the substitution, a plurality of R 4 s may be the same or different when m 1 stands for a value of 2 or greater, R 3 may be coupled with either R 1 or R 2 , thereby forming a ring, X denotes at least one atom or group selected from hydrogen, halogens, hydroxyl group, R 7 0-, R 7 C- and R 7 CN- groups(where R is as defined above), cyano group, nitro group and carboxyl group, a plurality of Xs may be the same or different when m 2 stands for a value of 2 or greater, and m 1 , m 2 and m 3 represent independently a positive integer and m l , + m 2 + m 3 = 5, dimers of said maleimides and polymers of said maleimides having a polymerization degree of at least 3; and b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof.
Claim 3
Dependent Claim 94 words
A curable resin composition as claimed in Claim 1, wherein said composition further comprises c) an amino compound represented by the general formula (II): wherein Q indicates an organic group having 1-150 carbon atoms and a valence of n, Q may contain at least one kind of atoms selected from hydrogen, oxygen, sulphur, halogen, nitrogen, phosphorus and silicon atoms, and n stands for an integer of at least 1, and said composition contains at least one kind of a prepolymer of at least parts of any two components among components a), b) and c).
Claim 4
Dependent Claim 41 words
A curable resin composition as claimed in Claim 1 or 2, wherein said maleimide compound is at least one maleimide compound selected from the group consisting of N-(p-isopropenylphenyl)maleimide, its dimers and its polymers having a polymerization degree of at least 3.
Claim 5
Dependent Claim 21 words
A curable resin composition as claimed in Claim 1-or 2, wherein said maleimide compound is at least one dimer of N-(p-isopropenylphenyl)maleimide.
Claim 6
Dependent Claim 22 words
A curable resin composition as claimed in.Claim 1 or 2, wherein said maleimide compound is at least one linear dimer of N-(p-isopropenylphenyl)maleimide.
Claim 7
Dependent Claim 26 words
A curable resin composition as claimed in Claim 5, wherein the linear dimer of N-(p-isopropenylphenyl) maleimide is at least one dimer selected from 4-methyl-2,4-bis(p-N-maleimidophenyl)pentene-l and 4-methyl-2,4-bis(p-N-maleimidophenyl)pentene-2.
Claim 8
Dependent Claim 39 words
A curable resin composition as claimed in Claim 1 or 2, wherein component a) is a mixture of N-(p-isopropenyl- phenyl)maleimide, its dimers, its trimers, and one or more of its polymers having a polymerization degree of at least 4.
Claim 9
Dependent Claim 20 words
A curable resin composition as claimed in Claim 7, wherein said mixture contains at least 70% of dimers of N-(p-isopropenylphenyl)maleimide.
Claim 10
Dependent Claim 24 words
A curable resin composition as claimed in Claim 1 or 2, wherein said epoxy resins include at least one epoxy resin containing benzene rings.
Claim 11
Dependent Claim 22 words
A curable resin composition as claimed in Claim 1 or 2, wherein said epoxy resins include at least one bisphenol-type epoxy resin.
Claim 12
Dependent Claim 22 words
A curable resin composition as claimed in Claim 1 or 2, wherein said epoxy resins include at least one novolak-type epoxy resin.
Claim 13
Dependent Claim 23 words
A curable resin composition as claimed in Claim 2, wherein said amino compound is an amino compound containing one or more benzene rings.
Claim 14
Dependent Claim 21 words
A curable resin composition as claimed in Claim 2, wherein said amino compound is a reaction product of aniline and formaldehyde.
Claim 15
Dependent Claim 18 words
A curable resin composition as claimed in Claim 2, wherein said amino compound is 4,4 t- diaminodiphenyl methane.
Claim 16
Dependent Claim 26 words
A curable resin composition as claimed in Claim 1 or 2, wherein the weight ratio of component b) to component a) ranges from 3:97 to 97:3.
Claim 17
Dependent Claim 24 words
A curable resin composition as claimed in Claim 2, wherein the weight ratio of component c) to component a) ranges from 3:97 to 97:3.
Claim 18
Dependent Claim 69 words
A curable resin composition as claimed in Claim 2, wherein the prepolymer is formed by a part of component c) and a part of component a) and the weight ratio of component c) to component a) in said prepolymer is such that the number ratio of all amino groups in component c) in the prepolymer to all maleimido groups in component a) in the prepolymer is 1 or less.
Claim 19
Dependent Claim 44 words
A curable resin composition as claimed in Claim 2, wherein the prepolymer is formed by a part of component b) and a part of component c), and has a molecular weight of from 50 to 8000 and is soluble to a solvent and fusible.
Claim 20
Dependent Claim 19 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition is substantially free of solvent.
Claim 21
Dependent Claim 19 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises an organic solvent.
Claim 22
Dependent Claim 49 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises at least one compound selected from the group consisting of tetrahydrofuran, methylethyl ketone, 1,4-dioxane, acetone, methylisobutyl ketone, dichloromethane, trichloroethane, benzene, toluene, xylene, acetonitrile, 2-methoxyethanol, 2-n-butoxyethanol, 2-ethoxyethylacetate, diethylether, methylcellosolve, ethylcellosolve, N,N-dimethylformamide, N,N-dimethylacetamide and N-methyl-2-pyrrolidone.
Claim 23
Dependent Claim 35 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises at least one compound selected from the group consisting of tetrahydrofuran, methylethyl ketone, 1,4-dioxane, acetone, acetonitrile, methylcellosolve, and ethylcellosolve.
Claim 24
Dependent Claim 26 words
- Varnish containing a curable resin composition as claimed in Claim 1 or 2 and having a resin concentration of from 5 to 80% by weight.
Claim 25
Dependent Claim 25 words
Varnish containing a curable resin composition as claimed in Claim 1 or 2 and having a resin concentration of from 10 to 70% by weight.
Claim 26
Dependent Claim 81 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises one or more resins selected from the group consisting of drying oil, semi-drying oil, oleoresin, rosin, shellac, oil-modified rosin, phenol resins, alkyl resins, urea resins, melamine resins, polyester resins, polyvinylbutyral resins, vinylacetate resins vinylchloride resin, acrylic resins and silicone resins, and said one or more resins are contained in total in an amount of not more than 30% of the weight of the entire resins.
Claim 27
Dependent Claim 45 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises one or more powdery materials other than resins and said powdery materials are contained in total in an amount up to 4 time the weight of the entire resins.
Claim 28
Dependent Claim 30 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises a coupling agent in an amount of 0.001-10% by weight of the entire resins.
Claim 29
Dependent Claim 30 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises a coupling agent in an amount of 0.01-5% by weight of the entire resins.
Claim 30
Dependent Claim 38 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises at least one kind of fire retardants and flame resistant agents in an amount of 1-70% by weight of the entire resins.
Claim 31
Dependent Claim 38 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises at least one kind of fire retardants and flame resistant agents in an amount of 5-40% by weight of the entire resins,
Claim 32
Dependent Claim 22 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises a curing agent for component b).
Claim 33
Dependent Claim 20 words
A curable resin composition as claimed in Claim 1 or 2, wherein said composition further comprises a radical polymerization initiator.
Claim 34
Dependent Claim 18 words
An article or item obtained by curing a curable resin composition as claimed in Claim 1 or 2.
Claim 35
Dependent Claim 17 words
A coating film obtained by curing a curable- resin composition as claimed in Claim 1 or 2.
Claim 36
Dependent Claim 17 words
A molded product obtained by curing a curable resin composition as claimed in Claim 1 or 2.
Claim 37
Dependent Claim 17 words
A laminated product obtained by curing a curable resin composition as claimed in Claim 1 or 2.
Claim 38
Dependent Claim 37 words
A preimpregnate obtained by impregnating a sheet-like reinforcement material with a curable resin composition as claimed in Claim 1 or 2 and then causing said composition to semi-cure, in other words, converting said composition into the B-stage.
Claim 39
Dependent Claim 15 words
A preimpregnate as claimed in Claim 37, wherein said sheet-like reinforcement material contains glass fibers.
Claim 40
Dependent Claim 13 words
A laminate obtained from a plurality of preimpregnates as claimed in Claim 37.
Claim 41
Dependent Claim 14 words
A copper-lined laminate obtained from a plurality of preimpregnates as claimed in Claim 37.
Claim 42
Dependent Claim 13 words
A laminate obtained from a plurality of preimpregnates as claimed in Claim 37.
Claim 43
Dependent Claim 14 words
A copper-lined laminate obtained from a plurality of preimpregnates as claimed in Claim 37.

References Cited (Backward Citations)

EP0010489A2 Cited
GB2046263A Cited

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